Microorganism-removing filter medium having high isoelectric material and low melt index binder

• US 6,989,101 B2
• Filed: 04/04/2003
• Issued: 01/24/2006
• Est. Priority Date: 04/04/2003
• Status: Active Grant

• Current Assignee: Colorox Company
• Original Assignee: Clorox Company
• Inventors: Rinker, Edward B., Cumberland, Scott L., Enriquez, Carlos
• Primary Examiner(s): Hopkins, Robert A.
• Application Number:
  US10/407,506
• Publication Number:
  US 20040195180A1
• Time in Patent Office: 1,026 Days
• Field of Search: 210/660, 210/764, 422/28
• US Class Current: 210/660
• CPC Class Codes: B01D 2239/0407 comprising particulate additives, e.g. adsorbents apparatus incorporating gas filtering material B01D46/0036
• CPC Class Codes: B01D 2239/0442 Antimicrobial, antibacterial, antifungal additives apparatus incorporating such gas filtering material B01D46/0028
• CPC Class Codes: B01D 2239/086 Binders between particles or fibres
• CPC Class Codes: B01D 2239/1216 Pore size
• CPC Class Codes: B01D 2239/1291 Other parameters
• CPC Class Codes: B01D 39/2062 Bonded, e.g. activated carbon blocks
• CPC Class Codes: Y02W 10/37 using solar energy

Abstract

A filter medium capable of removing microorganisms from a fluid such as water. The filter medium includes particles of activated carbon, particles of a substantially insoluble inorganic material having an isoelectric point greater than the fluid being filtered. A low melt index binder, preferably with a melt index of less than about 1 gram per 10 minutes, binds the particles of activated carbon and particles of inorganic material, such that the binder will become tacky at elevated temperatures without becoming sufficiently liquid to substantially wet the particles of activated carbon and inorganic material.

Claims

1. A filter medium capable of removing microorganisms from a fluid, comprising:

particles of activated carbon;

particles of a substantially insoluble inorganic material having an isoelectric point greater than a pH of a fluid being filtered, the particles of inorganic material mixed together with the particles of activated carbon; and

a binder for binding the particles of activated carbon and particles of inorganic material, the binder having a melt index of less than about 1 gram per 10 minutes as determined by ASTM D1238 at 190 degrees C. and 15 kilograms load.

2. A filter medium as recited in claim 1, wherein the inorganic material is a magnesium containing material.

3. A filter medium as recited in claim 2, wherein the inorganic material is magnesium hydroxide.

4. A filter medium as recited in claim 1, wherein the inorganic material has an isoelectric point greater than about 9 pH.

5. A filter medium as recited in claim 1, wherein the inorganic material has an isoelectric point greater than about 10 pH.

6. A filter medium as recited in claim 1, wherein the inorganic material is present in an amount between about 25 weight percent to about 45 weight percent of the total weight of the filter medium.

7. A filter medium as recited in claim 1, wherein the binder is an ultra high molecular weight polymer having a molecular weight greater than about 4 million.

8. A filter medium as recited in claim 1, wherein the binder is ultra high molecular weight polyethylene.

9. A filter medium as recited in claim 1, wherein the melt index of the binder is less than about 0.1 grams per 10 minutes as determined by ASTM D 1238 at 190 degrees C. and 15 kilograms load.

10. A filter medium as recited in claim 1, wherein the binder is present in an amount between about 20 weight percent to about 35 weight percent of the total weight of the filter medium.

11. A filter medium as recited in claim 1, wherein 75 grams of the filter medium performs a greater than 1×

10⁴ plaque forming units/milliliter reduction of viruses after 100 gallons of water passes through the filter medium.

12. A filter medium as recited in claim 1, wherein the filter medium is cylindrically shaped with an outer diameter of less than about 4 inches and a maximum length between ends of the filter medium of less than about 3 inches.

13. A filter medium as recited in claim 12, wherein the filter medium performs a greater than 1×

10⁴ plaque forming units/milliliter reduction of viruses after 100 gallons of water passes through the filter medium.

