Polymer-wrapped single wall carbon nanotubes

• US 7,008,563 B2
• Filed: 08/23/2001
• Issued: 03/07/2006
• Est. Priority Date: 08/24/2000
• Status: Expired due to Term

• Current Assignee: Rice University
• Original Assignee: Rice University
• Inventors: Smalley, Richard E., O'Connell, Michael, Colbert, Daniel T., Smith, Ken A.
• Primary Examiner(s): KOPEC, MARK T
• Application Number:
  US09/935,994
• Publication Number:
  US 20020046872A1
• Time in Patent Office: 1,657 Days
• Field of Search: 252/502, 252/511, 423/445.R, 423/460, 423/461, 524/495, 524/496, 204/164
• US Class Current: 252/511
• CPC Class Codes: B82Y 10/00 Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: C08K 9/08 Ingredients agglomerated by treatment with a binding agent
• CPC Class Codes: D01F 11/14 with organic compounds, e.g. macromolecular compounds
• CPC Class Codes: H01C 17/0652 containing carbon or carbides
• CPC Class Codes: H01Q 17/002 using short elongated elements as dissipative material, e.g. metallic threads or flake-like particles
• CPC Class Codes: H05K 1/0373 containing additives, e.g. fillers H05K1/036 takes precedence
• CPC Class Codes: H05K 1/162 incorporating printed capacitors
• CPC Class Codes: H10K 85/221 Carbon nanotubes
• CPC Class Codes: H10K 85/615 Polycyclic condensed aromatic hydrocarbons, e.g. anthracene
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
• CPC Class Codes: Y10S 977/745 having a modified surface
• CPC Class Codes: Y10S 977/746 Modified with biological, organic, or hydrocarbon material
• CPC Class Codes: Y10S 977/748 Modified with atoms or molecules bonded to the surface
• CPC Class Codes: Y10S 977/75 Single-walled
• CPC Class Codes: Y10S 977/783 Organic host/matrix, e.g. lipid
• CPC Class Codes: Y10T 428/2935 Discontinuous or tubular or cellular core
• CPC Class Codes: Y10T 428/2991 Coated
• CPC Class Codes: Y10T 428/2998 including synthetic resin or polymer

Abstract

The present invention relates to new compositions of matter and articles of manufacture comprising SWNTs as nanometer scale conducting rods dispersed in an electrically-insulating matrix. These compositions of matter have novel and useful electrical, mechanical, and chemical properties including applications in antennas, electromagnetic and electro-optic devices, and high-toughness materials. Other compositions of matter and articles of manufacture are disclosed, including polymer-coated and polymer wrapped single-wall nanotubes (SWNTs), small ropes of polymer-coated and polymer-wrapped SWNTs and materials comprising same. This composition provides one embodiment of the SWNT conducting-rod composite mentioned above, and also enables creation of high-concentration suspensions of SWNTs and compatibilization of SWNTs with polymeric matrices in composite materials. This solubilization and compatibilization, in turn, enables chemical manipulation of SWNT and production of composite fibers, films, and solids comprising SWNTs.

Claims

1. A dielectric material comprising a plurality of single-wall carbon nanotubes coated at least in part with a polymer molecule, wherein the polymer-coated single-wall carbon nanotubes are substantially electrically-isolated from one another.

2. A dielectric material in accordance with claim 1, wherein the single-wall carbon nanotubes are smaller on average in their circumference than the average length of the individual polymer molecules.

3. A structure comprising a dielectric material in accordance with claim 1, wherein the structure is selected from the group consisting of capacitor dielectrics, circuit board materials, waveguide materials, optical index-matching materials, electromagnetic radiation absorbing materials, electromagnetic radiation re-directing materials, optoelectronic materials, antenna arrays, materials for suspending antennas, electrically-loading antennas, and supports of antenna arrays.

4. A dielectric material in accordance with claim 1, wherein the polymer-coated single-wall carbon nanotubes are embedded in a polymer matrix.

