Method and apparatus for measuring the concentration of hydrogen peroxide in a fluid

• US 6,933,733 B2
• Filed: 09/22/2003
• Issued: 08/23/2005
• Est. Priority Date: 03/14/2003
• Status: Expired due to Term

• Current Assignee: Steris Corporation
• Original Assignee: Steris Corporation
• Inventors: Centanni, Michael A., Korenev, Sergey A., Korenev, Ivan S.
• Primary Examiner(s): Deb, Anjan
• Assistant Examiner(s): He, Amy
• Application Number:
  US10/667,988
• Publication Number:
  US 20040178799A1
• Time in Patent Office: 701 Days
• Field of Search: 324/663, 324/664, 324691-698, 324658-662, 324/453, 324439-450, 204/403.01, 204/416, 204/431, 205/775, 205/777, 205/778.5, 205/782, 205/789
• US Class Current: 324/663
• CPC Class Codes: G01N 27/06 of a liquid involving electrolysis G01N27/26
• CPC Class Codes: G01N 27/221 by investigating the dielectric properties using microwaves G01N22/00; measuring loss factors or dielectric constants per se G01R27/26

Abstract

A method and apparatus for measuring the concentration of hydrogen peroxide in a liquid or gaseous fluid. A capacitor is exposed to the fluid, wherein the fluid acts as the dielectric between the conductors of the capacitor. The permittivity and dielectric constant associated with the fluid is affected by the relative concentrations of the chemical components comprising the fluid. A measurement of the capacitance is used to determine the relative concentration levels of the chemical components in the fluid. In an alternative embodiment, a resistor, and associated resistance values, are used to determine the concentration of hydrogen peroxide in a liquid or gaseous fluid.

Claims

1. A chemical concentration measuring system used in a biocontamination deactivation apparatus having a vaporizer that receives a feed stream comprised of a fluid having hydrogen peroxide and at least one chemical component, wherein the chemical concentration measuring system determines the concentration of the hydrogen peroxide in the fluid, the system comprising:

sensing means responsive to changes in the concentration of the hydrogen peroxide in the fluid, the sensing means including a capacitive voltage divider circuit including;

(a) a first capacitor having first and second conductors exposed to the fluid, said fluid comprising a dielectric therebetween, and

(b) a second capacitor;

an alternating current (AC) voltage generator for applying an AC voltage to the capacitive voltage divider circuit;

a memory for storing a table of data including capacitance values and corresponding concentration values indicative of the relative concentration of hydrogen peroxide in the fluid; and

processing means for measuring a voltage across the second capacitor to determine a capacitance value associated with the first capacitor, and determining the concentration of the hydrogen peroxide in the fluid using the determined capacitance value and the table of data stored in the memory.

2. A chemical concentration measuring system according to claim 1, wherein said first capacitor is selected from the group consisting of:

a parallel plate capacitor, a cylindrical capacitor, and a spherical capacitor.

3. A chemical concentration measuring system according to claim 2, wherein said first capacitor is a parallel plate capacitor, said first and second conductors being metal net plates.

4. A chemical concentration measuring system according to claim 1, wherein said processing means obtains a relative concentration of the hydrogen peroxide using said table of data.

5. A chemical concentration measuring system according to claim 4, wherein said processing means normalizes said relative concentration of the hydrogen peroxide to provide an absolute concentration of the hydrogen peroxide in the fluid.

6. A chemical concentration measuring system according to claim 1, wherein said processing means interpolates or extrapolates a relative concentration of the hydrogen peroxide using said table of data.

7. A chemical concentration measuring system according to claim 1, wherein said at least one chemical component is liquid water.

8. A chemical concentration measuring system used in a biocontamination deactivation apparatus having a vaporizer that receives a feed stream comprised of a fluid having hydrogen peroxide and at least one chemical component, wherein the chemical concentration measuring system determines the concentration of the hydrogen peroxide in the fluid, the system comprising:

sensing means responsive to changes in the concentration of the hydrogen peroxide in the fluid, the sensing means including a resistive voltage divider circuit including;

(a) a first resistor including first and second conductors exposed to the fluid, said fluid comprising a resistive element of the first resistor, and

(b) a second resistor;

a memory for storing a table of data including resistance values and corresponding concentration values indicative of the relative concentration of hydrogen peroxide in the fluid;

an alternating current (AC) voltage generator for applying an AC voltage to the resistive voltage divider circuit; and

processing means for measuring a voltage across the second resistor to determine a resistance value associated with the first resistor, and determining the concentration of the hydrogen peroxide in the fluid using the determined resistance value and the table of data stored in the memory.

9. A chemical concentration measuring system according to claim 8, wherein said processing means obtains a relative concentration of the hydrogen peroxide using said table of data.

10. A chemical concentration measuring system according to claim 9, wherein said processing means normalizes said relative concentration of the hydrogen peroxide to provide an absolute concentration of the hydrogen peroxide in the fluid.

11. A chemical concentration measuring system according to claim 8, wherein said processing means interpolates or extrapolates a relative concentration of the hydrogen peroxide using said table of data.

12. A chemical concentration measuring system according to claim 8, wherein said at least one chemical component is liquid water.

13. A method for determining a concentration of hydrogen peroxide in a feed stream received by a vaporizer for a biocontamination deactivation apparatus, wherein the feed stream is comprised of a fluid having hydrogen peroxide and at least one chemical component, the method comprising:

exposing a capacitor, of a capacitive voltage divider circuit, to the fluid, wherein said fluid comprises a dielectric between first and second conductors of the capacitor, said capacitor having an associated voltage that varies according to the concentration of the hydrogen peroxide in the fluid;

pre-storing data in a memory, including capacitance values associated with the capacitor and corresponding concentration values that arc indicative of the concentration of the hydrogen peroxide in the fluid;

measuring the associated voltage;

determining a capacitance value associated with the capacitor using the measured associated voltage; and

accessing said pre-stored data using the capacitance value to determine the relative concentration of the hydrogen peroxide in the fluid.

14. A method according to claim 13, wherein said method further comprises:

interpolating or extrapolating from the table of data a relative concentration of the hydrogen peroxide in the fluid, corresponding to the capacitance value associated with the capacitor.

15. A method according to claim 13, wherein said method further comprises:

normalizing said relative concentration to provide an absolute concentration of the hydrogen peroxide in the fluid.

16. A method according to claim 13, wherein said at least one chemical component is liquid water.

17. A method for determining a concentration of hydrogen peroxide in a feed stream received by a vaporizer for a biocontamination deactivation apparatus, wherein the feed stream is comprised of a fluid having hydrogen peroxide and at least one chemical component, the method comprising:

exposing a resistor, of a resistive voltage divider circuit, to the fluid, wherein said fluid comprises a resistive element of the resistor between first and second conductors of the resistor, said resistor having an associated voltage that varies according to the concentration of the hydrogen peroxide in the fluid;

pre-storing data in a memory, including resistance values associated with the resistor and corresponding concentration values that are indicative of the concentration of the hydrogen peroxide in the fluid;

measuring the associated voltage;

determining a resistance value associated with the resistor using the measured associated voltage; and

accessing said pre-stored data using the resistance value to determine the relative concentration of the hydrogen peroxide in the fluid.

18. A method according to claim 17, wherein said method further comprises:

interpolating or extrapolating from the table of data a relative concentration of the hydrogen peroxide in the fluid, corresponding to the resistance value associated with the resistor.

19. A method according to claim 17, wherein said method further comprises:

normalizing said relative concentration to provide an absolute concentration of the hydrogen peroxide in the fluid.

20. A method according to claim 17, wherein said at least one chemical component is liquid water.