14. A filter medium as recited in claim 1, wherein a mean pore size of pores formed by the particles and binder is between about 0.01 micron and about 10 microns.

15. A filter medium as recited in claim 1, wherein a mean pore size of pores formed by the particles and binder is between about 0.1 micron and about 1 microns.

16. A filter medium as recited in claim 1, further comprising at least one additional adsorptive material other than the activated carbon and inorganic material.

17. A filter medium as recited in claim 1, wherein the filter medium is formed in a block.

18. A filter medium as recited in claim 1, wherein the filter medium is formed in a sheet.

19. A filter medium as recited in claim 1, wherein the fluid is water.

20. A filter medium as recited in claim 1, wherein a percentage concentration of an inorganic cation provided by the inorganic material times pressure drop through the filter medium in pounds per square inch is at least about 0.5 [g Mg·

lb]/[g filter·

in²].

21. A method for removing microorganisms from a fluid, comprising causing the fluid to flow through the filter medium of claim 1.

22. A device for removing microorganisms from a fluid, comprising

a housing;

and

the filter medium of claim 1 positioned in the housing.

23. A device as recited in claim 22, wherein the housing is adapted to be mounted to a pressurized water source.

24. A device as recited in claim 22, wherein the housing is a pitcher.

25. A device as recited in claim 22, wherein the housing is a bottle.

26. A device as recited in claim 22, further comprising a pump coupled to the housing for urging flow of the fluid through the filter medium.

35. A device for removing microorganisms from a fluid, comprising

a housing;

and

a filter medium according to any of the previous claims, the filter medium being positioned in the housing.

27. A filter medium capable of removing microorganisms from a fluid, comprising:

particles of activated carbon;

particles of magnesium hydroxide; and

a binder for binding the particles of activated carbon and inorganic material, the binder having a melt index of less than about 1 gram per 10 minutes as determined by ASTM D 1238 at 190 degrees C. and 15 kilograms load.

28. A filter medium capable of removing microorganisms from a fluid, comprising:

particles of activated carbon;

particles of a substantially insoluble inorganic material having an isoelectric point greater than about 9.0 pH, the particles of organic material mixed together with the particles of activated carbon; and

an ultra high molecular weight polyethylene binder for binding the particles of activated carbon and inorganic material, the binder having a melt index of less than about 1 gram per 10 minutes as determined by ASTM D 1238 at 190 degrees C. and 15 kilograms load.

29. A filter medium capable of removing microorganisms from a fluid, comprising:

particles of activated carbon;

particles of magnesium hydroxide; and

an ultra high molecular weight polyethylene binder for binding the particles of activated carbon and magnesium hydroxide, the binder having a melt index of less than about 1 gram per 10 minutes as determined by ASTM D 1238 at 190 degrees C. and 15 kilograms load.

30. A filter medium as recited in claim 29, wherein the magnesium hydroxide is present in an amount between about 25 weight percent to about 45 weight percent of the total weight of the filter medium.

31. A filter medium as recited in claim 29, wherein the binder is present in an amount between about 20 weight percent to about 35 weight percent of the total weight of the filter medium.

32. A filter medium capable of removing microorganisms from a fluid, comprising:

particles of activated carbon;

particles of a substantially insoluble inorganic material having an isoelectric point greater than about 7.0 pH, the particles of organic material mixed together with the particles of activated carbon; and

a binder for binding the particles of activated carbon and particles of inorganic material, the binder having a melt index of less than about 1 gram per 10 minutes as determined by ASTM D 1238 at 190 degrees C. and 15 kilograms load.

33. A filter medium capable of removing microorganisms from a fluid, comprising:

granular activated carbon;

a material providing an inorganic cation having an isoelectric point greater than a pH of a fluid being filtered; and

a binder for binding the granular activated carbon and material providing the inorganic cation;

wherein a percentage concentration of the inorganic cation times pressure drop through the filter medium in pounds per square inch is at least about 0.5 [g Mg·

lb]/[g filter in²].

