Sorbents and methods for the removal of mercury from combustion gases

• US 6,953,494 B2
• Filed: 05/06/2003
• Issued: 10/11/2005
• Est. Priority Date: 05/06/2002
• Status: Expired due to Term

• Current Assignee: Albemarle Amendments LLC (Albemarle Corporation)
• Original Assignee: Sidney G. Nelson Jr
• Inventors: Nelson, Sidney G. Jr.
• Primary Examiner(s): Spitzer, Robert H.
• Application Number:
  US10/430,577
• Publication Number:
  US 20040003716A1
• Time in Patent Office: 889 Days
• Field of Search: 95/58, 95/62, 951/34, 959/01, 961/08, 210/688, 423/210, 502/417, 502/432
• US Class Current: 95/134
• CPC Class Codes: B01D 2253/102 Carbon
• CPC Class Codes: B01D 2253/304 Linear dimensions, e.g. particle shape, diameter
• CPC Class Codes: B01D 2257/602 Mercury or mercury compounds
• CPC Class Codes: B01D 2258/00 Sources of waste gases
• CPC Class Codes: B01D 2259/40001 Methods relating to additional, e.g. intermediate, treatment of process gas
• CPC Class Codes: B01D 53/02 by adsorption, e.g. preparative gas chromatography solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01
• CPC Class Codes: B01D 53/04 with stationary adsorbents B01D53/025 takes precedence
• CPC Class Codes: B01D 53/64 Heavy metals or compounds thereof, e.g. mercury
• CPC Class Codes: B03C 3/013 Conditioning by chemical additives, e.g. with SO3
• CPC Class Codes: B03C 3/017 Combinations of electrostatic separation with other processes, not otherwise provided for
• CPC Class Codes: Y10S 95/901 Activated carbon

Abstract

A method for removing mercury and mercury-containing compounds from a combustion gas in an exhaust gas system has the steps of providing a mercury sorbent; injecting the mercury sorbent into a stream of the mercury-containing combustion gas for a sufficient time to allow at least an effective amount of the mercury and mercury-containing compounds in the combustion gas to adsorb onto the mercury sorbent, and collecting and removing the mercury sorbent from the combustion gas stream. The mercury sorbent is prepared by treating a carbonaceous substrate with an effective amount of a bromine-containing gas, especially one containing elemental bromine or hydrogen bromide, for a time sufficient to increase the ability of the carbonaceous substrate to adsorb mercury and mercury-containing compounds. The points of injecting and collecting and removing the mercury sorbent may be varied, depending upon the exact configuration of the exhaust gas system.

Claims

1. A method for removing mercury and mercury-containing compounds from a combustion gas in an exhaust gas system, comprising the steps of:

providing a mercury sorbent that has been prepared by treating a carbonaceous substrate with an effective amount of a bromine-containing gas for a sufficient time to increase the ability of the carbonaceous substrate to adsorb mercury and mercury-containing compounds;

injecting the mercury sorbent into a stream of the mercury-containing combustion gas for a sufficient time to allow an effective amount of the mercury and mercury-containing compounds in the combustion gas to adsorb onto the mercury sorbent; and

collecting and removing the mercury sorbent from the combustion gas stream.

2. The method of claim 1, wherein:

the bromine-containing gas comprises elemental bromine.

3. The method of claim 2, wherein:

the carbonaceous substrate comprises activated carbon.

4. The method of claim 3, wherein:

the carbonaceous substrate or mercury sorbent is reduced to a particle size distribution that is fluidizable in the combustion gas stream.

5. The method of claim 2, wherein:

the carbonaceous substrate or mercury sorbent is reduced to a particle size distribution that is fluidizable in the combustion gas stream.

6. The method of claim 1, wherein:

the bromine-containing gas comprises hydrogen bromide.

7. The method of claim 6, wherein:

the carbonaceous substrate comprises activated carbon.

8. The method of claim 7, wherein:

the carbonaceous substrate or mercury sorbent is reduced to a particle size distribution that is fluidizable in the combustion gas stream.

9. The method of claim 6, wherein:

the carbonaceous substrate or mercury sorbent is reduced to a particle size distribution that is fluidizable in the combustion gas stream.

10. The method of claim 1, wherein:

the carbonaceous substrate comprises activated carbon.

11. The method of claim 10, wherein:

the carbonaceous substrate or mercury sorbent is reduced to a particle size distribution that is fluidizable in the combustion gas stream.

12. The method of claim 1, wherein:

the preparation of the mercury sorbent is done at a temperature greater than 60°

C.

13. The method of claim 12, wherein:

the preparation of the mercury sorbent is done at a temperature greater than about 150°

C.

14. The method of claim 13, wherein:

the carbonaceous substrate or mercury sorbent is reduced to a particle size distribution that is fluidizable in the combustion gas stream.

15. The method of claim 12, wherein:

the carbonaceous substrate or mercury sorbent is reduced to a particle size distribution that is fluidizable in the combustion gas stream.

16. The method of claim 1, wherein:

the carbonaceous substrate or mercury sorbent is reduced to a particle size distribution that is fluidizable in the combustion gas stream.

17. The method of claim 1, wherein:

the bromine-containing gas comprises elemental bromine,

the carbonaceous substrate comprises activated carbon,

the preparation of the mercury sorbent is done at a temperature greater than 60°

C., and

the carbonaceous substrate or mercury sorbent is reduced to a particle size distribution fluidizable in the combustion gas stream.

18. The method of claim 1, wherein the adsorbing of the mercury and mercury-containing compounds in the combustion gas onto the mercury sorbent takes place at a temperature between about 300°

C. and about 400°

C.

19. A process for manufacturing a mercury sorbent, comprising:

providing a carbonaceous substrate;

providing a bromine-containing gas; and

contacting the carbonaceous substrate with the bromine-containing gas for a sufficient time to increase the mercury adsorbing ability of the carbonaceous substrate;

to provide a brominated mercury sorbent capable of adsorbing mercury in a high temperature combustion gas.

20. The process of claim 19, wherein:

the bromine-containing gas comprises elemental bromine.

21. The process of claim 19, wherein:

the bromine-containing gas comprises hydrogen bromide.

22. The process of claim 19, wherein:

the carbonaceous substrate is activated carbon.

23. The process of claim 19, wherein:

the contacting step occurs at a temperature greater than 60°

C.

24. The process of claim 23, wherein:

the contacting step occurs at a temperature greater than about 150°

C.

25. The process of claim 19, further comprising the step of:

reducing the particle size distribution of the carbonaceous substrate or mercury sorbent to a distribution fluidizable in the ductwork of a combustion gas stream.

26. The process of claim 25, wherein:

the bromine-containing gas comprises elemental bromine,

the carbonaceous substrate comprises activated carbon, and

the contacting step occurs at a temperature above 60°

C.

27. A mercury sorbent prepared according to the process of claim 26.

28. The process of claim 19, wherein the brominated mercury sorbent is brominated to less than about 3 weight percent bromine.

29. The process of claim 19, wherein the brominated mercury sorbent is capable of adsorbing mercury in a combustion gas at a temperature greater than 150°

C.