Natural gas liquefaction
First Claim
1. In a process for liquefying a natural gas stream containing methane and heavier hydrocarbon components wherein(a) said natural gas stream is cooled under pressure to condense at least a portion of it and form a condensed stream;
- and (b) said condensed stream is expanded to lower pressure to form said liquefied natural gas stream;
the improvement wherein (1) said natural gas stream is treated in one or more cooling steps;
(2) said cooled natural gas stream is divided into at least a first gaseous stream and a second gaseous stream;
(3) said first gaseous stream is cooled to condense substantially all of it and thereafter expanded to an intermediate pressure;
(4) said expanded substantially condensed first gaseous stream is directed in heat exchange relation with a more volatile vapor distillation stream which rises from fractionation stages of a distillation column and is thereby warmed;
(5) said second gaseous stream is expanded to said intermediate pressure;
(6) said warmed expanded first gaseous stream and said expanded second gaseous stream are directed into said distillation column wherein said streams are separated into said more volatile vapor distillation stream and a relatively less volatile fraction containing a major portion of said heavier hydrocarbon components;
(7) said more volatile vapor distillation stream is cooled by said expanded substantially condensed first gaseous stream sufficiently to partially condense it and is thereafter separated to form a volatile residue gas fraction containing a major portion of said methane and lighter components and a reflux stream;
(8) said reflux stream is directed into said distillation column as a top feed thereto; and
(9) said volatile residue gas fraction is cooled under pressure to condense at least a portion of it and form thereby said condensed stream.
5 Assignments
0 Petitions
Accused Products
Abstract
A process for liquefying natural gas in conjunction with producing a liquid stream containing predominantly hydrocarbons heavier than methane is disclosed. In the process, the natural gas stream to be liquefied is partially cooled, expanded to an intermediate pressure, and supplied to a distillation column. The bottom product from this distillation column preferentially contains the majority of any hydrocarbons heavier than methane that would otherwise reduce the purity of the liquefied natural gas. The residual gas stream from the distillation column is compressed to a higher intermediate pressure, cooled under pressure to condense it, and then expanded to low pressure to form the liquefied natural gas stream.
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Citations
78 Claims
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1. In a process for liquefying a natural gas stream containing methane and heavier hydrocarbon components wherein
(a) said natural gas stream is cooled under pressure to condense at least a portion of it and form a condensed stream; - and
(b) said condensed stream is expanded to lower pressure to form said liquefied natural gas stream;
the improvement wherein (1) said natural gas stream is treated in one or more cooling steps;
(2) said cooled natural gas stream is divided into at least a first gaseous stream and a second gaseous stream;
(3) said first gaseous stream is cooled to condense substantially all of it and thereafter expanded to an intermediate pressure;
(4) said expanded substantially condensed first gaseous stream is directed in heat exchange relation with a more volatile vapor distillation stream which rises from fractionation stages of a distillation column and is thereby warmed;
(5) said second gaseous stream is expanded to said intermediate pressure;
(6) said warmed expanded first gaseous stream and said expanded second gaseous stream are directed into said distillation column wherein said streams are separated into said more volatile vapor distillation stream and a relatively less volatile fraction containing a major portion of said heavier hydrocarbon components;
(7) said more volatile vapor distillation stream is cooled by said expanded substantially condensed first gaseous stream sufficiently to partially condense it and is thereafter separated to form a volatile residue gas fraction containing a major portion of said methane and lighter components and a reflux stream;
(8) said reflux stream is directed into said distillation column as a top feed thereto; and
(9) said volatile residue gas fraction is cooled under pressure to condense at least a portion of it and form thereby said condensed stream. - View Dependent Claims (6, 11, 16, 17, 18, 19, 20, 21, 22, 23)
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2. In a process for liquefying a natural gas stream containing methane and heavier hydrocarbon components wherein
(a) said natural gas stream is cooled under pressure to condense at least a portion of it and form a condensed stream; - and
(b) said condensed stream is expanded to lower pressure to form said liquefied natural gas stream;
the improvement wherein (1) said natural gas stream is treated in one or more cooling steps to partially condense it;
(2) said partially condensed natural gas stream is separated to provide thereby a vapor stream and a liquid stream;
(3) said vapor stream is divided into at least a first gaseous stream and a second gaseous stream;
