Antireflection film, polarizing plate, and apparatus for displaying an image

• US 6,950,236 B2
• Filed: 04/09/2002
• Issued: 09/27/2005
• Est. Priority Date: 04/10/2001
• Status: Active Grant

• Current Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Original Assignee: Fuji Photo Film Co Limited (Fujifilm Holdings Corporation)
• Inventors: Nakamura, Kazuhiro, Hokazono, Hirohisa
• Primary Examiner(s): Assaf, Fayez G.
• Application Number:
  US10/473,420
• Publication Number:
  US 20040114248A1
• Time in Patent Office: 1,267 Days
• Field of Search: 359/586, 359/587, 359/582, 359/589, 359/603, 359/883, 428/212, 428/220, 349/137
• US Class Current: 359/586
• CPC Class Codes: G02B 1/111 using layers comprising organic materials
• CPC Class Codes: G02B 1/116 including electrically conducting layers
• CPC Class Codes: G02B 1/14 Protective coatings, e.g. hard coatings
• CPC Class Codes: G02F 1/133502 Antiglare, refractive index matching layers
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree

Abstract

An antireflection film having a low reflectance and giving non-tinged reflected light with a low cost, which comprises: a transparent substrate; and a low-refractive layer having a lower refractive index than said transparent substrate, wherein the antireflection film has an average specular reflectance of 0.5% or less at an incidence angle of 5° in a wavelength region of from 450 to 650 nm, and, when CIE standard illuminant D₆₅ in a wavelength region of from 380 to 780 nm is incident on the antireflection film at an incidence angle of 5°, the regular reflection light has a color having a* and b* values in a ranges specified by −7≦a*≦7 and −10*≦b*≦10 in the CIE 1976 L*a*b* color space.

Claims

1. An antireflection film comprising:

a transparent substrate; and

a low-refractive layer having a lower refractive index than said transparent substrate,

wherein the antireflection film has an average specular reflectance of 0.5% or less at an incidence angle of 5°

in a wavelength region of from 450 to 650 nm, and, when CIE standard illuminant D₆₅ in a wavelength region of from 380 to 780 nm is incident on the antireflection film at an incidence angle of 5°

, the regular reflection light has a color having a* and b* values in a ranges specified by −

7≦

a*≦

7 and −

10≦

b*≦

10 in the CIE 1976 L*a*b* color space.

2. The antireflection film according to claim 1, wherein said regular reflection light has a* and b* values in the ranges specified by 0≦

a*≦

5 and −

10≦

b*≦

10.

3. The antireflection film according to claim 1, wherein said average specular reflectance at an incidence angle of 5°

in a wavelength region of from 450 to 650 nm is 0.4% or less.

4. The antireflection film according to claim 1, wherein said average specular reflectance at an incidence angle of 5°

in a wavelength region of from 450 to 650 nm is 0.3% or less.

5. The antireflection film according to claim 1, which further comprises an adhesive layer which is in contact with the lower side of said low-refractive layer, wherein a surface of said adhesive layer has a center-line average roughness (Ra) of 0.001 to 0.030 μ

m.

6. The antireflection film according to claim 5, wherein the surface of said adhesive layer has a center-line average roughness (Ra) of 0.005 to 0.020 μ

m.

7. The antireflection film according to claim 5, which further comprises a hard coat layer having a thickness of 1 μ

m or greater between said adhesive layer and said transparent substrate, wherein said adhesive layer is an adhesive and high-refractive layer having a higher refractive index than said transparent substrate.

8. The antireflection film according to claim 7, which further comprises a medium-refractive layer between said adhesive and high-refractive layer and said hard coat layer, wherein said medium-refractive layer has a refractive index higher than that of said low-refractive layer and lower than that of said adhesive and high-refractive layer.

9. The antireflection film according to claim 5, wherein said low-refractive layer includes a fluorine-containing compound capable of crosslinking by one of a heat and an irradiation with an ionizing radiation, and said low-refractive layer has:

a refractive index of 1.35 to 1.49;

a kinetic friction coefficient of 0.03 to 0.15; and

a contact angle of 90 to 120°

with water.

10. A polarizing plate having the antireflection film described in claim 5 on at least one side thereof.

11. An apparatus for displaying an image, comprising the antireflection film described in claim 5.

12. The apparatus for displaying an image according to claim 11, wherein the antireflection film is provided so that the low-refractive layer is the outermost layer of the display.

13. The antireflection film according to claim 1, wherein a layer constituting said antireflection film is a layer formed by applying a coating composition comprising a film-forming solute and at least one solvent, drying the coating film to remove the solvent, and curing the coating film by applying at least one of a heat and an ionizing radiation.

