Elastomeric adhesive

• US 7,015,155 B2
• Filed: 07/02/2002
• Issued: 03/21/2006
• Est. Priority Date: 07/02/2002
• Status: Expired due to Term

• Current Assignee: Kimberly-Clark Worldwide Incorporated (Kimberly-Clark Corporation)
• Original Assignee: Kimberly-Clark Worldwide Incorporated (Kimberly-Clark Corporation)
• Inventors: Zhou, Peiguang, Neculescu, Cristian M.
• Primary Examiner(s): Morris, Terrel
• Assistant Examiner(s): Piziali, Andrew T
• Application Number:
  US10/187,681
• Publication Number:
  US 20040005834A1
• Time in Patent Office: 1,358 Days
• Field of Search: 442/149, 442/104, 442/328, 442/329, 442/382, 442/394, 442/400, 442/401, 428/343, 428/355.R, 156/60, 156/196, 156/229
• US Class Current: 442/149
• CPC Class Codes: A61F 13/15593 having elastic ribbons fixed thereto; Devices for applying the ribbons
• CPC Class Codes: A61F 13/49011 the elastic means is located at the waist region
• CPC Class Codes: A61F 13/49014 the elastic means is located at the side panels
• CPC Class Codes: A61F 13/49017 the elastic means being located at the crotch region
• CPC Class Codes: A61F 13/4902 characterised by the elastic material
• CPC Class Codes: B32B 2305/20 in the form of a non-woven mat
• CPC Class Codes: B32B 2307/51 Elastic
• CPC Class Codes: B32B 25/04 comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material next to a layer of a particular substance B32B9/043; next to a bituminous or tarry layer B32B11/044; next to a water setting substance layer B32B13/042; next to a metal layer B32B15/06; next to a glass layer B32B17/063; next to a layer formed of natural mineral fibres or particles B32B19/043; next to a wood layer B32B21/045; next to a cellulosic plastic layer B32B23/046
• CPC Class Codes: B32B 2555/02 Diapers or napkins
• CPC Class Codes: B32B 37/144 using layers with different mechanical or chemical conditions or properties, e.g. layers with different thermal shrinkage, layers under tension during bonding constructional features for tensioning B32B38/1825
• CPC Class Codes: C09J 153/00 Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
• CPC Class Codes: C09J 153/02 Vinyl aromatic monomers and conjugated dienes
• CPC Class Codes: Y10T 156/10 Methods of surface bonding and/or assembly therefor
• CPC Class Codes: Y10T 156/1002 with permanent bending or reshaping or surface deformation of self sustaining lamina
• CPC Class Codes: Y10T 428/28 Web or sheet containing structurally defined element or component and having an adhesive outermost layer
• CPC Class Codes: Y10T 428/2852 Adhesive compositions
• CPC Class Codes: Y10T 442/2369 Coating or impregnation improves elasticity, bendability, resiliency, flexibility, or shape retention of the fabric
• CPC Class Codes: Y10T 442/2738 Coating or impregnation intended to function as an adhesive to solid surfaces subsequently associated therewith
• CPC Class Codes: Y10T 442/601 Nonwoven fabric has an elastic quality
• CPC Class Codes: Y10T 442/602 Nonwoven fabric comprises an elastic strand or fiber material
• CPC Class Codes: Y10T 442/66 : Additional nonwoven fabric is a spun-bonded fabric
• CPC Class Codes: Y10T 442/674 : Nonwoven fabric with a preformed polymeric film or sheet
• CPC Class Codes: Y10T 442/68 : Melt-blown nonwoven fabric
• CPC Class Codes: Y10T 442/681 : Spun-bonded nonwoven fabric

Abstract

Elastomeric adhesive compositions including a high softening point tackifier resin in combination with a base polymer can be used to create laminates having effective adhesion and elastic properties. The compositions may also include a low softening point additive, and/or an antioxidant. Facing layers, such as nonwoven webs and/or films, can be laminated to both surfaces of the elastomeric compositions to form laminates. A method of making such compositions and laminates involves forming the compositions into elastomeric adhesive films.