34. A granular filter medium capable of removing microorganisms from a fluid, comprising:

particles of activated carbon; and

particles of a substantially insoluble inorganic material having an isoelectric point greater than about 9.0 pH, the particles of organic material mixed together with the particles of activated carbon.

36. A method for forming a filter medium capable of removing microorganisms from a fluid, comprising:

mixing particles of activated carbon, particles of a substantially insoluble inorganic material having an isoelectric point greater than a pH of a fluid being filtered, and a binder, thereby forming a mixture;

heating the mixture such that the binder becomes tacky without becoming sufficiently liquid to substantially wet the particles of activated carbon and inorganic material; and

compressing the heated mixture for setting a pore size of pores formed by the particles and binder, a mean pore size after compression being between 0.01 micron and 10 microns.

37. A method as recited in claim 36, wherein the inorganic material is a magnesium containing material.

38. A method as recited in claim 37, wherein the inorganic material is magnesium hydroxide.

39. A method as recited in claim 36, wherein the inorganic material has an isoelectric point greater than about 9 pH.

40. A method as recited in claim 36, wherein the inorganic material has an isoelectric point greater than about 10 pH.

41. A method as recited in claim 36, wherein the inorganic material is present in an amount between about 25 weight percent to about 45 weight percent of the total weight of the filter medium.

42. A method as recited in claim 36, wherein the binder has a melt index of less than about 1 gram per 10 minutes as determined by ASTM D 1238 at 190 degrees C. and 15 kilograms load a melt index of less than about 1 gram per 10 minutes as determined by ASTM D 1238 at 190 degrees C. and 15 kilograms load.

43. A method as recited in claim 36, wherein the binder is an ultra high molecular weight polymer having a molecular weight greater than about 4 million.

44. A method as recited in claim 36, wherein the binder is ultra high molecular weight polyethylene.

45. A method as recited in claim 36, wherein the melt index of the binder is less than about 0.1 grams per 10 minutes as determined by ASTM D 1238 at 190 degrees C. and 15 kilograms load.

46. A method as recited in claim 36, wherein the binder is present in an amount between about 20 weight percent to about 35 weight percent of the total weight of the filter medium.

47. A method as recited in claim 36, wherein 75 grams of the compressed mixture performs a greater than 1×

10⁴ plaque forming units/milliliter reduction of viruses after 100 gallons of water passes through the filter medium.

48. A method as recited in claim 36, wherein the heated material is compressed in a cylindrically shaped mold to form a block having an outer diameter of less than about 4 inches and a maximum length between ends of the block of less than about 3 inches.

49. A method as recited in claim 48, wherein the block performs a greater than 1×

10⁴ plaque forming units/milliliter reduction of viruses after 100 gallons of water passes through the filter medium.

50. A method as recited in claim 36, further comprising shaping the mixture in the form of a sheet.

51. A method as recited in claim 36, wherein a mean pore size of pores formed by the particles and binder is between about 0.01 micron and about 10 microns.

52. A method as recited in claim 36, wherein a mean pore size of pores formed by the particles and binder is between about 0.1 micron and about 1 microns.

53. A method as recited in claim 36, wherein a percentage concentration of an inorganic cation provided by the inorganic material times pressure drop through the filter medium in pounds per square inch is at least about 0.5 [g Mg·

lb]/[g filter·

in²].

54. A device for removing microorganisms from water in the event of a bioterrorism attack, comprising:

a housing; and

a filter medium positioned in the housing, the filter medium comprising;

particles of activated carbon;

particles of a substantially insoluble inorganic material having an isoelectric point greater than about 9.0 pH, the particles of material mixed together with the particles of activated carbon; and

a binder for binding the particles of activated carbon and particles of inorganic material, the binder having a melt index of less than about 1 gram per 10 minutes as determined by ASTM D1238 at 190 degrees C. and 15 kilograms load.

55. A device as recited in claim 54, wherein the insoluble inorganic material is a magnesium containing compound.

56. A device as recited in claim 54, wherein the magnesium containing compound is magnesium hydroxide.