Ceramic to noble metal braze and method of manufacture

• US 6,989,200 B2
• Filed: 10/30/2003
• Issued: 01/24/2006
• Est. Priority Date: 10/30/2003
• Status: Active Grant

• Current Assignee: Alfred E. Mann Foundation For Scientific Research
• Original Assignee: Alfred E. Mann Foundation For Scientific Research
• Inventors: Schnittgrund, Gary D., Jiang, Guangqiang, Byers, Charles L.
• Primary Examiner(s): Jones, Deborah D.
• Assistant Examiner(s): Savage, Jason L.
• Application Number:
  US10/697,149
• Publication Number:
  US 20050095442A1
• Time in Patent Office: 817 Days
• Field of Search: 228/122.1, 228/201, 228/124.5, 228/202, 228/124.6, 228/245, 228/248.1, 228/262.1, 228/246, 228/56.3, 428/621, 428/615, 428/632, 428/635, 428/640, 428/661, 428/670, 428/680
• US Class Current: 428/621
• CPC Class Codes: B23K 35/007 at least one of the workpieces being of copper or another noble metal
• CPC Class Codes: B23K 35/3033 Ni as the principal constituent
• CPC Class Codes: B23K 35/325 Ti as the principal constituent
• CPC Class Codes: B23K 35/38 Selection of media, e.g. special atmospheres for surrounding the working area
• CPC Class Codes: C04B 2237/122 based on refractory metals
• CPC Class Codes: C04B 2237/708 of one or more of the interlayers
• CPC Class Codes: C04B 37/023 characterised by the interlayer used C04B37/028 takes precedence
• CPC Class Codes: C04B 37/026 consisting of metals or metal salts
• CPC Class Codes: Y10T 428/12535 with additional, spatially distinct nonmetal component
• CPC Class Codes: Y10T 428/12611 Oxide-containing component
• CPC Class Codes: Y10T 428/12632 Four or more distinct components with alternate recurrence of each type component
• CPC Class Codes: Y10T 428/12812 Diverse refractory group metal-base components: alternative to or next to each other
• CPC Class Codes: Y10T 428/12875 Platinum group metal-base component
• CPC Class Codes: Y10T 428/12944 Ni-base component

Abstract

The invention is a method of bonding a ceramic part to a metal part by heating a component assembly comprised of the metal part, the ceramic part, and a compatible interlayer material such as titanium-nickel alloy placed between the two parts and heated at a temperature that is greater than the eutectic temperature of the interlayer material, where alloys, intermetallics or solid solution formed between the metal part and the metal interlayer material, but that is less than the melting point of either the ceramic part or the metal part. The component assembly is held in intimate contact at temperature in a non-reactive atmosphere for a sufficient time to develop a hermetic and strong bond between the ceramic part and the metal part. The bonded component assembly is optionally treated with acid to remove unwanted materials, to assure a biocompatible component assembly for implantation in living tissue.

Claims

1. A component assembly comprising:

a ceramic part;

a metal part comprised of a noble metal; and

a titanium-nickel interlayer material disposed between and in contact with a surface of the ceramic part and a surface of the metal part wherein the ceramic part and the metal part are bonded together by means of said titanium-nickel interlayer material.

2. The component assembly of claim 1 wherein

said titanium-nickel interlayer material being a laminate foil.

3. The component assembly of claim 1 wherein

said component assembly being biocompatible to be suitable for use in living tissue.

4. The component assembly of claim 1 wherein

said titanium-nickel interlayer being comprised of 50% nickel and 50% titanium.

5. The component assembly of claim 1 wherein

said titanium-nickel interlayer being comprised of 67% titanium and 33% nickel.

6. The component assembly of claim 1 wherein

said ceramic part being selected from the group consisting of alumina, titania, zirconia, stabilized-zirconia, partially-stabilized zirconia, tetragonal zirconia polycrystal, magnesia-stabilized zirconia, ceria-stabilized zirconia, calcia-stabilized zirconia, and yttria-stabilized zirconia.

7. The component assembly of claim 1 wherein

said noble metal being selected from the group consisting of platinum, iridium, palladium, ruthenium, rhodium, and their respective alloys.

8. The component assembly of claim 1 wherein

said interlayer material being capable of forming a liquidus and creating a bond between said metal part and said ceramic part subsequent to the assembly being heated above a pre-selected temperature.

9. The component assembly of claim 8 wherein

the pre-selected temperature being greater than the liquidus point of the interlayer material and less than the melting point of the metal part.

10. The component assembly of claim 1 wherein

said interlayer material having a thickness no greater than approximately 0.003 inches.

11. The component assembly of claim 1 wherein

said interlayer material being a thin coating of titanium-nickel disposed on at least one of the surface to be bonded together.

12. The component assembly of claim 1 wherein

said interlayer material being a thin coating of titanium-nickel disposed on at least one of the surfaces to be bonded together by means of electroless plating or electroplating.

13. The component assembly of claim 1 wherein

said interlayer material being a thin coating of titanium-nickel that is disposed on at least one of the surfaces to be bonded together by means of depositing metallic beads or metallic powder on the surfaces.

