Method and apparatus for analyzing mixtures of gases
First Claim
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1. A method for calculating the concentration of at least two individual analyte gas components in a multi-component gas mixture having a temperature of about 400°
- C. or more, comprising;
(a) providing within the gas mixture an array of at least three chemo/electro-active materials, each chemo/electro-active material having a different electrical response characteristic upon exposure to each of the individual analyte gas components than each of the other chemo/electro-active materials, wherein at least one chemo/electro-active material, when at a temperature of about 400°
C. or more, (i) has an electrical resistivity in the range of about 1 ohm-cm to about 105 ohm-cm, and (ii) exhibits a change in electrical resistance of at least about 0.1 percent upon exposure of the material to an analyte gas component, as compared to the resistance before exposure;
(b) heating the array to a temperature above 500°
C.;
(c) determining an electrical response of each chemo/electro-active material upon exposure of the array to the unseparated components of the gas mixture;
(d) inputting the electrical responses of the chemo/electro-active materials, but not a baseline response value, a comparison response value or a reference gas value, to a pattern recognition technique; and
(e) calculating the concentration of each of the individual analyte gas components from the inputs in step (d).
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Abstract
Disclosed herein is a method and apparatus for analyzing, sensing and measuring the concentrations of various gases, including NOx, hydrocarbons, carbon monoxide and oxygen, in a multi-component gas system using chemical sensors and chemical sensor arrays. The sensors and sensor arrays use chemo/electro-active materials to analyze and detect the presence of gases.
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Citations
102 Claims
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1. A method for calculating the concentration of at least two individual analyte gas components in a multi-component gas mixture having a temperature of about 400°
- C. or more, comprising;
(a) providing within the gas mixture an array of at least three chemo/electro-active materials, each chemo/electro-active material having a different electrical response characteristic upon exposure to each of the individual analyte gas components than each of the other chemo/electro-active materials, wherein at least one chemo/electro-active material, when at a temperature of about 400°
C. or more,(i) has an electrical resistivity in the range of about 1 ohm-cm to about 105 ohm-cm, and (ii) exhibits a change in electrical resistance of at least about 0.1 percent upon exposure of the material to an analyte gas component, as compared to the resistance before exposure;
(b) heating the array to a temperature above 500°
C.;
(c) determining an electrical response of each chemo/electro-active material upon exposure of the array to the unseparated components of the gas mixture;
(d) inputting the electrical responses of the chemo/electro-active materials, but not a baseline response value, a comparison response value or a reference gas value, to a pattern recognition technique; and
(e) calculating the concentration of each of the individual analyte gas components from the inputs in step (d). - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14)
- C. or more, comprising;
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15. A method for analyzing at least one individual gas component in a multi-component gas mixture, comprising:
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(a) providing an array of at least two chemo/electro-active materials, each chemo/electro-active material having a different electrical response characteristic upon exposure at a selected temperature to the individual gas component than each of the other chemo/electro-active materials, the electrical response characteristic of each material being quantifiable as a value, wherein the response value of at least one material is constant or varies by no more than about twenty percent during exposure of the material to an individual gas component at the selected temperature for a period of at least about one minute;
(b) heating the array to a temperature above 500°
C.;
(c) determining the electrical response value of each chemo/electro-active material upon exposure of the array to the gas mixture;
(d) inputting the electrical responses of the chemo/electro-active materials, but not a baseline response value, a comparison response value or a reference gas value, to a pattern recognition technique; and
(e) performing an analysis of the individual gas component from the inputs in step (d). - View Dependent Claims (16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32)
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33. A method for directly sensing gas components in a multi-component gas system, comprising
(a) exposing a chemical sensor comprising an array of at least two chemo/electro-active materials to a multi-component gas system; -
(b) heating the array to a temperature above 500°
C.;
(c) detecting a response;
(d) directly measuring the response of each chemo/electro-active material;
(e) inputting the electrical responses of the chemo/electro-active materials, but not a baseline response value, a cornparison response value or a reference gas value, to a pattern recognition technique; and
(f) detecting the presence of and/or calculating the concentration of one or more individual analyte gas components in the system from the inputs in step (e). - View Dependent Claims (34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51)
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52. A method for directly sensing gas components in a multi-component gas system, comprising
(a) exposing a chemical sensor comprising an array of at least two chemo/electro-active materials to a multi-component gas system; -
(b) heating the array to a temperature above 500°
C.;
(c) detecting a response;
(d) directly measuring the response of each chemo/electro-active material;
(e) inputting only the electrical responses of the chemo/electro-active materials to a pattern recognition technique; and
(f) detecting the presence of and/or calculating the concentration of one or more individual analyte gas components in the system from the inputs in step (e). - View Dependent Claims (53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70)
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71. A method for calculating the concentration of at least two individual analyte gas components in a multi-component gas mixture having a temperature of about 400°
- C. or more, comprising;
(a) providing within the gas mixture an array of at least three chemo/electro-active materials, each chemo/electro-active material having a different electrical response characteristic upon exposure to each of the individual analyte gas components than each of the other chemo/electro-active materials, wherein at least one chemo/electro-active material, when at a temperature of about 400°
C. or more,(i) has an electrical resistivity in the range of about 1 ohm-cm to about 105 ohm-cm, and (ii) exhibits a change in electrical resistance of at least about 0.1 percent upon exposure of the material to an analyte gas component, as compared to the resistance before exposure;
(b) heating the array to a temperature above 500°
C.;
(c) determining an electrical response of each chemo/electro-active material upon exposure of the array to the unseparated components of the gas mixture;
(d) inputting only the electrical responses of the chemo/electro-active materials to a pattern recognition technique; and
(e) calculating the concentration of each of the individual analyte gas components from the inputs in step (d). - View Dependent Claims (72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84)
- C. or more, comprising;
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85. A method for analyzing at least one individual gas component in a multi-component gas mixture, comprising:
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(a) providing an array of at least two chemo/electro-active materials, each chemo/electro-active material having a different electrical response characteristic upon exposure at a selected temperature to the individual gas component than each of the other chemo/electro-active materials, the electrical response characteristic of each material being quantifiable as a value, wherein the response value of at least one material is constant or varies by no more than about twenty percent during exposure of the material to an individual gas component at the selected temperature for a period of at least about one minute;
(b) heating the array to a temperature above 500°
C.;
(c) determining the electrical response value of each chemo/electro-active material upon exposure of the array to the gas mixture;
(d) inputting only the electrical responses of the chemo/electro-active materials to a pattern recognition technique; and
(e) performing an analysis of the individual gas component from the inputs in step (d). - View Dependent Claims (86, 87, 88, 89, 90, 91, 92, 93, 94, 95, 96, 97, 98, 99, 100, 101, 102)
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Specification