Processes and apparatus for making transversely drawn films with substantially uniaxial character

• US 6,939,499 B2
• Filed: 05/28/2002
• Issued: 09/06/2005
• Est. Priority Date: 05/31/2001
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Wheatley, John A., Merrill, William Ward, Ruff, Andrew T., Jackson, Jeffery N., Krueger, Dennis L.
• Primary Examiner(s): Lechert, Jr., Stephen J.
• Application Number:
  US10/156,347
• Publication Number:
  US 20020190406A1
• Time in Patent Office: 1,197 Days
• Field of Search: 264/288.4, 264/290.2, 264/291
• US Class Current: 264/288.4
• CPC Class Codes: B29C 2793/009 after shaping
• CPC Class Codes: B29C 55/08 transverse to the direction of feed
• CPC Class Codes: B29C 55/20 Edge clamps
• CPC Class Codes: B29C 69/001 a shaping technique combined with cutting, e.g. in parts or slices combined with rearranging and joining the cut parts for reinforced material B29C70/545; B29C49/4278, B29C51/268 take precedence
• CPC Class Codes: B29K 2067/003 PET, i.e. poylethylene terephthalate
• CPC Class Codes: B29K 2995/0051 mono-axially
• CPC Class Codes: B29L 2011/00 Optical elements, e.g. lenses, prisms
• CPC Class Codes: G02B 5/3033 in the form of a thin sheet or foil, e.g. Polaroid
• CPC Class Codes: Y10S 425/041 Reshape

Abstract

A process for stretching films is described. The process preferably stretches films in a uniaxial fashion. Preferably, optical films are stretched including multilayer optical films. Other aspects of the invention include a roll of stretched film and an apparatus for stretching films.

Claims

1. A method of processing a film, the method comprising:

conveying a film within a stretcher along a machine direction while holding opposing edge portions of the film; and

stretching the film within the stretcher by moving the opposing edge portions along diverging, substantially parabolic paths to form a stretched film.

2. The method of claim 1, wherein stretching the film comprises stretching the film to a draw ratio in excess of four within the stretcher by moving the opposing edge portions along diverging, substantially parabolic paths to form a stretched film.

3. The method of claim 1, wherein stretching the film comprises stretching the film under non-constant strain within the stretcher by moving the opposing edge portions along diverging, substantially parabolic paths to form a stretched film.

4. The method of claim 1, wherein the film has an initial thickness and initial width when conveyed into the stretcher and the stretched film has a stretched thickness and a stretched width;

and

wherein, after stretching the film to a ratio of stretched width/initial width defined as λ

, a ratio of stretched thickness/initial thickness is approximately λ

<sup>−

1/2</sup>.

5. The method of claim 1, wherein the step of stretching the film comprises stretching the film within the stretcher by moving the opposing edge portions along diverging, substantially parabolic paths, wherein the paths are coplanar.

6. The method of claim 1, wherein the step of stretching the film comprises stretching the film within the stretcher by moving the opposing edge portions along diverging, substantially parabolic paths, wherein the paths are substantially symmetrical about a center axis of the film.

7. The method of claim 1, further comprising providing the film to the stretcher in a continuous manner from a roll of film.

8. The method of claim 1, further comprising extruding or coextruding the film in-line with the stretcher.

9. The method of claim 1, wherein the stretched film comprises at least one layer with indices of refraction in a length direction, corresponding to the machine direction, and a thickness direction that are substantially the same but substantially different from an index of refraction in a width direction.

10. The method of claim 1, further comprising releasing the edge portions of the film at an end of the substantially parabolic paths.

11. The method of claim 1, wherein the film comprises a multilayer film having a plurality of alternating layers of different polymeric composition.

12. The method of claim 1, wherein the minimum value of the extent of uniaxial character, U, is at least 0.7, wherein U is defined as

U=(1/MDDR−

1)/(TDDR^1/2−

1)

wherein MDDR is the machine direction draw ratio and TDDR is the transverse direction draw ratio.

13. The method of claim 1, wherein the diverging, substantially parabolic paths have a functional form:

x/x₀=±

((1/4)(y/x₀)²+1)

wherein an x-axis is defined in a plane of the film and orthogonal to the machine direction with x=0 at a center axis of the film, a y-axis is defined in the plane of the film and along the machine direction with y=0 where stretching of the film commences within the stretcher, and x₀ is a distance of the edge portions from the center axis of the film when y=0.

14. The method of claim 1, wherein at least a portion of the diverging, substantially parabolic paths have a functional form:

(x+c)/(x₁+c)=±

((1/4)(y/(x₁+c))²+1)

wherein an x-axis is defined in a plane of the film and orthogonal to the machine direction with x=0 at a center axis of the film, a y-axis is defined in the plane of the film and along the machine direction with y=0 where stretching of the film commences within the stretcher, c is any number, and x₁ is a distance of the edge portions from the center axis of the film when y=0.

