Electrochemical sensor having improved response time

• US 6,929,735 B2
• Filed: 01/16/2003
• Issued: 08/16/2005
• Est. Priority Date: 11/19/1999
• Status: Expired due to Fees

• Current Assignee: PerkinElmer LAS, Inc. (Perkinelmer Incorporated)
• Original Assignee: Perkinelmer Instruments LLC (Revvity, Inc.)
• Inventors: Dalmia, Avinash, Prohaska, Otto J.
• Primary Examiner(s): Olsen, Kaj K.
• Application Number:
  US10/345,772
• Publication Number:
  US 20030106811A1
• Time in Patent Office: 943 Days
• Field of Search: 204421-429, 205/783.5
• US Class Current: 205/783.5
• CPC Class Codes: G01N 2030/125 pyrolising
• CPC Class Codes: G01N 2030/645 electrical conductivity detectors
• CPC Class Codes: G01N 27/4074 for detection of gases other than oxygen

Abstract

The invention relates to a method and apparatus for providing an electrochemical gas sensor having improved response time for detecting a gas introduced into the sensor. The sensor includes a substrate having a first surface and a second surface and an electrode deposited on the first surface. The sensor also includes an ionomer membrane in contact with the first surface and the electrode. The ionomer membrane has an opening in a location proximate to the electrode for permitting gas introduced into the sensor to diffuse through the opening to simultaneously contact the electrode and the ionomer membrane within the opening. The substrate further includes at least one hole extending from the first surface to the second surface for permitting moisture to diffuse through the at least one hole to contact the ionomer membrane for enhancing sensitivity.

Claims

1. An electrochemical gas sensor for detecting a gas, comprising:

a substrate having a first surface and a second surface;

an ionomer membrane in contact with said first surface and having a proximal outermost surface and a distal outermost surface;

an electrode in contact with said first surface;

an opening in said ionomer membrane extending from said proximal outermost surface to said distal outermost surface in a location proximate to said electrode for defining a passage for gas to simultaneously contact said electrode and said ionomer membrane within said opening;

said substrate further including at least one hole extending from said first surface to said second surface for permitting moisture to diffuse through said at least one hole to contact said ionomer membrane;

a reservoir for containing moisture to moisten said ionomer membrane; and

said reservoir is located on a side of said substrate opposite said ionomer membrane.

2. The electrochemical gas sensor according to claim 1, wherein said reservoir is located adjacent to said substrate.

3. The electrochemical gas sensor according to claim 1, wherein said opening extends from a first surface to a second surface of said ionomer membrane for defining walls to guide the gas to said sensing electrode.

4. The electrochemical gas sensor according to claim 1, said at least one hole further comprising moisture, said moisture being diffused from said reservoir to said ionomer membrane.

5. The electrochemical gas sensor according to claim 1, further comprising a wicking material in contact with said second surface for drawing moisture from said reservoir toward said substrate.

6. The electrochemical gas sensor according to claim 5, wherein said wicking material is located in said at least one hole of said substrate.

7. The electrochemical gas sensor according to claim 5, wherein said reservoir is spaced apart from said second surface and said wicking material is between said second surface and said reservoir.

8. The electrochemical gas sensor according to claim 1, further comprising a film of electrolytic material on said electrode to increase a three phase contact between the gas, said electrode, and said ionomer membrane.

9. The electrochemical gas sensor according to claim 1, wherein said substrate is a foil.

10. A method for detecting a gas, comprising the steps of:

providing a substrate having a surface;

providing at least one hole in the substrate that extends from a first surface of the substrate to a second surface of the substrate;

depositing an electrode on the first surface;

contacting an ionomer membrane with the electrode;

providing an opening in the ionomer membrane extending from a proximal outermost surface to a distal outermost surface in an approximate area of the electrode;

introducing a gas into the opening toward the electrode;

simultaneously contacting the gas with both the electrode and ionomer membrane;

providing a reservoir containing moisture to moisten the ionomer membrane; and

positioning the reservoir on a side of the substrate opposite the ionomer membrane.

11. The method according to claim 10, further comprising the step of positioning the reservoir adjacent to the substrate.

12. The method according to claim 10, further comprising the step of diffusing moisture from the reservoir to the at least one hole.

13. The method according to claim 10, further comprising the step of placing a wicking material in contact with the second surface and a solution in the reservoir for drawing moisture from the reservoir toward the substrate.

14. The method according to claim 10, further comprising the step of placing a wicking material in the at least one hole.

15. The method according to claim 10, further comprising the step of directing gas through the opening toward the electrode.

16. The method according to claim 10, further comprising the step of controlling the gas as it passes through the opening toward the electrode.

17. The method according to claim 10, further comprising the step of controlling the solution as it passes through the at least one hole in the substrate.

18. The method according to claim 10, further comprising the step of oxidizing the gas as the gas contacts the surface of the electrode.

19. The method according to claim 10, further comprising the step of reducing the gas as the gas contacts the surface of the electrode.