Methods for hydrogen storage using doped alanate compositions

• US 7,011,768 B2
• Filed: 06/16/2003
• Issued: 03/14/2006
• Est. Priority Date: 07/10/2002
• Status: Expired due to Fees

• Current Assignee: Limnia
• Original Assignee: Fuelsell Technologies Incorporated
• Inventors: Redmond, Scott D., Jensen, Craig M.
• Primary Examiner(s): ANTHONY, JOSEPH DAVID
• Application Number:
  US10/463,352
• Publication Number:
  US 20040009121A1
• Time in Patent Office: 1,002 Days
• Field of Search: 252/184, 252/188.25, 252/188.26, 252/188.27, 252/188.28, 252/950, 252/182.35, 48/61, 481/20, 481/90, 423/648.1, 423/644, 423/658.2, 429/19, 429/20, 429/22, 429/34, 420/900, 420/543
• US Class Current: 252/188.25
• CPC Class Codes: C01B 3/001 characterised by the uptaking medium; Treatment thereof
• CPC Class Codes: C01B 3/0031 Intermetallic compounds; Metal alloys; Treatment thereof
• CPC Class Codes: C01B 3/0078 Composite solid storage mediums, i.e. coherent or loose mixtures of different solid constituents, chemically or structurally heterogeneous solid masses, coated solids or solids having a chemically modified surface region
• CPC Class Codes: C01B 6/243 containing only hydrogen, aluminium and alkali metals, e.g. Li(AlH4)
• CPC Class Codes: C07F 17/00 Metallocenes
• CPC Class Codes: H01M 8/04 Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
• CPC Class Codes: H01M 8/065 by dissolution of metals or alloys; by dehydriding metallic substances
• CPC Class Codes: Y02E 60/32 Hydrogen storage
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y10S 420/90 Hydrogen storage

Abstract

The present invention concerns compositions, apparatus and methods for hydrogen storage. In certain embodiments, the compositions comprise sodium alanate and {n⁵-C₅H₅}₂TiH₂. In preferred embodiments, the components of the composition are present in specified molar ratios, for example 0.7 NaH to 1.0 Al to 0.1 Ti. In various embodiments, the hydrocarbon rings coordinating the titanium are removed from the composition, for example by melting at 182° C. or higher or by cyclic discharge and recharge of hydrogen at temperatures of 100° C. or less. Methods for producing and using the claimed compositions are also provided. In various embodiments, the alanate composition may be stored, shipped and used in a modular container, such as a cassette. Exemplary hydrogen utilizing systems and methods for ordering, distribution and shipping of cassettes are also disclosed herein.

Claims

1. A composition comprising NaAlH₄ and {n⁵-C₅H₅}₂TiH₂.

2. The composition of claim 1, wherein the molar ratios of NaH:

Al;

Ti in the composition are respectively 0.7 to 1.0 to 0.1.

3. The composition of claim 1, wherein the molar ratio of NaH in the composition is between 0.1 and 0.88.

4. The composition of claim 1, wherein the molar ratio of Ti in the composition is between 0.04 and 0.3.

5. The composition of claim 1, wherein the molar ratio of Ti in the composition is equal to (1.0 minus the molar ratio of NaH in the composition) divided by three.

6. The composition of claim 1, wherein the composition has been heated to a temperature of 182°

C. or higher.

7. A hydrogen storage system comprising:

a) a cassette; and

b) a composition comprising NaAlH₄ and {n⁵-C₅H₅}₂TiH₂.

8. The system of claim 7, wherein the cassette contains an opening, the opening sealed with one or more valves.

9. The system of claim 8, wherein the cassette comprises a single two-way valve.

10. The system of claim 8, wherein the cassette comprises two one-way valves.

11. The system of claim 8, wherein the cassette comprises a bidirectional one-way valve.

12. The system of claim 8, wherein a valve opens when hydrogen gas is generated from the composition.

13. The system of claim 8, wherein a valve opens when external hydrogen at a pressure of two or more atmospheres is applied.

14. The system of claim 8, wherein the opening and closing of the one or more valves is electrically controlled.

15. The system of claim 7, further comprising a heater to heat the composition.

16. The system of claim 15, wherein the heater is capable of heating the composition to 100°

C.

17. The system of claim 7, further comprising a smart chip.

18. The system of claim 17, wherein the smart chip reports the conditions inside the cassette to an external information processing and control system.

19. The system of claim 18, wherein the conditions are selected from the group consisting of temperature, pressure and the amount of hydrogen charge remaining in the cassette.

20. The system of claim 19, wherein the cassette is installed in a vehicle and the conditions are reported to the operator of the vehicle.

21. The system of claim 7, wherein the system is attached to one or more units selected from the group consisting of a fuel cell, a vehicle, a catalytic heater, a hydrogen combustion device, an emergency power generator, a light, a computer and a portable electronic device.

22. The system of claim 7, further comprising an information processing and control system.

23. A method of preparing a doped sodium alanate composition comprising:

a) mixing NaH, Al and {n⁵-C₅H₅}₂TiH₂; and

b) heating the mixture to a temperature above 182°

C.

24. The method of claim 23, wherein said mixing occurs in the absence of ball milling.

25. The method of claim 23, wherein the molar ratios of NaH:

Al;

Ti in the composition are respectively 0.7 to 1.0 to 0.1.

26. The method of claim 23, wherein said heating occurs at a temperature of between 200 and 250°

C.

27. The process of claim 23, further comprising performing the process under a noble gas atmosphere.

28. The process of claim 27, wherein the noble gas is argon.