Electrophotographic photoconductor, and process cartridge and electrophotographic apparatus using the same
First Claim
Patent Images
1. An electrophotographic photoconductor comprising:
- an electroconductive support and a photoconductive layer thereon; and
an outermost layer of the photoconductive layer comprising particles;
wherein a surface of the particles comprises;
a) a poly organosiloxane-containing phase which contains polyorganosiloxane; and
b) an organic polymer-containing phase which contains organic polymer without silicone or having polyorganosiloxane content less than the polyorganosiloxane-containing phase.
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Abstract
An electrophotographic photoconductor comprising at least an electroconductive support and a photoconductive layer which is formed on said electroconductive support, the outermost layer of the photoconductor contains particles comprising a polyorganosiloxane-containing phase which contains polyorganosiloxane and an organic polymer-containing phase which contains organic polymer without silicon and has a polyorganosiloxane content which is less than the polyorganosiloxane-containing phase, each phase being exposed at the top surface of the photoconductor.
59 Citations
22 Claims
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1. An electrophotographic photoconductor comprising:
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an electroconductive support and a photoconductive layer thereon; and
an outermost layer of the photoconductive layer comprising particles;
wherein a surface of the particles comprises;
a) a poly organosiloxane-containing phase which contains polyorganosiloxane; and
b) an organic polymer-containing phase which contains organic polymer without silicone or having polyorganosiloxane content less than the polyorganosiloxane-containing phase. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8)
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9. An electrophotographic photoconductor comprising:
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an electroconductive support and a photoconductive layer thereon;
wherein an outermost layer of the photoconductor comprises an acryl-modified polyorganosiloxane comprising a) main chain of a polyorganosiloxane; and
b) a graft chain of an acryl polymer without containing silicon;
wherein the acryl-modified polyorganosiloxane is prepared by emulsion graft copolymerizing of a polyorganosiloxane compound represented by the following formula (I) and a (meth)acrylic acid ester represented by the following formula (II) or a mixture of the (meth)acrylic acid ester and a monomer copolymerizable with the (meth)acrylic acid ester via emulsion graft copolymerization;
Formula (I) in the formula (I), each of R1, R2 and R3 is a hydrocarbon group having 1 to 20 carbon atoms and R1, R2 and R3 may be identical or different, or be halogenated;
Y is an organic group containing either a radical reactive group or SH group or both of them;
each of Z1 and Z2 is a hydrogen atom, lower alkyl group or one represented by the following formula (n), and Z1 and Z2 may be identical or different;
m is a plus integer of 10,000 or less; and
n is an integer of 1 or more;
in the formula (n) each of R4 and R5 is a hydrocarbon group or a halogenated hydrocarbon group having 1 to 20 carbon atoms and R4 and R5 may be identical or different; and
R6 is a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group, an organic group containing either a radical reactive group or SH group or both of them;
in the formula (II);
R7 is a hydrogen atom or a methyl group; and
R8 is at least any one member selected from the group consisting of an alkyl group, alkoxy-substituted alkyl group, cyclo alkyl group and aryl group. - View Dependent Claims (10, 11, 12, 13, 14, 15, 16, 17, 18)
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19. A process cartridge comprising an electrophotographic photoconductor which comprises:
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an electroconductive support and a photoconductive layer thereon; and
an outermost layer of the photoconductive layer comprising particles;
wherein a surface of the particles comprises;
a) a polyorganosiloxane-containing phase which contains polyorganosiloxane; and
b) an organic polymer-containing phase which contains organic polymer without silicone or having polyorganosiloxane content less than the polyorganosiloxane-containing phase.
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20. An electrophotographic device comprising:
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an electrophotographic photoconductor;
a charging unit configured to charge a latent image carrier;
a light irradiating unit configured to irradiate light imagewisely onto the latent image carrier so as to form a latent electrostatic image thereon;
an image developing unit configured to develop the latent electrostatic image to a developed image; and
a transfer charger configured to transfer the developed image to a recording medium;
wherein the electrophotographic photoconductor comprises;
an electroconductive support and a photoconductive layer thereon; and
an outermost layer of the photoconductive layer comprising particles;
wherein a surface of the particles comprises;
a) a polyorganosiloxane-containing phase which contains polyorganosiloxane; and
b) an organic polymer-containing phase which contains organic polymer without silicone or having polyorganosiloxane content less than the polyorganosiloxane-containing phase.