14. The antireflection film according to claim 13, which has a substantially three-layered structure comprising a medium-refractive layer, a high-refractive layer, and said low-refractive layer, in the order from the substrate side, wherein the high-refractive layer has a higher refractive index than said transparent substrate, and the medium-refractive layer has a refractive index higher than that of said transparent substrate and lower than that of said high-refractive layer.

15. The antireflection film according to claim 14, wherein said medium-refractive layer, said high-refractive layer, and said low-refractive layer satisfy formulae (I), (II), and (III), respectively, at a designed wavelength λ

(=500 nm);

lλ

/4×

0.80<

n₁d₁<

lλ

/4×

1.00 

 

(I)

mλ

/4×

0.75<

n₂d₂<

mλ

/4×

0.95 

 

(II)

nλ

/4×

0.95<

n₃d₃<

nλ

/4×

1.05 

 

(III)

wherein l is 1;

n₁ is the refractive index of the medium-refractive layer;

d₁ is the thickness (nm) of the medium-refractive layer;

m is 2;

n₂ is the refractive index of the high-refractive layer;

d₂ is the thickness (nm) of the high-refractive layer;

n is 1;

n₃ is the refractive index of the low-refractive layer;

d₃ is the thickness (nm) of the low-refractive layer.

16. The antireflection film according to claim 13, wherein said low-refractive layer comprises a fluorine-containing resin capable of curing by at least one of a heat and an irradiation of an ionizing radiation.

17. The antireflection film according to claim 16, wherein said low-refractive layer has a kinetic friction coefficient of 0.15 or smaller and a contact angle of 100°

or greater with water.

18. The antireflection film according to claim 13, wherein said high-refractive layer is a layer formed by:

applying a coating composition comprising;

ultrafine particles containing-at least one metal oxide selected from oxides of titanium, zirconium, indium, zinc, tin and antimony;

an anionic dispersant;

a curing resin having at least three-functional polymerizable group;

a polymerization initiator; and

a solvent,

drying the coating film to remove the solvent; and

curing the coating film by applying at least one of a heat and an ionizing radiation.

19. The antireflection film according to claim 1, which further comprises at least one hard coat layer between said low-refractive layer and said transparent substrate.

20. The antireflection film according to claim 1, which further comprises at least one forward-scattering layer between said low-refractive layer and said transparent substrate.

21. The antireflection film according to claim 1, wherein, when CIE standard illuminant D₆₅ in a wavelength region of from 380 to 780 nm is incident on the antireflection film at an incidence angle of 5°

, the regular reflection light shows a color difference of less than 2 in terms of a Δ

Eab* value in the CIE 1976 L*a*b* color space between two arbitrary points 10 cm apart in one of the machine direction (MD) and the transverse direction (TD).

22. A polarizing plate comprising a polarizer and at least two surface protective films, in which each of the at least two protective films is adhered to both sides of said polarizer, wherein at least one of said protective films is the antireflection film described in claim 1, said antireflection film having been immersed in an alkali solution at least once to saponify the back surface of said antireflection film after the formation of the low-refractive layer.

23. A polarizing plate according to claim 22, wherein the surface protective film other than the antireflection film is an optical compensation film having, on the side opposite to said polarizer, an optical compensation layer comprising an optically an isotropic layer, said optically anisotropic layer being a negative birefringence layer comprising a compound having a discotic structural unit, in which the disc of said discotic structural unit tilts with respect to the plane of said protective film at an angle varying in the thickness direction of said optically anisotropic layer.

24. A transmission, reflection or semi-transmission type liquid crystal display in a twisted nematic mode, a supertwisted nematic mode, a vertical alignment mode, an in-plane switching mode or an optical compensated bend cell mode, which comprises at least one polarizing plate described in claim 22.

25. A transmission or semi-transmission type liquid crystal display, which comprises at least one polarizing plate described in claim 22, wherein a polarized light splitting film having a polarized light selecting layer is disposed between a backlight and a polarizing plate which is disposed on the opposite side to the viewer'"'"'s side.

26. A surface protective plate for an organic electroluminescence display, which comprises the polarizing plate described in claim 22 and a λ

/4 plate, wherein the λ

/4 plate is disposed on a transparent protective film opposite to the antireflection film side.

27. A polarizing plate comprising a polarizer and at least two surface protective films, in which each of at least two protective films is adhered to both sides of said polarizer, wherein at least one of said protective films is the antireflection film described in claim 1, said antireflection film being prepared by:

coating the back side of the antireflection film opposite to the side on which the low-refractive layer is to be formed with an alkali solution, either before or after formation of said low-refractive layer;

heating said coated antireflection film, followed by at least one of washing with water and a neutralization thereby to saponify only the back side of said antireflection film.

28. The antireflection film according to claim 1, wherein said transparent substrate is one of a polyethylene terephthalate film, a polyethylene naphthalate film and a cellulose triacetate film.