Hydrophilic surfaces carrying temporary protective covers

• US 6,902,813 B2
• Filed: 09/11/2001
• Issued: 06/07/2005
• Est. Priority Date: 09/11/2001
• Status: Expired due to Term

• Current Assignee: Cardinal CG Company (Cardinal Glass Industries Incorporated)
• Original Assignee: Cardinal CG Company (Cardinal Glass Industries Incorporated)
• Inventors: Hartig, Klaus, Krisko, Annette J., O'Shaughnessy, Roger D.
• Primary Examiner(s): McNeil, Jennifer
• Assistant Examiner(s): BLACKWELL, GWENDOLYN
• Application Number:
  US10/009,284
• Publication Number:
  US 20030118860A1
• Time in Patent Office: 1,365 Days
• Field of Search: 428/426, 428/432, 428/701, 428/702, 428/699, 428/41.7
• US Class Current: 428/432
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C03C 2217/75 Hydrophilic and oleophilic coatings
• CPC Class Codes: C03C 2218/355 Temporary coating
• CPC Class Codes: Y10T 428/1259 Oxide
• CPC Class Codes: Y10T 428/12611 Oxide-containing component
• CPC Class Codes: Y10T 428/12792 Zn-base component
• CPC Class Codes: Y10T 428/1471 Protective layer

Abstract

A substrate carrying a temporary protective cover and related methods of producing and processing substrates are described. In one embodiment, a substrate bears a hydrophilic coating carrying a temporary protective cover that protects the hydrophilic coating against contamination but that can readily be readily removed from the hydrophilic coating by washing with a given washing fluid.

Claims

1. A substrate having an exterior surface bearing a hydrophilic coating that is resistant to attack by a weak acid or a weak base, the hydrophilic coating carrying a temporary protective cover that is durable to glass tempering and is stable in the presence of water but breaks down in the presence of a weak acid or a weak base, wherein the substrate has an interior surface bearing a low-emissivitv coating comprising a metal layer sandwiched between a pair of dielectric layers.

2. The substrate of claim 1 wherein the cover comprises a sputtered material.

3. The substrate of claim 1 wherein the cover comprises an oxide of a metal.

4. The substrate of claim 3 wherein the cover comprises an oxide of a metal selected from the group consisting of zinc, bismuth, cadmium, iron, and nickel.

5. The substrate of claim 4 wherein the cover comprises zinc oxide.

6. The substrate of claim 1 wherein the cover has a thickness of less than about 2500 angstroms.

7. The substrate of claim 6 wherein the cover has a thickness of less than about 100 angstroms.

8. The substrate of claim 7 wherein the cover has a thickness of between about 25 angstroms and about 60 angstroms.

9. The substrate of claim 1 wherein the cover breaks down in the presence of vinegar.

10. The substrate of claim 1 wherein the cover is formed directly upon the hydrophilic coating.

11. The substrate of claim 10 wherein the hydrophilic coating is an oxide.

12. The substrate of claim 1 wherein the hydrophilic coating has a contact angle with water of less than about 25 degrees when the cover is removed.

13. The substrate of claim 1 wherein the hydrophilic coating comprises sputtered silicon dioxide.

14. The substrate of claim 13 wherein the silicon dioxide is substantially non-porous.

15. The substrate of claim 1 wherein the hydrophilic coating is formed directly upon the substrate.

16. The substrate of claim 1 wherein the hydrophilic coating is formed upon one or more films previously deposited on the substrate.

17. The substrate of claim 1 wherein the hydrophilic coating is formed upon an infrared-reflective coating previously deposited on the substrate.

18. The substrate of claim 17 wherein the infrared-reflective coating comprises at least one pyrolytically-applied layer.

19. A substrate bearing a hydrophilic coating comprising silicon dioxide formed directly upon the substrate, the hydrophilic coating being durable to a given washing fluid, the hydrophilic coating carrying a temporary protective cover comprising a sputtered film that protects the hydrophilic coating against contamination but that can readily be removed from the hydrophilic coating by washing with said washing fluid, the temporary protective cover being durable to glass tempering, wherein the substrate has an interior surface bearing a low-emissivity coating comvrising a metal layer sandwiched between a pair of dielectric layers.

20. The substrate of claim 19 wherein the sputtered film comprises an oxide of a metal.

21. The substrate of claim 20 wherein the sputtered film comprises an oxide of a metal selected from the group consisting of zinc, bismuth, cadmium, iron, and nickel.

22. The substrate of claim 21 wherein the sputtered film comprises zinc oxide.