5. A dielectric material in accordance with claim 4, wherein the polymer matrix is an electrically-insulating polymer material.

6. A dielectric material in accordance with claim 1, wherein a dielectric constant of said dielectric material is at least about 10.

7. A dielectric material in accordance with claim 1, wherein a dielectric constant of said dielectric material is at least about 100.

8. A dielectric material in accordance with claim 1, wherein a dielectric constant of said dielectric material is at least about 500.

9. A dielectric material comprising a plurality of aggregates of single-wall carbon nanotubes, wherein the aggregates are coated at least in part with a polymer molecule and wherein the aggregates of single-wall carbon nanotubes are substantially electrically-isolated from one another.

10. A dielectric material in accordance with claim 9, wherein the aggregates of single-wall carbon nanotubes comprise ropes of single-wall carbon nanotubes in which the nanotubes are substantially aligned along the longitudinal axes of the ropes.

11. A dielectric material in accordance with claim 9, wherein the aggregates of single-wall carbon nanotubes comprise bundles of single-wall carbon nanotubes in which the nanotubes are substantially aligned along the longitudinal axes of the bundles.

12. A dielectric material in accordance with claim 9, wherein the aggregates of single-wall carbon nanotubes are smaller on average in their circumference than the average length of the individual polymer molecules.

13. A structure comprising a dielectric material in accordance with claim 9, wherein the structure is selected from the group consisting of capacitor dielectrics, circuit board materials, waveguide materials, optical index-matching materials, electromagnetic radiation absorbing materials, electromagnetic radiation re-directing materials, optoelectronic materials, antenna arrays, materials for suspending antennas, electrically-loading antennas, and supports of antenna arrays.

14. A dielectric material in accordance with claim 9, wherein the polymer-coated aggregates of single-wall carbon nanotubes are embedded in a polymer matrix.

15. A dielectric material in accordance with claim 14, wherein the polymer matrix is an electrically-insulating polymer material.

16. A structure comprising a dielectric material in accordance with claim 14, wherein the structure is selected from the group consisting of capacitor dielectrics, circuit board materials, waveguide materials, optical index-matching materials, electromagnetic radiation absorbing materials, electromagnetic radiation re-directing materials, optoelectronic materials, antenna arrays, materials for suspending antennas, electrically-loading antennas, and supports of antenna arrays.

17. A dielectric material in accordance with claim 9, wherein a dielectric constant of said dielectric material is at least about 10.

18. A dielectric material in accordance with claim 9, wherein a dielectric constant of said dielectric material is at least about 100.

19. A dielectric material in accordance with claim 9, wherein a dielectric constant of said dielectric material is at least about 500.

20. A method comprising:

(a) selecting a plurality of coated single-wall carbon nanotubes, wherein the coated single-wall carbon nanotubes are coated at least in part with a polymer molecule; and

(b) contacting a species with the coated single-wall carbon nanotubes to effect a chemical adsorption of the species on the surface of the coated single-wall carbon nanotubes, wherein the coated single-wall carbon nanotubes change dimensionally, electronically, or both in response to the chemical adsorption.

21. The method in accordance with claim 20, wherein the coated single-wall carbon nanotubes are part of a chemical sensor that responds to at least one of (i) the dimensional change of the coated single-wall carbon nanotubes and (ii) the electronic change of the coated single-wall carbon nanotubes.

22. The method in accordance with claim 20, wherein the coated single-wall carbon nanotubes are part of a transducer that responds to at least one of (i) the dimensional change of the coated single-wall carbon nanotubes and (ii) the electronic change of the coated single-wall carbon nanotubes.