15. The method of claim 1, wherein the opposing edge portion of the film are substantially continuously supported.

16. A method of forming an optical film, the method comprising:

forming a multilayer film comprising alternating layers of different polymeric compositions;

conveying the multilayer film into a stretcher along a machine direction while holding opposing edge portions of the multilayer film; and

stretching the multilayer film within the stretcher by moving the opposing edge portions along diverging, substantially parabolic paths to form a multilayer optical film.

17. The method of claim 16, wherein the multilayer optical film is a substantially uniaxially-oriented multilayer optical film.

18. The method of claim 16, wherein the multilayer film has an initial thickness and initial width when conveyed into the stretcher and the multilayer optical film has a stretched thickness and a stretched width;

and

wherein, after stretching the multilayer film to a ratio of stretched width/initial width defined λ

, a ratio of stretched thickness/initial thickness is approximately λ

<sup>−

1/2</sup>.

19. The method of claim 16, wherein the minimum value of the extent of uniaxial character, U, is at least 0.7, wherein U is defined as

U=(1/MDDR−

1)/(TDDR^1/2−

1)

wherein MDDR is the machine direction draw ratio and TDDR is the transverse direction draw ratio.

20. The method of claim 16, wherein the diverging, substantially parabolic paths have a functional form:

x/x₀=±

((1/4)(y/x₀)²+1)

wherein an x-axis is defined in a plane of the multilayer film and orthogonal to the machine direction with x=0 at a center axis of the multilayer film, a y-axis is defined in the plane of the multilayer film and along the machine direction with y=0 where stretching of the multilayer film commences within the stretcher, and x₀ is a distance of the edge portions from the center axis of the multilayer film when y=0.

21. The method of claim 16, wherein at least a portion of the diverging, substantially parabolic paths have a functional form:

(x+c)/(x₁+c)=±

((1/4)(y/(x₁+c))²+1)

wherein an x-axis is defined in a plane of the multilayer film and orthogonal to the machine direction with x=0 at a center axis of the multilayer film, a y-axis is defined in the plane of the multilayer film and along the machine direction with y=0 where stretching of the multilayer film commences within the stretcher, c is any number, and x₁ is a distance of the edge portions from the center axis of the multilayer film when y=0.

22. A method of processing a film, the method comprising:

conveying a film within a stretcher along a machine direction while holding opposing edge portions of the film; and

stretching the film to a draw ratio in excess of four within the stretcher by moving the opposing edge portions along diverging, non-linear, coplanar paths to form a stretched film, wherein, during the stretching of the film, the minimum value of the extent of uniaxial character, U, is at least 0.8 over a final portion of the stretching after achieving a TDDR of 2.5 and U is less than 1 at the end of the stretching, wherein U is defined as

U=(1/MDDR−

1)/(TDDR^1/2−

1)

wherein MDDR is the machine direction draw ratio corresponding to a divergence angle of the diverging paths and TDDR is the transverse direction draw ratio as measured between the diverging paths.

23. The method of claim 22, wherein the minimum value of the extent of uniaxial character is at least 0.85.

24. The method of claim 22, wherein the film comprises a multilayer film having a plurality of alternating layers of different polymeric composition.

25. The method of claim 22, wherein the step of stretching the film comprises stretching the film within the stretcher by moving the opposing edge portions along diverging non-linear paths, wherein the paths are in a plane of the film.

26. The method of claim 22, wherein the step of stretching the film comprises stretching the film within the stretcher by moving the opposing edge portions along diverging non-linear paths, wherein the paths are substantially symmetrical about a center axis of the film.

27. The method of claim 22, wherein the extent of uniaxial character, U, is at least 0.8 over a final portion of the stretching after achieving a TDDR of 2.0.

28. A method of processing a film, the method comprising:

conveying a film within a stretcher along a machine direction while holding opposing edge portions of the film; and

stretching the film within the stretcher by moving the opposing edge portions along diverging non-linear paths to form a stretched film, wherein, during the stretching of the film, the speed of the film along the machine direction decreases by a factor of approximately λ

^1/2 where λ

is the transverse direction draw ratio.

29. The method of claim 28, wherein the film comprises a multilayer film having a plurality of alternating layers of different polymeric composition.

30. The method of claim 28, wherein the step of stretching the film comprises stretching the film within the stretcher by moving the opposing edge portions along diverging non-linear paths, wherein the paths are in a plane of the film.

31. The method of claim 28, wherein the step of stretching the film comprises stretching the film within the stretcher by moving the opposing edge portions along diverging non-linear paths, wherein the paths are substantially symmetrical about a center axis of the film.