(4) said first gaseous stream is cooled to condense substantially all of it and thereafter expanded to an intermediate pressure;
(5) said expanded substantially condensed first gaseous stream is directed in heat exchange relation with a more volatile vapor distillation stream which rises from fractionation stages of a distillation column and is thereby warmed;
(6) said second gaseous stream is expanded to said intermediate pressure;
(7) said liquid stream is expanded to said intermediate pressure;
(8) said warmed expanded first gaseous stream, said expanded second gaseous stream, and said expanded liquid stream are directed into said distillation column wherein said streams are separated into said more volatile vapor distillation stream and a relatively less volatile fraction containing a major portion of said heavier hydrocarbon components;
(9) said more volatile vapor distillation stream is cooled by said expanded substantially condensed first gaseous stream sufficiently to partially condense it and is thereafter separated to form a volatile residue gas fraction containing a major portion of said methane and lighter components and a reflux stream;
(10) said reflux stream is directed into said distillation column as a top feed thereto; and
(11) said volatile residue gas fraction is cooled under pressure to condense at least a portion of it and form thereby said condensed stream. - View Dependent Claims (7, 12)
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3. In a process for liquefying a natural gas stream containing methane and heavier hydrocarbon components wherein
(a) said natural gas stream is cooled under pressure to condense at least a portion of it and form a condensed stream; - and
(b) said condensed stream is expanded to lower pressure to form said liquefied natural gas stream;
the improvement wherein (1) said natural gas stream is treated in one or more cooling steps to partially condense it;
(2) said partially condensed natural gas stream is separated to provide thereby a vapor stream and a liquid stream;
(3) said vapor stream is divided into at least a first gaseous stream and a second gaseous stream;
(4) said first gaseous stream is combined with at least a portion of said liquid stream, forming thereby a combined stream;
(5) said combined stream is cooled to condense substantially all of it and thereafter expanded to an intermediate pressure;
(6) said expanded substantially condensed combined stream is directed in heat exchange relation with a more volatile vapor distillation stream which rises from fractionation stages of a distillation column and is thereby warmed;
(7) said second gaseous stream is expanded to said intermediate pressure;
(8) any remaining portion of said liquid stream is expanded to said intermediate pressure;
(9) said warmed expanded combined stream, said expanded second gaseous stream, and said expanded remaining portion of said liquid stream are directed into said distillation column wherein said streams are separated into said more volatile vapor distillation stream and a relatively less volatile fraction containing a major portion of said heavier hydrocarbon components;
(10) said more volatile vapor distillation stream is cooled by said expanded substantially condensed combined stream sufficiently to partially condense it and is thereafter separated to form a volatile residue gas fraction containing a major portion of said methane and lighter components and a reflux stream;
(11) said reflux stream is directed into said distillation column as a top feed thereto; and
(12) said volatile residue gas fraction is cooled under pressure to condense at least a portion of it and form thereby said condensed stream. - View Dependent Claims (8, 13)
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4. In a process for liquefying a natural gas stream containing methane and heavier hydrocarbon components wherein
(a) said natural gas stream is cooled under pressure to condense at least a portion of it and form a condensed stream; - and
(b) said condensed stream is expanded to lower pressure to form said liquefied natural gas stream;
the improvement wherein (1) said natural gas stream is treated in one or more cooling steps to partially condense it;
(2) said partially condensed natural gas stream is separated to provide thereby a vapor stream and a liquid stream;
(3) said vapor stream is divided into at least a first gaseous stream and a second gaseous stream;
(4) said first gaseous stream is cooled to condense substantially all of it and thereafter expanded to an intermediate pressure;
(5) said expanded substantially condensed first gaseous stream is directed in heat exchange relation with a more volatile vapor distillation stream which rises from fractionation stages of a distillation column and is thereby warmed;
(6) said second gaseous stream is expanded to said intermediate pressure;
(7) said liquid stream is cooled and thereafter divided into at least a first portion and a second portion;
(8) said first portion is expanded to said intermediate pressure and thereafter warmed;
(9) said second portion is expanded to said intermediate pressure;
(10) said warmed expanded first gaseous stream, said expanded second gaseous stream, said warmed expanded first portion, and said expanded second portion are directed into said distillation column wherein said streams are separated into said more volatile vapor distillation stream and a relatively less volatile fraction containing a major portion of said heavier hydrocarbon components;
