Method for the removal of mercury from a gas stream

• US 6,974,564 B2
• Filed: 01/23/2002
• Issued: 12/13/2005
• Est. Priority Date: 01/26/2001
• Status: Expired due to Term

• Current Assignee: Minplus Holding BV
• Original Assignee: B. V. Cdem Holland
• Inventors: Voogt, Nicolaas, Biermann, Joseph Jan
• Primary Examiner(s): Silverman, Stanley S.
• Assistant Examiner(s): Strickland, Jonas N.
• Application Number:
  US10/149,946
• Publication Number:
  US 20030103882A1
• Time in Patent Office: 1,420 Days
• Field of Search: 423/210, 502/411, 502/414
• US Class Current: 423/210
• CPC Class Codes: B01D 53/02 by adsorption, e.g. preparative gas chromatography solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01
• CPC Class Codes: B01D 53/64 Heavy metals or compounds thereof, e.g. mercury
• CPC Class Codes: B01J 20/041 Oxides or hydroxides
• CPC Class Codes: B01J 20/043 Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
• CPC Class Codes: B01J 20/12 Naturally occurring clays or bleaching earth
• CPC Class Codes: B01J 20/16 Alumino-silicates B01J20/12 takes precedence
• CPC Class Codes: B01J 20/3078 Thermal treatment, e.g. calcining or pyrolizing
• CPC Class Codes: B01J 2220/42 Materials comprising a mixture of inorganic materials materials coated or impregnated on a carrier B01J20/32
• CPC Class Codes: B01J 2220/4831 having been subjected to further processing, e.g. paper, cellulose pulp

Abstract

The present invention relates to a method for the removal of mercury from a gas stream. The method is characterized in that at a temperature above 170° C. the gas stream is contacted with a sorbent that as the active component is comprised of a mixture of substantially silica-alumina compounds and/or calcium compounds. According to a preference, the sorbent is kaolin, that may or may not be in the dehydrated form of meta-kaolin and is optionally obtained by thermal conversion of a material chosen from paper waste or residue from the paper industry. By this method it is possible to remove mercury at temperatures higher than room temperature.

The invention also relates to a method for the removal of mercury from a gas stream, wherein the gas stream is contacted with a sorbent at a temperature above 50° C., which sorbent comprises as active substance a mixture of substantially silica-alumina compounds and/or calcium compounds, as well as with an oxidator. The invention also relates to a mercury-comprising sorbent obtained by this method and products manufactured therewith.

Claims

1. A method for the removal of mercury from a gas stream, characterized in that at a temperature above 230°

C. the gas stream is contacted with a sorbent that as the active component is comprised of a mixture of substantially silica-alumina compounds and calcium compounds for the removal of mercury from the gas stream.

2. A method according to claim 1, characterized in that the sorbent comprises kaolin, that may or may not be in the dehydrated form of meta-kaolin.

3. A method according to claim 1, characterized in that the calcium compounds comprise calcium carbonate and/or calcium oxide.

4. A method according to claim 3, wherein the calcium compounds comprise 60-70% calcium carbonate and 40-30% calcium oxide.

5. A method according to claim 1, characterized in that the sorbent is obtained by thermal conversion of a material chosen from 1, paper waste and 2, residue from paper production.

6. A method according to claim 1, further comprising the step of activating the sorbent by means of an oxidator chosen from, sulphate compounds, peroxides or chloride compounds.

7. A method according to claim 6, characterized in that the activation of the sorbent and the oxidator is carried out prior to contacting the sorbent with the gas stream to be cleaned.

8. A method according to claim 7, characterized in that after activation of the sorbent, the oxidator is removed.

9. A method according to claim 6, characterized in that the oxidator and the sorbent are mixed together and are added to the gas stream to be cleaned as a mixture.

10. A method according to claim 6, characterized in that the oxidator is added earlier to the gas stream, upstream from the sorbent.

11. A method according to claim 6, characterized in that a chlorine compound is used as the oxidator.

12. A method according to claim 11, wherein calcium hypochlorite is used as the oxidator.

13. A method according to claim 6, characterized in that during sorption the temperature is higher than 50°

C.

14. A method according to claim 13, wherein the temperature during sorption is higher than 400°

C.

15. A method according to claim 1, characterized in that the mercury is present in the metallic form.

16. A sorbent, characterized in that it comprises mercury adsorbed thereto, obtained by a method according to claim 1.

17. A sorbent according to claim 16, characterized in that up to temperatures of more than 900°

C. the mercury is irreversibly bound to the sorbent.

18. A binding agent using the mercury-comprising sorbent according to claim 16 as hydraulic or pozzolanic compound.

19. A molded product obtained by using a sorbent according to claim 16.

20. A method according to claim 1, wherein the temperature during sorption is higher than 550°

C.

21. A method of improving a sorbent for the removal of mercury from a gas stream, characterized in that the same comprises steps of activating a compound comprised of a mixture of substantially silica-alumina compounds and calcium compounds, with an oxidator wherein the sorbent contacts a gas stream at a temperature above 230°

C. for the removal of mercury from the gas stream.