23. A method comprising:

(a) selecting aggregates of coated single-wall carbon nanotubes, wherein the aggregates of coated single-all carbon nanotubes are coated at least in part with a polymer molecule; and

(b) contacting a species with the coated aggregates of single-wall carbon nanotubes to effect a chemical adsorption of the species on the surface of the coated aggregates of single-wall carbon nanotubes, wherein the coated aggregates of single-wall carbon nanotubes change dimensionally, electronically, or both in response to the chemical adsorption.

24. The method in accordance with claim 23, wherein the coated aggregates of single-wall carbon nanotubes comprise ropes of single-wall carbon nanotubes in which the single wall carbon nanotubes in the ropes are substantially aligned along their longitudinal axes.

25. The method in accordance with claim 23, wherein the coated aggregates of single-wall carbon nanotubes are part of a chemical sensor that responds to at least one of (i) the dimensional change of the coated single-wall carbon nanotubes and (ii) the electronic change of the coated single-wall carbon nanotubes.

26. The method in accordance with claim 23, wherein the coated aggregates of single-wall carbon nanotubes are part of a transducer that responds to at least one of (i) the dimensional change of the coated single-wall carbon nanotubes and (ii) the electronic change of the coated single-wall carbon nanotubes.

27. A method comprising:

(a) selecting a fluid comprising a dispersion of a plurality of single-wall carbon nanotubes coated at least in part with a polymer; and

(b) controlling the viscosity of the fluid by applying to the fluid a field selected from the group consisting of an electric field, a magnetic field and combinations thereof.

28. A method comprising:

(a) selecting a fluid comprising a dispersion of a plurality of aggregates of single-wall carbon nanotubes, wherein the aggregates are coated at least in part with a polymer;

(b) controlling the viscosity of the fluid by applying to the fluid a field selected from the group consisting of an electric field, a magnetic field and combinations thereof.

29. A method in accordance with claim 28, wherein the aggregates of single-wall carbon nanotubes comprise ropes of single-wall carbon nanotubes in which the single-wall carbon nanotubes in the ropes are substantially aligned along their longitudinal axes.

30. A method in accordance with claim 28, wherein the aggregates of single-wall carbon nanotubes comprise bundles of single-wall carbon nanotubes in which the single-wall carbon nanotubes in the bundles are substantially aligned along their longitudinal axes.

31. A film comprising a plurality of aggregates of single-wall carbon nanotubes, wherein:

(a) the aggregates of single-wall carbon nanotubes are coated at least in part with a polymer; and

(b) the film is a dielectric material, wherein the aggregates of single-wall carbon nanotubes are substantially electrically-isolated from one another.

32. A film in accordance with claim 31, wherein the single-wall carbon nanotube aggregate comprises a rope of single-wall carbon nanotubes in which the nanotubes are substantially aligned along their longitudinal axes.

33. A film in accordance with claim 32, wherein the single-wall carbon nanotube aggregate comprises a bundle of single-wall carbon nanotubes in which the nanotubes are substantially aligned along their longitudinal axes.

34. A fiber comprising a plurality of aggregates of single-wall carbon nanotubes, wherein:

(a) the aggregates of single-wall carbon nanotubes are coated at least in part with a polymer; and

(b) the fiber is a dielectric material, wherein the aggregates of single-wall carbon nanotubes are substantially electrically-isolated from one another.

35. A fiber in accordance with claim 34, wherein the single-wall carbon nanotube aggregate comprises a rope of single-wall carbon nanotubes in which the nanotubes are substantially aligned along their longitudinal axes.

36. A fiber in accordance with claim 34, wherein the single-wall carbon nanotube aggregate comprises a bundle of single-wall carbon nanotubes in which the nanotubes are substantially aligned along their longitudinal axes.

37. A method comprising:

(a) selecting a plurality of coated single-wall carbon nanotubes, wherein the coated single-wall carbon nanotubes are coated at least in part with a polymer molecule; and

(b) applying an electric field, wherein the coated single-wall carbon nanotubes change dimensionally, electronically, or both in response to the applied electric field.