Claims

1. An elastomeric construction adhesive composition that can be used to create a bonded, elasticized region, comprising:

between about 55% and about 65% by weight base polymer selected from the group consisting of polystyrene-polyethylene-polypropylene-polystyrene (SEPS) block copolymer, styrene-isoprene-styrene (SIS,) styrene-butadiene-styrene (SBS) block copolymer, and combinations thereof, the base polymer having a melt flow rate between about 5 and about 100 grams per minute, a Shore A hardness between about 20 and about 70, and may be stretched up to about 1300%; and

a high softening point tackifier resin including at least one type of hydrocarbon selected from a group consisting of petroleum distillates, rosin, rosin esters, polyterpenes derived from wood, polyterpenes derived from synthetic chemicals, and combinations thereof, the tackifier having a softening point of at least 80 degrees Celsius, and a viscosity of at least 1500 cps at 182 degrees Celsius;

wherein the elastomeric adhesive composition has a viscosity of about 5,000 to 80,000 cps at between 177 and 204 degrees Celsius and can be stretched prior to lamination.

2. The composition of claim 1, wherein the base polymer comprises a styrene content of between about 15% and about 45% by weight.

3. The composition of claim 1, wherein the base polymer comprises a styrene content of between about 18% and about 30% by weight.

4. The composition of claim 1, wherein the high softening point tackifier is present in the composition in an amount of at least about 30% by weight.

5. The composition of claim 1, further comprising a low softening point additive having a softening point of less than 80 degrees Celsius and a viscosity of less than 1000 cps at 182 degrees Celsius, present in an amount between about 0% and about 20% by weight.

6. The composition of claim 1, further comprising an antioxidant in an amount between about 0.1% and about 1.0% by weight.

7. The composition of claim 1, wherein the composition can be stretched up to about 1300% prior to lamination.

8. The composition of claim 1, wherein the composition can be stretched up to about 1000% prior to lamination.

9. The composition of claim 1, wherein the composition can be stretched up to about 700% prior to lamination.

10. The composition of claim 1, wherein the composition can be stretched up to about 500% prior to lamination.

11. The composition of claim 1, wherein the composition has a viscosity of about 10,000 to 50,000 cps at between 177 and 196 degrees Celsius.

12. The composition of claim 1, wherein the composition is formed as a plurality of extruded strands.

13. The composition of claim 1, wherein the composition is formed as an extruded film.

14. The composition of claim 1, wherein the composition is formed as a combination of a plurality of extruded strands and an extruded film.

15. The composition of claim 1, wherein the composition can be processed by conventional hot melt equipment.

16. An elastomeric laminate, comprising:

first and second facing sheets; and

an elastomeric adhesive composition between the first and second facing sheets thereby permanently bonding the first and second facing sheets to one another and providing elasticity in the bonded area, the elastomeric adhesive composition including between about 55% and about 65% by weight base polymer selected from the group consisting of polystyrene-polyethylene-polypropylene-polystyrene (SEPS) block copolymer, styrene-isoprene-styrene (SIS), styrene-butadiene-styrene (SBS) block copolymer, and combinations thereof; and

a high softening point tackifier resin including at least one type of hydrocarbon selected from a group consisting of petroleum distillates, rosin, rosin esters, polyterpenes deeerived from wood, polyterpenes derived from synthetic chemicals, and combinations thereof, the tackifier having a softening point of at least 80 degrees Celsius and a viscosity of at least 1500 cps at 182 degrees Celsius;

wherein the elastomeric adhesive composition has a viscosity of about 5,000 to 80,000 cps at between 177 and 204 degrees Celsius.

17. The elastomeric laminate of claim 16 wherein at least one of the first and second facing sheets comprises a nonwoven web selected from a spunbond web and a meltblown web.

18. The elastomeric laminate of claim 16, wherein at least one of the first and second facing sheets comprises a film.

19. The elastomeric laminate of claim 16, wherein the base polymer comprises a styrene content of between about 15% and about 45% by weight.

20. The elastomeric laminate of claim 16, wherein the base polymer comprises a styrene content of between about 18% and about 30% by weight.

21. The elastomeric laminate of claim 16, wherein the base polymer has a melt flow rate between about 5 and about 100 grams per minute, a Shore A hardness between about 20 and about 70, and may be stretched up to about 1300%.

