Preparation of adsorbents from organic fertilizer and mineral oil and their application for removal of acidic gases from sulfur containing wet gas streams

• US 6,962,616 B1
• Filed: 08/08/2003
• Issued: 11/08/2005
• Est. Priority Date: 08/08/2003
• Status: Active Grant

• Current Assignee: City College of New York
• Original Assignee: City College of New York
• Inventors: Bahryeyev, Andriy, Bandosz, Teresa J.
• Primary Examiner(s): Spitzer, Robert H.
• Application Number:
  US10/638,291
• Time in Patent Office: 823 Days
• Field of Search: 951/29, 951/36, 951/37, 951/41, 959/00, 961/08, 55D/IG.5, 423/230, 423/244.01, 423/244.03, 502/423, 502/424, 502/428, 502/430
• US Class Current: 95/129
• CPC Class Codes: B01D 2253/20 Organic adsorbents
• CPC Class Codes: B01D 2257/304 Hydrogen sulfide
• CPC Class Codes: B01D 53/02 by adsorption, e.g. preparative gas chromatography solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01
• CPC Class Codes: B01J 20/22 comprising organic material
• CPC Class Codes: B01J 20/30 Processes for preparing, regenerating, or reactivating
• CPC Class Codes: B01J 20/3078 Thermal treatment, e.g. calcining or pyrolizing
• CPC Class Codes: B01J 2220/4887 Residues, wastes, e.g. garbage, municipal or industrial sludges, compost, animal manure; fly-ashes
• CPC Class Codes: Y10S 55/05 Methods of making filter
• CPC Class Codes: Y10S 95/90 Solid sorbent

Abstract

A method of making an adsorbent which includes: a) thermally drying dewatered sewage sludge to form granulated organic fertilizer; b) treating the fertilizer with mineral oil; and c) pyrolyzing the treated fertilizer at temperatures between about 600° C. and about 1000° C. The disclosure is also directed to adsorbents made by this method and to the processes of removing acidic gas or gases from wet gas streams by putting an adsorbent in contact with the wet gas stream and allowing the adsorbent to adsorb the acidic gas or gases.

Claims

1. A process for removing one or more acidic gas or gases from wet gas streams comprising:

(a) forming an adsorbent by thermally drying dewatered sewage sludge to form granulated organic fertilizer;

(b) treating the fertilizer with mineral oil;

(c) pyrolyzing the treated fertilizer at a pyrolysis temperature between about 600°

C. and about 1000°

C.;

(d) contacting the adsorbent with a wet gas stream; and

(e) allowing the adsorbent to adsorb the acidic gas or gases.

2. The process of claim 1, wherein the acidic gases are selected from the group consisting of hydrogen sulfide, methyl mercaptan, sulfur dioxide, hydrogen cyanide, nitrogen dioxide, and mixtures thereof.

3. The process of claim 1, wherein the acidic gas comprises hydrogen sulfide which reacts with inorganic matter to be oxidized to sulfur dioxide or elemental sulfur or salt forms thereof.

4. The process of claim 1, wherein the acidic gas comprises sulfur dioxide.

5. The process of claim 1, wherein the wet gas stream is effluent from a sewage treatment plant, gaseous fuel, or gases from hydrothermal vents.

6. The process of claim 1, wherein the pyrolysis temperature is between about 800°

C. and about 950°

C.

7. The process of claim 1 further comprising:

(f) regenerating the adsorbent by heating the adsorbent to a heating temperature.

8. The process of claim 7, wherein the heating temperature is between about 300°

C. and about 500°

C.

9. The process of claim 1, wherein the mineral oil is selected from light mineral oil, heavy mineral oil, natural mineral oil, synthetic mineral oil, spent motor oil, and combinations thereof.

18. The process of claim 1, wherein the mineral oil comprises a C₁₄–

C₁₈ petroleum hydrocarbon product, optionally containing one or more heteroatoms selected from sulfur, oxygen and nitrogen, having a boiling point of about 270°

C. to about 360°

C.

10. A process for making an adsorbent, comprising:

(a) thermally drying dewatered sewage sludge to form granulated organic fertilizer;

(b) treating the fertilizer with mineral oil;

(c) pyrolyzing the treated fertilizer at a pyrolysis temperature between about 600°

C. and about 1000°

C.

11. The process of claim 10, wherein step (b) comprises treating the granulated organic fertilizer with between about 5 and about 30 wt % mineral oil.

12. The process of claim 11, wherein step (b) is conducted at a temperature of between about 20°

C. and about 100°

C. for a period of time between about 1 hour and about 24 hours.

13. The process of claim 10, wherein the pyrolysis temperature is maintained for a period of time between about 0.5 and about 4 hours.

14. The process of claim 10, wherein the pyrolysis temperature is between about 800°

C. and about 950°

C. and the pyrolysis temperature is maintained for a period of time between about 0.5 and about 2 hours.

15. The process of claim 10, wherein step (c) comprises pyrolyzing the treated fertilizer at a heating rate of between about 1 and about 50°

C./minute.

16. The process of claim 10, wherein step (c) comprises pyrolyzing the treated fertilizer at a heating rate of between about 10 and about 30°

C./minute.

17. The process of claim 10, wherein the pyrolysis is continued until no flame is observed from the combustion of exhaust gases.

19. The process of claim 10, wherein the mineral oil is selected from light mineral oil, heavy mineral oil, natural mineral oil, synthetic mineral oil, spent motor oil, and combinations thereof.

20. An adsorbent formed by the process of claim 10.