Thermal-sprayed metallic conformal coatings used as heat spreaders

• US 6,965,071 B2
• Filed: 11/01/2002
• Issued: 11/15/2005
• Est. Priority Date: 05/10/2001
• Status: Active Grant

• Current Assignee: Parker Intangibles LLC (Parker-Hannifin Corporation)
• Original Assignee: Parker-Hannifin Corporation
• Inventors: de Sorgo, Miksa, Liu, Peter W., Rodriguez, Christian V., Oppenheim, Scott M., Lionetta, William G., Watchko, George R., Gagnon, Matthew T.
• Primary Examiner(s): Ngo, Hung V.
• Application Number:
  US10/287,490
• Publication Number:
  US 20030066672A1
• Time in Patent Office: 1,110 Days
• Field of Search: 174/35.R, 174/35.MS, 174/35.GC, 361/816, 361/818, 361/718
• US Class Current: 174/377
• CPC Class Codes: C23C 30/00 Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process C23C26/00, C23C28/00 take precedence
• CPC Class Codes: C23C 4/00 Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge build-up welding B23K, e.g. B23K5/18, B23K9/04
• CPC Class Codes: C23C 4/06 Metallic material
• CPC Class Codes: C23C 4/08 containing only metal elements C23C4/073 takes precedence
• CPC Class Codes: C23C 4/12 characterised by the method of spraying
• CPC Class Codes: C23C 4/131 Wire arc spraying
• CPC Class Codes: H01L 2924/00 Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
• CPC Class Codes: H01L 2924/0002 Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
• CPC Class Codes: H05K 7/20454 with a conformable or flexible structure compensating for irregularities, e.g. cushion bags, thermal paste
• CPC Class Codes: H05K 9/0015 Gaskets or seals
• CPC Class Codes: H05K 9/0045 being rigid plastic containers having a coating of shielding material
• CPC Class Codes: H05K 9/0086 comprising a single discontinuous metallic layer on an electrically insulating supporting structure, e.g. metal grid, perforated metal foil, film, aggregated flakes, sintering

Abstract

Heat dissipation and electromagnetic interference (EMI) shielding for an electronic device having an enclosure. An interior surface of the enclosure is covered with a conformal metallic layer which, as disposed in thermal adjacency with one or more heat-generating electronic components or other sources contained within the enclosure, may provide both thermal dissipation and EMI shielding for the device. The layer may be sprayed onto the interior surface in a molten state and solidified to form a self-adherent coating.

Claims

1. A method of dissipating heat from an electronic device having an enclosure and at least one heat-generating source received within the enclosure, the enclosure having one or more parts, and at least one of the parts having an exterior surface and an opposing interior surface, the method comprising the steps of:

(a) covering at least a portion of the interior surface of said one of the enclosure parts with a conformal metallic layer by the steps of;

(i) providing a feed material comprising a metal or metal alloy;

(ii) heating said feed material of step (i) into a molten state;

(iii) atomizing said feed material of step (ii) while in said molten state;

(iv) spraying the atomized feed material of step (ii) while in said molten state on said portion of the interior surface of said one of the enclosure part to form a self-adherent coating of said metal thereon; and

(v) solidifying said coating of step (iii) to form said conformal metallic layer; and

(b) disposing the conformal metallic layer covered on said one of the enclosure parts and the source in heat transfer adjacency with each other.

2. The method of claim 1 wherein the metallic layer comprises tin, nickel, copper, zinc, aluminum, silver, or an alloy thereof.

3. The method of claim 1 wherein said feed material is heated in step (a)(ii) by generating an electric arc within an arc zone, and passing said feed material through said arc zone.

4. The method of claim 3 wherein:

said feed material is atomized in step (a)(iii) by a gas stream passed with said feed material through said arc zone; and

said feed material is sprayed in step (a)(iv) by entrainment within said gas stream.

5. The method of claim 3 wherein:

said feed material is provided as a first wire and a second wire, each said wire being passed with the other said wire through said arc zone; and

wherein said arc is generated by applying an electrical potential difference between said first and said second wire.

17. The assembly of claim 1 wherein the metallic layer has an electrical surface resistance of not greater than about 0.10 Ω

/sq.