(11) said more volatile vapor distillation stream is cooled by said expanded substantially condensed first gaseous stream sufficiently to partially condense it and is thereafter separated to form a volatile residue gas fraction containing a major portion of said methane and lighter components and a reflux stream;
(12) said reflux stream is directed into said distillation column as a top feed thereto; and
(13) said volatile residue gas fraction is cooled under pressure to condense at least a portion of it and form thereby said condensed stream. - View Dependent Claims (9, 14)
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5. In a process for liquefying a natural gas stream containing methane and heavier hydrocarbon components wherein
(a) said natural gas stream is cooled under pressure to condense at least a portion of it and form a condensed stream; - and
(b) said condensed stream is expanded to lower pressure to form said liquefied natural gas stream;
the improvement wherein (1) said natural gas stream is treated in one or more cooling steps to partially condense it;
(2) said partially condensed natural gas stream is separated to provide thereby a vapor stream and a liquid stream;
(3) said vapor stream is divided into at least a first gaseous stream and a second gaseous stream;
(4) said first gaseous stream is cooled to condense substantially all of it;
(5) said liquid stream is cooled and thereafter divided into at least a first portion and a second portion;
(6) said first portion is expanded to an intermediate pressure and thereafter warmed;
(7) said second portion is combined with said substantially condensed first gaseous stream, forming thereby a combined stream, whereupon said combined stream is expanded to said intermediate pressure;
(8) said expanded combined stream is directed in heat exchange relation with a more volatile vapor distillation stream which rises from fractionation stages of a distillation column and is thereby warmed;
(9) said second gaseous stream is expanded to said intermediate pressure;
(10) said warmed expanded combined stream, said expanded second gaseous stream, and said warmed expanded first portion are directed into said distillation column wherein said streams are separated into said more volatile vapor distillation stream and a relatively less volatile fraction containing a major portion of said heavier hydrocarbon components;
(11) said more volatile vapor distillation stream is cooled by said expanded combined stream sufficiently to partially condense it and is thereafter separated to form a volatile residue gas fraction containing a major portion of said methane and lighter components and a reflux stream;
(12) said reflux stream is directed into said distillation column as a top feed thereto; and
(13) said volatile residue gas fraction is cooled under pressure to condense at least a portion of it and form thereby said condensed stream. - View Dependent Claims (10, 15)
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24. An apparatus for the liquefaction of a natural gas stream containing methane and heavier hydrocarbon components, which includes
(1) one or more first heat exchange means to receive said natural gas stream and cool it under pressure; -
(2) dividing means connected to said first heat exchange means to receive said cooled natural gas stream and divide it into at least a first gaseous stream and a second gaseous stream;
(3) second heat exchange means connected to said dividing means to receive said first gaseous stream and to cool it sufficiently to substantially condense it;
(4) first expansion means connected to said second heat exchange means to receive said substantially condensed first gaseous stream and expand it to an intermediate pressure;
(5) third heat exchange means connected to said first expansion means to receive said expanded substantially condensed first gaseous stream and heat it, said third heat exchange means being further connected to a distillation column to receive a more volatile vapor distillation stream rising from fractionation stages of said distillation column and cool it sufficiently to partially condense it;
(6) second expansion means connected to said dividing means to receive said second gaseous stream and expand it to said intermediate pressure;
(7) said distillation column being further connected to said third heat exchange means and said second expansion means to receive said heated expanded first gaseous stream and said expanded second gaseous stream, with said distillation column adapted to separate said streams into said more volatile vapor distillation stream and a relatively less volatile fraction containing a major portion of said heavier hydrocarbon components;
(8) separation means connected to said third heat exchange means to receive said cooled partially condensed distillation stream and separate it into a volatile residue gas fraction containing a major portion of said methane and lighter components and a reflux stream, said separation means being further connected to said distillation column to direct said reflux stream into said distillation column as a top feed thereto;
(9) fourth heat exchange means connected to said separation means to receive said volatile residue gas fraction, with said fourth heat exchange means adapted to cool said volatile residue gas fraction under pressure to condense at least a portion of it and form thereby a condensed stream;