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21. An electrophotographic device comprising:
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an electrophotographic photoconductor;
a charging unit configured to charge a latent image carrier;
a light irradiating unit configured to irradiate light imagewisely onto the latent image carrier so as to form a latent electrostatic image thereon;
an image developing unit configured to develop the latent electrostatic image to a developed image; and
a transfer charger configured to transfer the developed image to a recording medium;
wherein the electrophotographic photoconductor comprises;
an electroconductive support; and
a photoconductive layer formed on the electroconductive support;
wherein an outermost layer of the photoconductor comprises an acryl-modified polyorganosiloxane comprising a) a main chain of a polyorganosiloxane; and
b) a graft chain of an acryl polymer without containing silicon;
wherein the acryl-modified polyorganosiloxane is prepared by emulsion graft copolymerizing of a polyorganosiloxane compound represented by the following formula (I) and a (meth)acrylic acid ester represented by the following formula (II) or a mixture of the (meth)acrylic acid ester and a monomer copolymerizable with the (meth)acrylic acid ester via emulsion graft copolymerization;
Formula (I) in the Formula (I), each of R1, R2 and R3 is a hydrocarbon group having 1 to 20 carbon atoms and R1, R2 and R3 may be identical or different, or be halogenated;
Y is an organic group containing either a radical reactive group or SH group or both of them;
each of Z1 and Z2 is a hydrogen atom, lower alkyl group or one represented by the following formula (n), and Z1 and Z2 may be identical or different;
m is a plus integer of 10,000 or less; and
n is an integer of 1 or more;
in the Formula (n) each of R4 and R5 is a hydrocarbon group or a halogenated hydrocarbon group having 1 to 20 carbon atoms and R4 and R5 may be identical or different; and
R6 is a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group, an organic group containing either a radical reactive group or SH group or both of them;
in the Formula (II);
R7 is a hydrogen atom or a methyl group; and
R8 is at least any one member selected from the group consisting of an alkyl group, alkoxy-substituted alkyl group, cyclo alkyl group and aryl group.
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22. A process cartridge comprising an electrophotographic photoconductor which comprises:
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an electroconductive support and a photoconductive layer thereon, the outermost layer of the photoconductive layer comprises an acryl-modified polyorganosiloxane comprising a) a main chain of a polyorganosiloxane; and
b) a graft chain of an acryl polymer without containing silicon;
wherein the acryl-modified polyorganosiloxane is prepared by emulsion graft copolymerizing of a polyorganosiloxane compound represented by the following formula (I) and a (meth) acrylic acid ester represented by the following formula (II) or a mixture of the (meth)acrylic acid ester and a monomer copolymerizable with the (meth)acrylic acid ester via emulsion graft copolymerization;
Formula (I) in the Formula (I), each of R1, R2 and R3 is a hydrocarbon group having 1 to 20 carbon atoms and R1, R2 and R3 may be identical or different, or be halogenated;
Y is an organic group containing either a radical reactive group or SH group or both of them;
each of Z1 and Z2 is a hydrogen atom, lower alkyl group or one represented by the following formula (n), and Z1 and Z2 may be identical or different;
m is a plus integer of 10,000 or less; and
n is an integer of 1 or more;
in the Formula (n) each of R4 and R5 is a hydrocarbon group or a halogenated hydrocarbon group having 1 to 20 carbon atoms and R4 and R5 may be identical or different; and
R6 is a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group, an organic group containing either a radical reactive group or SH group or both of them;
in the Formula (II);
R7 is a hydrogen atom or a methyl group; and
R8 is at least any one of an alkyl group, alkoxy-substituted alkyl group, cyclo alkyl group and aryl group.
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Specification