Thermo-electrically cooled surface-enhanced raman spectroscopy sensor system to detect volatile organic compounds

• US 6,947,132 B1
• Filed: 04/14/2003
• Issued: 09/20/2005
• Est. Priority Date: 06/14/2000
• Status: Expired due to Fees

• Current Assignee: the united states of america as represented by the secretary of the navy
• Original Assignee: the united states of america as represented by the secretary of the navy
• Inventors: Andrews, John M., Boss, Pamela A., Anderson, Gregory Wayne, Lieberman, Stephen H.
• Primary Examiner(s): Smith, Zandra V.
• Application Number:
  US10/413,188
• Time in Patent Office: 890 Days
• Field of Search: 356/301
• US Class Current: 356/301
• CPC Class Codes: G01J 3/0286 Constructional arrangements for compensating for fluctuations caused by temperature, humidity or pressure, or using cooling or temperature stabilization of parts of the device; Controlling the atmosphere inside a spectrometer, e.g. vacuum
• CPC Class Codes: G01J 3/44 Raman spectrometry; Scattering spectrometry ; Fluorescence spectrometry
• CPC Class Codes: G01N 21/658 enhancement Raman, e.g. surface plasmons
• CPC Class Codes: G01N 2201/1211 for temperature

Abstract

A thermoelectrically cooled surface-enhanced Raman spectrometer sensor system and method for monitoring of volatile organic compounds in gas, liquid, and soil environments. The sensor system comprises a means for providing an inert gas, a thermal desorption tube containing an adsorbate, and a sample chamber with a SERS structure. For liquid and soil environments, the sensor system also comprises a manifold having a semipermeable membrane for separating moisture from an analyte. An optical module mounted to the sample chamber directs an optical excitation signal for irradiating the SERS structure and receives a SERS optical emissions signal. Such optical emissions signal may be detected by a spectroanalysis system and correlated to a particular analyte by a control processor, which generates an alert signal containing a message that the presence of analyte has been detected. The control processor may also activate warning device, such as an audible siren or a visual alarm.

Claims

1. A thermo-electrically cooled surface enhanced Raman spectroscopy sensor system, comprising:

at least one means for providing an inert gas;

at least one thermal desorption tube coupled to the at least one means for providing an inert gas, wherein the at least one tube contains an adsorbate for collecting a gas sample and wherein the gas sample and the inert gas mix to create a gas mixture;

a sample chamber coupled to the at least one thermal desorption tube for receiving the gas mixture;

a SERS structure positioned in the sample chamber; and

an optical module mounted to the sample chamber for directing an optical excitation signal to irradiate the SERS structure and for receiving a SERS optical emissions signal.

2. The sensor system of claim 1 wherein the optical emissions signal represents an analyte in contact with the SERS structure, wherein the analyte is selected from the group that includes benzene, toluene, ethylbenzene, MTBE, TNT, RDX, cocaine, heroin, saran, xylene, mustard gas, and chlorinated solvents.

3. The sensor system of claim 1 further comprising a multiplexer disposed between the at least one thermal desorption tube and the sample chamber.

4. The sensor system of claim 1 further comprising a manifold, disposed between the means for providing an inert gas and the thermal desorption tube, wherein the manifold has a semipermeable membrane for separating moisture from an analyte and wherein the analyte and the inert gas mix to create the gas sample.

5. The sensor system of claim 1 further comprising a means for generating the optical excitation signal to irradiate the SERS structure, operably coupled to the sample chamber.

6. The sensor system of claim 5 wherein the means for generating an optical excitation signal to irradiate the SERS structure includes a laser.

7. The sensor system of claim 1 further comprising a means for detecting the SERS optical emissions signal, generated in response to the SERS structure being irradiated by the optical excitation signal when an analyte is in contact with the SERS structure.

8. The sensor system of claim 7 wherein the means for detecting a SERS optical emissions signal includes a spectrometer for detecting the spectral characteristics of the optical emissions signal and a means for recording the spectral characteristics.

9. The sensor system of claim 7 further comprising a control processor coupled to the means for detecting the SERS optical emissions signal, wherein the control processor:

positions the SERS structure in the sample chamber;

records and analyzes the SERS optical emissions signal; and

generates an alert signal when an analyte is in contact with the SERS structure.

10. The sensor system of claim 9 further comprising a remote processor for receiving the alert signal generated from the control processor.

11. The sensor system of claim 1 further comprising a thermoelectric cooler coupled to the SERS structure, for cooling the SERS structure.

12. The sensor system of claim 11 further comprising a heat exchanger coupled to the thermoelectric cooler, for removing heat energy from the sample chamber.

13. The sensor system of claim 1 further comprising a staging apparatus coupled to the SERS structure, for positioning the SERS structure at selected coordinates.

14. The sensor system of claim 1 wherein the inert gas includes diatomic nitrogen.

15. A method for identifying an analyte of interest, comprising the steps of:

collecting a gas sample in a thermal desorption tube;

mixing the gas sample with an inert gas to create a gas mixture;

contacting a SERS structure with the gas mixture;

irradiating the SERS structure with optical excitation energy for stimulating a SERS optical emission signal if the gas sample contains an analyte that is in contact with the SERS structure;

determining the identity of the analyte from the SERS optical emission signal; and

generating an alert signal when an analyte is in contact with the SERS structure.

16. The method of claim 15 further comprising the step of collecting the gas sample through a manifold having a semipermeable membrane.

17. The method of claim 15 wherein the gas sample is obtained from a gaseous environment.

18. The method of claim 15 wherein the gas sample is obtained from a liquid environment.

19. The method of claim 15 wherein the gas sample is obtained from a soil environment.