Method for removal of acid gases from a gas flow

• US 7,004,997 B2
• Filed: 07/19/2002
• Issued: 02/28/2006
• Est. Priority Date: 07/20/2001
• Status: Expired due to Term

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: BASF AG (BASF SE)
• Inventors: Asprion, Norbert, Grossmann, Christoph
• Primary Examiner(s): LAWRENCE JR, FRANK M
• Application Number:
  US10/484,161
• Publication Number:
  US 20040154469A1
• Time in Patent Office: 1,320 Days
• Field of Search: 951/87, 951/91, 951/92, 952/03, 952/35, 952/36, 423/220, 423/229
• US Class Current: 95/235
• CPC Class Codes: B01D 53/1456 Removing acid components
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents

Abstract

A process is described for removing acid gases from a gas stream in which an acid-gas-containing gas stream in which the sum of the partial pressures of the acid gases does not exceed 1,500 mbar is brought into contact with an aqueous absorbent in an absorption step and an absorbent is used which contains methyldiethanolamine and piperazine at a concentration of at least 8% by weight of the absorbent, an acid-gas-depleted gas stream and an acid-gas-loaded absorbent being obtained.

Claims

1. A process for removing acid gases from a gas stream comprising

contacting an acid-gas-containing gas stream in which the sum of the partial pressures of the acid gases does not exceed 1,500 mbar with an aqueous absorbent at a total pressure of from 50 to 70 bar wherein the absorbent consists of water, at least one tertiary alkanolamine and piperazine at a concentration of 15 to 40% by weight of the absorbent to form an acid-gas-depleted gas stream and an acid-gas-loaded absorbent.

2. The process as claimed in claim 1, wherein the sum of the partial pressures of the acid gases in the gas stream is <

1,000 mbar.

3. The process as claimed in claim 1, wherein the total amine concentration in the absorbent is in the range from 20 to 70% by weight of the absorbent.

4. The process as claimed in claim 3, wherein the total amine concentration in the absorbent is in the range from 20 to 55% by weight of the absorbent.

5. The process as claimed in claim 1, wherein the piperazine concentration in the absorbent is in the range from 15 to 25% by weight of the absorbent.

6. The process as claimed in claim 1, wherein the tertiary alkanolamine is methyldiethanolamine.

7. The process as claimed in claim 1, further comprising

releasing the acid gases from the loaded absorbent to form a regenerated absorbent.

8. The process as claimed in claim 7, wherein the releasing comprises one or more expansion stages.

9. The process as claimed in claim 7, wherein the releasing comprises one or more stripping stages.

10. The process as claimed in claim 1, wherein the sum of the partial pressures of the acid gases in the gas stream is ≦

500 mbar.

11. The process as claimed in claim 7, further comprising

recirculating the regenerated absorbent and contacting the regenerated absorbent with the acid-gas-containing gas stream.