38. The method in accordance with claim 37, wherein the coated single-wall carbon nanotubes are part of a transducer that responds to at least one of (i) the dimensional change of the coated single-wall carbon nanotubes and (ii) the electronic change of the coated single-wall carbon nanotubes.

39. A method comprising:

(a) selecting a composition comprising a plurality of coated single-wall carbon nanotubes, wherein the coated single-wall carbon nanotubes are coated at least in part with a polymer molecule; and

(b) applying a magnetic field, wherein the composition changes dimensionally, electronically, or both in response to the applied magnetic field.

40. The method in accordance with claim 39 wherein the composition is part of a transducer that responds to at least one of (i) the dimensional change of the composition and (ii) the electronic change of the composition.

41. A method comprising:

(a) selecting a composition comprising a plurality of coated single-wall carbon nanotubes, wherein the coated single-wall carbon nanotubes are coated at least in part with a polymer molecule; and

(b) contacting a species with the composition to effect a chemical adsorption of the species on the surface of the coated single-wall carbon nanotubes, wherein the coated single-wall carbon nanotubes change dimensionally, electronically, or both in response to the chemical adsorption.

42. The method in accordance with claim 41, wherein the composition is part of a chemical sensor that responds to at least one of (i) the dimensional change of the composition and (ii) the electronic change of the composition.

43. The method in accordance with claim 41, wherein the composition is part of a transducer that responds to at least one of (i) the dimensional change of the composition and (ii) the electronic change of the composition.

44. A method comprising:

(a) selecting a composition comprising coated aggregates of single-wall carbon nanotubes, wherein the coated aggregates of single-wall carbon nanotubes are coated at least in part with a polymer molecule; and

(b) contacting a species with the composition to effect a chemical adsorption of the species on the surface of the coated aggregates of single-wall carbon nanotubes, wherein the coated aggregates of single-wall carbon nanotubes change dimensionally, electronically, or both in response to the chemical adsorption.

45. The method in accordance with claim 44, wherein the coated aggregates of single-wall carbon nanotubes comprise ropes of single-wall carbon nanotubes in which the single-wall carbon nanotubes are substantially aligned along the longitudinal axes of the ropes.

46. The method in accordance with claim 44, wherein the composition is part of a chemical sensor that responds to at least one of (i) the dimensional change of the composition and (ii) the electronic change of the composition.

47. The method in accordance with claim 44, wherein the composition is part of a transducer that responds to at least one of (i) the dimensional change of the composition and (ii) the electronic change of the composition.

48. A method comprising:

(a) selecting a composition comprising coated aggregates of single-wall carbon nanotubes, wherein the coated aggregates of single-wall carbon nanotubes are coated at least in part with a polymer molecule; and

(b) applying an electric field, wherein the composition changes dimensionally, electronically, or both in response to the applied electric field.

49. The method in accordance with claim 48, wherein the coated aggregates of single-wall carbon nanotubes comprise ropes of single-wall carbon nanotubes in which the single-wall carbon nanotubes are substantially aligned along the longitudinal axes of the ropes.

50. The method in accordance with claim 48, wherein the composition is part a transducer that responds to at least one of (i) the dimensional change of the composition and (ii) the electronic change of the composition.

51. A method comprising:

(a) selecting a composition comprising coated aggregates of single-wall carbon nanotubes, wherein the coated aggregates of single-wall carbon nanotubes are coated at least in part with a polymer molecule; and

(b) applying a magnetic field, wherein the composition changes dimensionally, electronically, or both in response to the applied magnetic field.

52. The method in accordance with claim 51, wherein the coated aggregates of single-wall carbon nanotubes comprise ropes of single-wall carbon nanotubes in which the single-wall carbon nanotubes are substantially aligned along the longitudinal axes of the ropes.

53. The method in accordance with claim 51, wherein the composition is part of a transducer that responds to at least one of (i) the dimensional change of the composition and (ii) the electronic change of the composition.