Apparatus and process for producing (meth)acrylic acid

• US 6,966,973 B2
• Filed: 07/01/2002
• Issued: 11/22/2005
• Est. Priority Date: 12/28/1999
• Status: Expired due to Term

• Current Assignee: Nippon Shokubai Company Limited
• Original Assignee: Nippon Shokubai Company Limited
• Inventors: Ueoka, Masatoshi, Sakamoto, Kazuhiko, Matsumoto, Yukihiro, Nakahara, Sei, Sanada, Kenji
• Primary Examiner(s): Manoharan, Virginia
• Application Number:
  US10/186,569
• Publication Number:
  US 20020165407A1
• Time in Patent Office: 1,240 Days
• Field of Search: 202/267.1, 202/163, 203/86, 159/DIG.15, 562/600, 422/240, 165/133, 165/134
• US Class Current: 202/163
• CPC Class Codes: B01D 3/225 Dual-flow sieve trays
• CPC Class Codes: B01D 3/322 Reboiler specifications
• CPC Class Codes: B01J 19/02 Apparatus characterised by being constructed of material selected for its chemically-resistant properties
• CPC Class Codes: B01J 2219/00101 Reflux columns
• CPC Class Codes: B01J 2219/0277 Metal based
• CPC Class Codes: C07C 51/252 of propene, butenes, acrolein or methacrolein
• CPC Class Codes: C07C 51/44 by distillation
• CPC Class Codes: C07C 57/04 Acrylic acid; Methacrylic acid
• CPC Class Codes: Y10S 159/15 Special material

Abstract

The present invention provides an apparatus for producing (meth)acrylic acid and a process for producing (meth)acrylic acid with this apparatus wherein the apparatus enables the production of (meth)acrylic acid stably for a long period of time by effectively inhibiting the polymerization of (meth)acrylic acid in its production process (for example, in a reboiler). At least a part of the apparatus is made of a nickel-chromium-iron alloy with a molybdenum content of 3 to 20 mass %, but not including 3 mass %, or with a molybdenum content of 1 to 4 mass % and a copper content of 0.5 to 7 mass %.

Claims

1. An apparatus for producing (meth) acrylic acid by catalytic gas phase oxidation, with said apparatus being selected from the group consisting of a reactor, an absorber, a stripping column, an extraction column, a distillation column, their fittings including heat exchangers, and reboilers off distillation columns, wherein said apparatus comprises a part that comes into contact with (meth)acrylic acid, and wherein said part comprises:

(A) an alloy (A) comprising nickel, chromium and iron, with said alloy (A) having a molybdenum content of more than 3 mass % and not more than 20 mass %, with said alloy (A) minimizing polymerization of (meth)acrylic acid during production of (meth)acrylic acid;

or

(B) an alloy (B) comprising nickel, chromium and iron, with said alloy (B) having a molybdenum content of 1 to 4 mass % and a copper content of 0.5 to 7 mass %, with said alloy (B) minimizing polymerization of (meth)acrylic acid during production of (meth)acrylic acid.

2. An apparatus according to claim 1, wherein the apparatus comprises the distillation column.

3. An apparatus according to claim 1, wherein the apparatus comprises the reboiler of the distillation column.

4. An apparatus according to claim 1, of which at least a part of an inner surface of the apparatus has an Ry, as prescribed in JIS B0601, of not more than 12.5, where Ry stands for maximum height of profile and where JIS stands for Japanese industrial Standards.

5. An apparatus according to claim 1, wherein the alloy (A) further comprises copper in an amount of 0 to 7 mass %, tungsten in an amount of 0 to 5 mass %, and nitrogen in an amount of 0 to 0.5 mass %, and wherein said nickel is present in an amount of 10 to 65 mass %, said chromium is present in an amount of 10 to 35 mass %, and said iron is present in an amount of 4 to 70 mass %.

6. An apparatus according to claim 1, wherein the alloy (B) further comprises tungsten in an amount of 0 to 5 mass %, and nitrogen in an amount of 0 to 0.5 mass %, and wherein said nickel is present in an amount of 10 to 65 mass %, said chromium is present in an amount of 10 to 30 mass %, and said iron is present in an amount of 4 to 70 mass %.

7. An apparatus according to claim 1, wherein said apparatus further includes SUS 316 stainless steel comprising molybdenum in an amount of 2.0 to 3.0 mass % and copper in an amount of 0 mass %.

8. An apparatus according to claim 1, wherein said apparatus is the absorber.

9. An apparatus according to claim 1, wherein said apparatus is the heat exchanger.

10. A distillation column reboiler for distilling (meth)acrylic acid, comprising a portion coming into contact with (meth)acrylic acid, with said portion comprising:

(A) an alloy (A) comprising nickel, chromium, and iron, with said alloy (A) having a molybdenum content of more than 3 mass % and not more than 20 mass %;

or

(B) an alloy (B) comprising nickel, chromium, and iron, with said alloy (B) having a molybdenum content of 1 to 4 mass % and a copper content of 0.5 to 7 mass %.

11. An apparatus according to claim 10, wherein the alloy (A) further comprises copper in an amount of 0 to 7 mass %, tungsten in an amount of 0 to 5 mass %, and nitrogen in an amount of 0 to 0.5 mass %, and wherein said nickel is present in an amount of 10 to 65 mass %, said chromium is present in an amount of 10 to 35 mass %, and said iron is present in an amount of 4 to 70 mass %.

12. An apparatus according to claim 10, wherein the alloy (B) further comprises tungsten in an amount of 0 to 5 mass %, and nitrogen in an amount of 0 to 0.5 mass %, and wherein said nickel is present in an amount of 10 to 65 mass %, said chromium is present in an amount of 10 to 30 mass %, and said iron is present in an amount of 4 to 70 mass %.

13. An apparatus according to claim 10, wherein said apparatus further includes SUS 316 stainless steel comprising molybdenum in an amount of 2.0 to 3.0 mass % and copper in an amount of 0 mass %.

14. An apparatus for producing (meth)acrylic acid by catalytic gas phase oxidation, comprising a portion coming into contact with (meth)acrylic acid, with the portion comprising:

(A) an alloy (A) comprising nickel, chromium, and iron, with said alloy (A) having a molybdenum content of more than 3 mass % and not more than 20 mass %;

or

(B) alloy (B) comprising nickel, chromium, and iron, with said alloy (B) having a molybdenum content of 1 to 4 mass % and a copper content of 0.5 to 7 mass %.

15. An apparatus according to claim 14, wherein the alloy (A) further comprises copper in an amount of 0 to 7 mass %, tungsten in an amount of 0 to 5 mass %, and nitrogen in an amount of 0 to 0.5 mass %, and wherein said nickel is present in an amount of 10 to 65 mass %, said chromium is present in an amount of 10 to 35 mass %, and said iron is present in an amount of 4 to 70 mass %.

16. An apparatus according to claim 14, wherein the alloy (B) further comprises tungsten in an amount of 0 to 5 mass %, and nitrogen in an amount of 0 to 0.5 mass %, and wherein said nickel is present in an amount of 10 to 65 mass %, said chromium is present in an amount of 10 to 30 mass %, and said iron is present in an amount of 4 to 70 mass %.

17. An apparatus according to claim 14, wherein said apparatus further includes SUS 316 stainless steel comprising molybdenum in an amount of 2.0 to 3.0 mass % and copper in an amount of 0 mass %.