14. The component assembly of claim 1 wherein

said interlayer material being a thin coating of titanium-nickel that is disposed on at least one of the surfaces to be bonded together by means of a thermal process selected from the group consisting of sputtering, evaporating, and ion beam enhanced deposition.

15. The component assembly of claim 1 wherein

said component assembly being hermetic.

16. A method of hermetically sealing a ceramic and metal component assembly, comprising the steps of:

selecting a ceramic part;

selecting a noble metal part;

selecting an interlayer material being compatible with said ceramic part, said interlayer material being capable of forming alloys, intermetallics or solid solutions with said metal part, said interlayer material having a liquidus temperature and said noble metal part having a melting point;

interposing said interlayer material between said ceramic part and said metal part;

applying a force to said ceramic part and said metal part to place said interposed interlayer material in compression;

placing said assembly in a non-reactive atmosphere;

heating said assembly to a bonding temperature between said liquidus temperature of said interlayer material and said melting point of said noble metal part;

holding said assembly at said bonding temperature for a predetermined time to form a bond between said ceramic part and said noble metal part; and

cooling the assembly.

17. The method of claim 16 wherein

said step of selecting the interlayer material is selecting a laminate material.

18. The method of claim 16 wherein

said step of applying the force creates compression between 20 and 2000 psi.

19. The method of claim 16 wherein

said step of selecting the ceramic part is selecting from the group consisting of alumina, titania, zirconia, stabilized-zirconia, partially-stabilized zirconia, tetragonal zirconia polycrystal, magnesia-stabilized zirconia, ceria-stabilized zirconia, yttria-stabilized zirconia, and calcia-stabilized zirconia.

20. The method of claim 16 wherein

said step of selecting the interlayer material is selecting a material comprised of titanium-nickel.

21. The method of claim 16 wherein

said step of selecting the interlayer material is selecting approximately 0.003 inches or less thick foil.

22. The method of claim 16 further comprising the step of

applying said interlayer material chemically.

23. The method of claim 16 further comprising the step of

applying said interlayer material thermally.

24. The method of claim 16 further comprising the step of

applying said interlayer material in the form of metallic beads.

25. The method of claim 16 further comprising the step of

applying said interlayer material in the form of metallic powder.

26. The method of claim 16 further comprising the step of

placing said assembly in a vacuum atmosphere between approximately 10–

5 to 10–

7 torr.

27. The method of claim 16 wherein

the holding said bonding temperature being between approximately 960°

C. and 1080°

C.

28. The method of claim 16 wherein

the holding said predetermined time is between approximately 1 and 60 minutes.

29. The method of claim 16 additionally comprising the step of

cleaning said component assembly after bonding to remove toxic materials that are harmful to living tissue.

30. The method of claim 29 additionally comprising the step of

cleaning said component assembly after bonding by placing it in an acid bath.

31. A method of bonding a noble metal part to a ceramic part making a hermetically sealed component assembly, comprising the steps of:

selecting said ceramic part from the group comprised of tetragonal zirconia polycrystal ceramic;

selecting said metal part from the group consisting of platinum, iridium, palladium, ruthenium, rhodium, and their respective alloys;

interposing a laminate titanium-nickel foil between said ceramic part and said metal part;

applying a force to said ceramic part and said metal part to place said titanium-nickel foil in compression;

placing said component assembly in a non-reactive atmosphere;

heating said component assembly to between approximately 960°

C. and 1080°

C. for between approximately 1 and 60 minutes; and

cooling said component assembly.

32. The method of claim 31 wherein

said step of interposing a foil is interposing a foil comprised of approximately equal amounts of nickel and titanium.

33. The method of claim 31 wherein

said step of interposing a foil is interposing a foil comprised of approximately twice as much titanium as nickel.

34. A method of bonding a ceramic part to a metal part, having a melting point, to form a component assembly for placement in living tissue in which an interlayer material, having a liquidus temperature, is placed between the ceramic part and the metal part, applying a compressive force of 20 to 2000 psi to said ceramic part and said metal part placing said interlayer material in compression, said interlayer material capable of forming alloys, intermetallics or solid solutions with said metal part, and in which said component assembly is placed at a bonding temperature, for a predetermined time, that is less than the melting point of said metal part, but greater than the liquidus temperature of said interlayer material, and selecting said ceramic part from the group consisting of alumina, titania, zirconia, stabilized-zirconia, partially-stabilized zirconia, tetragonal zirconia, magnesia-stabilized zirconia, ceria-stabilized zirconia, yttria-stabilized zirconia, and calcia-stabilized zirconia, wherein the improvement comprises:

selecting said metal part from a noble metal;

selecting said interlayer material to be titanium-nickel; and

selecting said bonding temperature between approximately 960°

C. and 1080°

C.

35. The method of claim 34 wherein

said noble metal being selected from the group consisting of platinum, iridium, palladium, ruthenium, rhodium, and their respective alloys.

36. The method of claim 34 wherein

said selecting the interlayer material is selecting a laminate material.

37. The method of claim 34 wherein

said selecting the interlayer material is selecting said interlayer material comprised of about equal proportions of nickel and titanium.

38. The method of claim 34 wherein

said step of selecting the interlayer material is selecting said interlayer material comprised of about twice as much titanium as nickel.