(10) third expansion means connected to said fourth heat exchange means to receive said condensed stream and expand it to lower pressure to form said liquefied natural gas stream; and
(11) control means adapted to regulate the quantities and temperatures of said feed streams to said distillation column to maintain the overhead temperature of said distillation column at a temperature whereby the major portion of said heavier hydrocarbon components is recovered in said relatively less volatile fraction. - View Dependent Claims (29, 34, 39, 42, 44, 46, 49, 51, 53, 56, 58, 62, 64, 66, 69, 71, 75, 77)
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25. An apparatus for the liquefaction of a natural gas stream containing methane and heavier hydrocarbon components, which includes
(1) one or more first heat exchange means to receive said natural gas stream and cool it under pressure sufficiently to partially condense it; -
(2) first separation means connected to said first heat exchange means to receive said partially condensed natural gas stream and separate it into a vapor stream and a liquid stream;
(3) dividing means connected to said first separation means to receive said vapor stream and divide it into at least a first gaseous stream and a second gaseous stream;
(4) second heat exchange means connected to said dividing means to receive said first gaseous stream and to cool it sufficiently to substantially condense it;
(5) first expansion means connected to said second heat exchange means to receive said substantially condensed first gaseous stream and expand it to an intermediate pressure;
(6) third heat exchange means connected to said first expansion means to receive said expanded substantially condensed first gaseous stream and heat it, said third heat exchange means being further connected to a distillation column to receive a more volatile vapor distillation stream rising from fractionation stages of said distillation column and cool it sufficiently to partially condense it;
(7) second expansion means connected to said dividing means to receive said second gaseous stream and expand it to said intermediate pressure;
(8) third expansion means connected to said first separation means to receive said liquid stream and expand it to said intermediate pressure;
(9) said distillation column being further connected to said third heat exchange means, said second expansion means, and said third expansion means to receive said heated expanded first gaseous stream, said expanded second gaseous stream, and said expanded liquid stream, with said distillation column adapted to separate said streams into said more volatile vapor distillation stream and a relatively less volatile fraction containing a major portion of said heavier hydrocarbon components;
(10) second separation means connected to said third heat exchange means to receive said cooled partially condensed distillation stream and separate it into a volatile residue gas fraction containing a major portion of said methane and lighter components and a reflux stream, said second separation means being further connected to said distillation column to direct said reflux stream into said distillation column as a top feed thereto;
(11) fourth heat exchange means connected to said second separation means to receive said volatile residue gas fraction, with said fourth heat exchange means adapted to cool said volatile residue gas fraction under pressure to condense at least a portion of it and form thereby a condensed stream;
(12) fourth expansion means connected to said fourth heat exchange means to receive said condensed stream and expand it to lower pressure to form said liquefied natural gas stream; and
(13) control means adapted to regulate the quantities and temperatures of said feed streams to said distillation column to maintain the overhead temperature of said distillation column at a temperature whereby the major portion of said heavier hydrocarbon components is recovered in said relatively less volatile fraction. - View Dependent Claims (30, 35, 40, 47, 54, 60, 67, 73)
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26. An apparatus for the liquefaction of a natural gas stream containing methane and heavier hydrocarbon components, which includes
(1) one or more first heat exchange means to receive said natural gas stream and cool it under pressure sufficiently to partially condense it; -
(2) first separation means connected to said first heat exchange means to receive said partially condensed natural gas stream and separate it into a vapor stream and a liquid stream;
(3) dividing means connected to said first separation means to receive said vapor stream and divide it into at least a first gaseous stream and a second gaseous stream;
(4) combining means connected to said dividing means and to said first separation means to receive said first gaseous stream and at least a portion of said liquid stream and form thereby a combined stream;
(5) second heat exchange means connected to said combining means to receive said combined stream and to cool it sufficiently to substantially condense it;
(6) first expansion means connected to said second heat exchange means to receive said substantially condensed combined stream and expand it to an intermediate pressure;
