After-treatment system and method for reducing emissions in diesel engine exhaust

• US 6,915,629 B2
• Filed: 03/07/2002
• Issued: 07/12/2005
• Est. Priority Date: 03/07/2002
• Status: Expired due to Term

• Current Assignee: GM Global Technology Operations LLC (General Motors Company)
• Original Assignee: General Motors Corporation (General Motors Company)
• Inventors: Szymkowicz, Patrick G.
• Primary Examiner(s): Denion, Thomas
• Assistant Examiner(s): TRAN, DIEM T
• Application Number:
  US10/093,182
• Publication Number:
  US 20030167756A1
• Time in Patent Office: 1,223 Days
• Field of Search: 602/74, 602/89, 602/86, 603/01, 603/11, 602/85, 602/95, 602/97, 603/00, 603/03
• US Class Current: 60/289
• CPC Class Codes: F01N 13/009 having two or more separate purifying devices arranged in series
• CPC Class Codes: F01N 13/0093 the purifying devices are of the same type
• CPC Class Codes: F01N 2570/04 Sulfur or sulfur oxides
• CPC Class Codes: F01N 2570/10 Carbon or carbon oxides
• CPC Class Codes: F01N 2570/14 Nitrogen oxides
• CPC Class Codes: F01N 3/023 using means for regenerating the filters, e.g. by burning trapped particles by electrically controlling the supply of combustible mixture or its constituents only F02D41/0235
• CPC Class Codes: F01N 3/035 with catalytic reactors , e.g. catalysed diesel particulate filters
• CPC Class Codes: F01N 3/0814 combined with catalytic converters, e.g. NOx absorption/storage reduction catalysts
• CPC Class Codes: F01N 3/0821 combined with particulate filters catalysed diesel particulate filters F01N3/035
• CPC Class Codes: F01N 3/0842 Nitrogen oxides
• CPC Class Codes: F01N 3/2033 using a fuel burner or introducing fuel into exhaust duct
• CPC Class Codes: F01N 3/22 Control of additional air supply only, e.g. using by-passes or variable air pump drives
• CPC Class Codes: F02B 37/00 Engines characterised by provision of pumps driven at least for part of the time by exhaust
• CPC Class Codes: Y02T 10/12 Improving ICE efficiencies

Abstract

An after-treatment system arrangement and method of operating the after-treatment system arrangement is provided for heating the exhaust gas of an internal combustion engine. The after-treatment system arrangement includes an oxidation device for catalytically oxidizing the exhaust gas and a port in the exhaust-gas stream for selectively introducing a controlled amount of oxygen into the exhaust gas in response to a condition of the exhaust gas. The introduction of oxygen can be selectively controlled in response to the temperature of the exhaust gas downstream of the oxidation device. Simultaneously or alternatively, the introduction of oxygen can be selectively controlled in response to the chemical composition of the exhaust gas. The air-to-fuel ratio of the exhaust gas may also be controlled to further facilitate heating of the exhaust gas. The after-treatment system arrangement can also be controlled to remove pollutant emissions from the exhaust gas.

Claims

1. A method of heating the exhaust gas of an internal combustion engine comprising the steps of:

determining a first temperature of the exhaust gas at a point downstream of a first oxidation device;

maintaining the air-to-fuel ratio entering the engine;

selectively increasing the level of oxygen and the level of a reactant in the exhaust gas by introduction of oxygen and the reactant into the exhaust gas before it enters the first oxidation device in response to the first temperature of the exhaust gas;

catalytically oxidizing the exhaust gas, wherein the catalytic oxidation of the reactant introduced into the exhaust gas raises the temperature of the exhaust gas; and

introducing the exhaust gas after the first oxidation device into a NO_x abatement device.

2. The method of claim 1 further including selectively increasing the level of reactants in the exhaust gas in response to the condition of the exhaust gas prior to catalytically oxidizing the exhaust gas.

3. The method of claim 2, wherein the reactant comprises carbon monoxide.

4. The method of claim 1, wherein the selectively increasing of the level of oxygen in the exhaust gas is further defined by selectively injecting a controlled amount of oxygen into the exhaust gas.

5. The method of claim 1, wherein the selectively increasing of the level of oxygen in the exhaust gas is further defined by selectively injecting a controlled amount of air into the exhaust gas.

6. The method of claim 1, wherein the determining of the temperature of the exhaust gas comprises determining the temperature of the exhaust gas subsequent to catalytically oxidizing the exhaust gas.

7. The method of claim 6, wherein determining the temperature of the exhaust gas comprises sensing the exhaust gas temperature and, wherein the increasing step comprises selectively increasing the level of oxygen to provide a desired temperature.

8. The method of claim 6, wherein the temperature of the exhaust gas is determined by a characteristic map and, wherein the increasing comprises selectively increasing the level of oxygen to provide a desired temperature.

9. An after-treatment system arrangement for heating the exhaust gas of an internal combustion engine comprising:

an oxidation device for catalytically oxidizing the exhaust gas;

a NO_x abatement device connected downstream of the oxidation device;

an oxygen source;

a source of reactants; and

a first port upstream of the oxidation device for selectively introducing a controlled amount of oxygen and a second port upstream of the oxidation device for selectively introducing a controlled amount of reactants into the exhaust gas in response to the temperature of the exhaust gas as determined at a point downstream of the oxidation device.