20. The assembly of claim 1 wherein said shielding layer of step (e) has a thickness of between about 0.5-100 mils (0.0125-2.5 mm).

21. The assembly of claim 1 which consists for the source essentially of the conformal metallic layer and the thermal interface material.

22. The assembly of claim 1 wherein the thermal interface material comprises an admixture of a resin and a filler.

23. The assembly of claim 1 where the heat-generating source is an electronic component.

24. The assembly of claim 23 where the electronic component is mounted on a circuit board.

25. The assembly of claim 1 wherein said housing part is formed of a plastic.

26. The assembly of claim 25 wherein said plastic is polycarbonate, acrylonitrile-butadiene-styrene, polysulfone, acrylic, polyvinyl chloride, polyphenylene ether, polystyrene, polyamide, nylon, polyolefin, poly(ether ether ketone), polyimide, polyetherimide, polybutylene terephthalate, polyethylene terephthalate, fluoropolymer, polyester, acetal, liquid crystal polymer, polymethylacrylate, polyurethane, polyphenylene oxide, polystyrene, epoxy, phenolic, or a copolymer or blend thereof.

27. The assembly of claim 1 wherein the metallic layer has a thermal conductivity of at least about 5 W/m-K.

28. The assembly of claim 1 wherein the metallic layer exhibits an EMI shielding effectiveness of at least about 60 dB substantially over a frequency range of between about 10 MHz and about 2 GHz.

6. A method of dissipating heat from an electronic device having an enclosure and at least one heat-generating source received within the enclosure, the enclosure having one or more parts, and at least one of the parts having an exterior surface and an opposing interior surface, the method comprising the steps of:

(a) covering at least a portion of the interior surface of said one of the enclosure parts with a conformal metallic layer; and

(b) disposing the conformal metallic layer covered on said one of the enclosure parts and the source in heat transfer adjacency with each other such that a gap is defined between the conformal metallic layer and the source,

wherein before or after step (b), a thermal interface material is interposed between the conformal metallic layer covered on said one the enclosure parts and the source, said thermal interface material at least partially filling said gap.

7. The method of claim 6 wherein the thermal interface material comprises an admixture of a resin and a filler.

8. The method of claim 6 wherein said housing part is formed of a plastic.

9. The method of claim 8 wherein said plastic is polycarbonate, acrylonitrile-butadiene-styrene, polysulfone, acrylic, polyvinyl chloride, polyphenylene ether, polystyrene, polyamide, nylon, polyolefin, poly(ether ether ketone), polyimide, polyetherimide, polybutylene terephthalate, polyethylene terephthalate, fluoropolymer, polyester, acetal, liquid crystal polymer, polymethylacrylate, polyurethane, polyphenylene oxide, polystyrene, epoxy, phenolic, or a copolymer or blend thereof.

10. The method of claim 6 wherein the metallic layer has a thermal conductivity of at least about 5 W/m-K.

11. The method of claim 6 wherein the metallic layer exhibits an EMI shielding effectiveness of at least about 60 dB substantially over a frequency range of between about 10 MHz and about 2 GHz.

12. The method of claim 6 wherein the metallic layer has an electrical surface resistance of not greater than about 0.10 Ω

/sq.

13. The method of claim 6 wherein said shielding layer of step (e) has a thickness of between about 0.5-100 mils (0.0125-2.5 mm).

14. The method of claim 6 where the heat-generating source is an electronic component.

15. The method of claim 14 where the electronic component is mounted on a circuit board.

16. A thermal management assembly for an electronic device having an enclosure and at least one heat-generating source received within the enclosure, the enclosure having one or more parts, and at least one of the parts having an exterior surface and an opposing interior surface, the assembly comprising:

a conformal metallic layer covering at least a portion of the interior surface of said one of the enclosure parts, and the layer being disposed in heat transfer adjacency with the source received within the enclosure to define a gap therebetween; and

a thermal interface material interposed between the conformal metallic layer and the source, said thermal interface material at least partially filling said gap.

18. The assembly of claim 16 wherein the metallic layer comprises a self-adherent coating of a metal or metal alloy.

19. The assembly of claim 18 wherein the metallic layer comprises tin, nickel, copper, zinc, aluminum, silver, or an alloy thereof.