(7) third heat exchange means connected to said first expansion means to receive said expanded substantially condensed combined stream and heat it, said third heat exchange means being further connected to a distillation column to receive a more volatile vapor distillation stream rising from fractionation stages of said distillation column and cool it sufficiently to partially condense it;
(8) second expansion means connected to said dividing means to receive said second gaseous stream and expand it to said intermediate pressure;
(9) third expansion means connected to said first separation means to receive any remaining portion of said liquid stream and expand it to said intermediate pressure;
(10) said distillation column being further connected to said third heat exchange means, said second expansion means, and said third expansion means to receive said heated expanded combined stream, said expanded second gaseous stream, and said expanded remaining portion of said liquid stream, with said distillation column adapted to separate said streams into said more volatile vapor distillation stream and a relatively less volatile fraction containing a major portion of said heavier hydrocarbon components;
(11) second separation means connected to said third heat exchange means to receive said cooled partially condensed distillation stream and separate it into a volatile residue gas fraction containing a major portion of said methane and lighter components and a reflux stream, said second separation means being further connected to said distillation column to direct said reflux stream into said distillation column as a top feed thereto;
(12) fourth heat exchange means connected to said second separation means to receive said volatile residue gas fraction, with said fourth heat exchange means adapted to cool said volatile residue gas fraction under pressure to condense at least a portion of it and form thereby a condensed stream;
(13) fourth expansion means connected to said fourth heat exchange means to receive said condensed stream and expand it to lower pressure to form said liquefied natural gas stream; and
(14) control means adapted to regulate the quantities and temperatures of said feed streams to said distillation column to maintain the overhead temperature of said distillation column at a temperature whereby the major portion of said heavier hydrocarbon components is recovered in said relatively less volatile fraction. - View Dependent Claims (31, 36)
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27. An apparatus for the liquefaction of a natural gas stream containing methane and heavier hydrocarbon components, which includes
(1) one or more first heat exchange means to receive said natural gas stream and cool it under pressure sufficiently to partially condense it; -
(2) first separation means connected to said first heat exchange means to receive said partially condensed natural gas stream and separate it into a vapor stream and a liquid stream;
(3) second heat exchange means connected to said first separation means to receive said liquid stream and cool it;
(4) first dividing means connected to said second heat exchange means to receive said cooled liquid stream and divide it into at least a first portion and a second portion;
(5) first expansion means connected to said first dividing means to receive said first portion and expand it to an intermediate pressure, said first expansion means being further connected to supply said expanded first portion to said second heat exchange means, thereby heating said expanded first portion while cooling said liquid stream;
(6) second dividing means connected to said first separation means to receive said vapor stream and divide it into at least a first gaseous stream and a second gaseous stream;
(7) third heat exchange means connected to said second dividing means to receive said first gaseous stream and to cool it sufficiently to substantially condense it;
(8) second expansion means connected to said third heat exchange means to receive said substantially condensed first gaseous stream and expand it to said intermediate pressure;
(9) third expansion means connected to said second dividing means to receive said second gaseous stream and expand it to said intermediate pressure;
(10) fourth expansion means connected to said first dividing means to receive said second portion and expand it to said intermediate pressure;
(11) fourth heat exchange means connected to said second expansion means to receive said expanded substantially condensed first gaseous stream and heat it, said fourth heat exchange means being further connected to a distillation column to receive a more volatile vapor distillation stream rising from fractionation stages of said distillation column and cool it sufficiently to partially condense it;
(12) said distillation column being further connected to said fourth heat exchange means, said third expansion means, said fourth expansion means, and said second heat exchange means to receive said heated expanded first gaseous stream, said expanded second gaseous stream, said expanded second portion, and said heated expanded first portion, with said distillation column adapted to separate said streams into said more volatile vapor distillation stream and a relatively less volatile fraction containing a major portion of said heavier hydrocarbon components;