10. The arrangement of claim 9, wherein the reactants comprise at least carbon monoxide.

11. The arrangement of claim 9, wherein the second port selectively injects a controlled amount of reactants to supplement the reactants introduced into the exhaust gas by operating the engine rich.

12. The arrangement of claim 9, wherein the oxygen is contained in air.

13. The arrangement of claim 12, wherein the first port is configured to selectively introduce a controlled amount of air into the exhaust-gas.

14. The arrangement of claim 9, further including at least one sensor, wherein the temperature of the exhaust gas is measured by the sensor and the first port is operated to increase the level of oxygen in the exhaust to provide a desired temperature.

15. The arrangement of claim 9, further including a control unit, wherein the temperature of the exhaust gas is determined by a characteristic map in the control unit and the first port is operated to increase the level of oxygen in the exhaust to provide a desired temperature.

16. A method of reducing emissions in the exhaust-gas of a diesel engine, comprising:

(a) when the air-to-fuel ratio of the exhaust gas is lean in fuel,

catalytically oxidizing in a first oxidation device the exhaust gas from the engine, selectively increasing the level of oxygen and the level of reactants in the exhaust gas by introduction of oxygen and reactants into the exhaust gas before it enters the first oxidation device in response to a first temperature of the exhaust gas measured downstream of the first oxidation device, wherein the catalytic oxidation of the reactants introduced into the exhaust gas raises the temperature of the exhaust gas exiting the first oxidation device;

removing nitrogen oxides from the exhaust gas in a NO_x abatement device; and

collecting particulate matter contained in the exhaust gas in a particulate filter; and

(b) periodically regenerating one or both of the NO_x abatement device and the particulate matter filter by intentionally shifting the air-to-fuel ratio of the exhaust to a fuel rich air-to-fuel ratio and

selectively introducing a controlled amount of oxygen into the exhaust gas prior to a second oxidation device downstream of the NO_x abatement device to facilitate heating of the exhaust gas to a temperature that promotes combustion of the collected particulate matter.

17. The method of claim 16, wherein the regenerating of the adsorbent and particulate filter occur nearly simultaneously.

18. The method of claim 16, wherein the regenerating of the particulate filter is further defined by introducing a controlled amount of air into the exhaust gas sufficient to promote the rapid combustion of the collected particulate matter.

19. The method of claim 16, wherein the removing of nitrogen oxides from the exhaust gas is further defined by catalytically reducing nitrogen oxides to nitrogen and water by selective catalytic reduction when the air-to-fuel ratio of the exhaust gas is lean in fuel.

20. The method of claim 19, wherein the catalytically reducing of nitrogen oxides is further defined by selectively introducing at least one of hydrocarbons, urea and ammonia into the exhaust gas prior to catalytically reducing the nitrogen oxides.

21. The method of claim 16, wherein the removing of nitrogen oxides from the exhaust gas is further defined by adsorbing the nitrogen oxides in an adsorbent when the air-to-fuel ratio of the exhaust gas is lean in fuel.

22. The method of claim 21 further including periodically regenerating the adsorbent by intentionally shifting the air-to-fuel ratio of the exhaust gas to a fuel rich air-to-fuel ratio and selectively introducing a controlled amount of oxygen into the exhaust gas to facilitate heating of the exhaust gas to a temperature range that supports the release of the nitrogen oxides from the adsorbent.

23. The method of claim 22, wherein the regenerating of the adsorbent is further defined by introducing a controlled amount of oxygen into the exhaust gas downstream of the adsorbent to oxidize substantially all of the hydrocarbons and carbon monoxide remaining in the exhaust gas.

24. The method of claim 22, wherein the regenerating of the adsorbent is further defined by introducing a controlled amount of oxygen into the exhaust gas downstream of the adsorbent to oxidize ammonia and hydrogen sulfide in the exhaust gas.

25. The method of claim 22, wherein the regenerating of the adsorbent is further defined by sensing at least the level of nitrogen oxides in the exhaust gas and switching the air-to-fuel ratio of the exhaust gas from being lean in fuel to being rich in fuel when the level of nitrogen oxides in the exhaust gas exceeds a threshold value.

26. The method of claim 22, wherein the regenerating of the adsorbent is further defined by switching the air-to-fuel ratio of the exhaust gas from being lean in fuel to being rich in fuel as determined by characteristic maps.

27. The method of claim 22, wherein the catalytically oxidizing of the exhaust gas from the engine comprises oxidizing at least one of hydrogen, hydrocarbons and carbon monoxide in the exhaust gas.

28. The method of claim 27, wherein the regenerating of the adsorbent is further defined by controlling the amount of oxygen introduced into the exhaust gas such that a portion of the hydrogen, hydrocarbons and carbon monoxide in the exhaust gas remain unoxidized.

29. The method of claim 28, wherein the regenerating of the adsorbent is further defined by passing the hydrogen, hydrocarbon and carbon monoxide rich exhaust gas through the adsorbent where a reaction occurs between at least a portion of the hydrogen, hydrocarbons and carbon monoxide and the stored nitrogen oxides.