(13) second separation means connected to said fourth heat exchange means to receive said cooled partially condensed distillation stream and separate it into a volatile residue gas fraction containing a major portion of said methane and lighter components and a reflux stream, said second separation means being further connected to said distillation column to direct said reflux stream into said distillation column as a top feed thereto;
(14) fifth heat exchange means connected to said second separation means to receive said volatile residue gas fraction, with said fifth heat exchange means adapted to cool said volatile residue gas fraction under pressure to condense at least a portion of it and form thereby a condensed stream;
(15) fifth expansion means connected to said fifth heat exchange means to receive said condensed stream and expand it to lower pressure to form said liquefied natural gas stream; and
(16) control means adapted to regulate the quantities and temperatures of said feed streams to said distillation column to maintain the overhead temperature of said distillation column at a temperature whereby the major portion of said heavier hydrocarbon components is recovered in said relatively less volatile fraction. - View Dependent Claims (32, 37, 41, 43, 45, 48, 50, 52, 55, 57, 59, 61, 63, 65, 68, 70, 72, 74, 76, 78)
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28. An apparatus for the liquefaction of a natural gas stream containing methane and heavier hydrocarbon components, which includes
(1) one or more first heat exchange means to receive said natural gas stream and cool it under pressure sufficiently to partially condense it; -
(2) first separation means connected to said first heat exchange means to receive said partially condensed natural gas stream and separate it into a vapor stream and a liquid stream;
(3) second heat exchange means connected to said first separation means to receive said liquid stream and cool it;
(4) first dividing means connected to said second heat exchange means to receive said cooled liquid stream and divide it into at least a first portion and a second portion;
(5) first expansion means connected to said first dividing means to receive said first portion and expand it to an intermediate pressure, said first expansion means being further connected to supply said expanded first portion to said second heat exchange means, thereby heating said expanded first portion while cooling said liquid stream;
(6) second dividing means connected to said first separation means to receive said vapor stream and divide it into at least a first gaseous stream and a second gaseous stream;
(7) third heat exchange means connected to said second dividing means to receive said first gaseous stream and to cool it sufficiently to substantially condense it;
(8) combining means connected to said third heat exchange means and to said first dividing means to receive said substantially condensed first gaseous stream and said second portion and form thereby a combined stream;
(9) second expansion means connected to said combining means to receive said combined stream and expand it to said intermediate pressure;
(10) third expansion means connected to said second dividing means to receive said second gaseous stream and expand it to said intermediate pressure;
(11) fourth heat exchange means connected to said second expansion means to receive said expanded combined stream and heat it, said fourth heat exchange means being further connected to a distillation column to receive a more volatile vapor distillation stream rising from fractionation stages of said distillation column and cool it sufficiently to partially condense it;
(12) said distillation column being further connected to said fourth heat exchange means, said third expansion means, and said second heat exchange means to receive said heated expanded combined stream, said expanded second gaseous stream, and said heated expanded first portion, with said distillation column adapted to separate said streams into said more volatile vapor distillation stream and a relatively less volatile fraction containing a major portion of said heavier hydrocarbon components;
(13) second separation means connected to said fourth heat exchange means to receive said cooled partially condensed distillation stream and separate it into a volatile residue gas fraction containing a major portion of said methane and lighter components and a reflux stream, said second separation means being further connected to said distillation column to direct said reflux stream into said distillation column as a top feed thereto;
(14) fifth heat exchange means connected to said second separation means to receive said volatile residue gas fraction, with said fifth heat exchange means adapted to cool said volatile residue gas fraction under pressure to condense at least a portion of it and form thereby a condensed stream;
(15) fourth expansion means connected to said first fifth exchange means to receive said condensed stream and expand it to lower pressure to form said liquefied natural gas stream; and
(16) control means adapted to regulate the quantities and temperatures of said feed streams to said distillation column to maintain the overhead temperature of said distillation column at a temperature whereby the major portion of said heavier hydrocarbon components is recovered in said relatively less volatile fraction. - View Dependent Claims (33, 38)
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Specification