22. The elastomeric laminate of claim 16, wherein the high softening point tackifier is present in the composition in an amount of at least about 30% by weight.

23. The elastomeric laminate of claim 16, further comprising a low softening point additive having a softening point of less than 80 degrees Celsius and a viscosity of less than 1000 cps at 182 degrees Celsius present in an amount between about 0% and about 20% by weight.

24. The elastomeric laminate of claim 16, further comprising an antioxidant in an amount between about 0.1% and about 1.0% by weight.

25. The elastomeric laminate of claim 16, wherein the composition can be stretched up to about 1200% prior to lamination.

26. The elastomeric laminate of claim 16, wherein the composition can be stretched up to about 1000% prior to lamination.

27. The elastomeric laminate of claim 16, wherein the composition can be stretched up to about 700% prior to lamination.

28. The elastomeric laminate of claim 16, wherein the composition can be stretched up to about 500% prior to lamination.

29. The elastomeric laminate of claim 16, wherein the composition has a viscosity of about 10,000 to 50,000 cps at between 177 and 196 degrees Celsius.

30. The elastomeric laminate of claim 16, wherein the composition is formed as a plurality of extruded strands.

31. The elastomeric laminate of claim 16, wherein the composition is formed as an extruded film.

32. The elastomeric laminate of claim 16, wherein the composition is formed as a combination of a plurality of extruded strands and an extruded film.

33. The elastomeric laminate of claim 16, further comprising:

a garment incorporating the elastomeric laminate into a structure of the garment.

34. The elastomeric laminate of claim 33, wherein the garment is one selected from a group consisting of personal care garments, medical garments, and industrial workwear garments.

35. The elastomeric laminate of claim 34, wherein the garment is one selected from a group consisting of diapers, training pants, swim wear, absorbent underpants, adult incontinence products, feminine hygiene products, protective medical gowns, surgical medical gowns, caps, gloves, drapes, face masks, laboratory coats, and coveralls.

36. A method of making an elastomeric adhesive composition, comprising:

forming a solid phase composition of about 55-65% by weight of a base polymer selected from the group consisting of polystyrene-polyethylene-polypropylene-polystyrene (SEPS) block copolymer, styrene-isoprene-styrene (SIS), styrene-butadiene-styrene (SBS) block copolymer, and combinations thereof, and having a melt flow rate between about 5 and about 100 grams per minute, a Shore A hardness between about 20 and about 70, and stretchable by up to about 1300%; and

a high softening point tackifier resin including at least one type of hydrocarbon selected from a group consisting of petroleum distillates, rosin, rosin, esters, polyterpenes derived from wood, polyterpenes derived from synthetic chemicals, and combinations thereof, and having a softening point of at least 80 degrees Celsius and a viscosity of at least 1500 cps at 182 degrees Celsius

forming a liquid phase composition by heating the solid phase composition;

forming a film by extruding the liquid phase composition onto a chill roll; and

peeling the film off the chill roll while stretching the film;

wherein the elastomeric adhesive composition has a viscosity of about 5,000 to 80,000 cps at between 177 and 204 degrees Celsius, and can be stretched prior to lamination.

37. The method of claim 36, wherein the liquid phase composition is extruded through a slot coat die onto the chill roll.

38. The method of claim 37, comprising stretching the film at an output of between about 50 and about 120 grams per square meter before stretching, from the slot coat die.

39. The method of claim 36, comprising stretching the film up to about 1200%.

40. The method of claim 36, comprising stretching the film up to about 1000%.

41. The method of claim 36, comprising stretching the film up to about 700%.

42. The method of claim 36, comprising stretching the film up to about 500%.

43. The method of claim 36, wherein the liquid phase composition is extruded through an extrusion die onto the chill roll.

44. The method of claim 43, comprising stretching the film at an output of between about 50 and about 120 grams per square meter, before stretching, from the extrusion die.

45. The method of claim 36, further comprising laminating the stretched film between two facing sheets.

46. The method of claim 45, wherein at least one of the facing sheets comprises a non-woven web.

47. The method of claim 45, wherein at least one of the facing sheets comprises a film.

48. The method of claim 36, wherein the liquid phase composition is formed by heating the solid phase composition at between about 177 and about 204 degrees Celsius.

49. The method of claim 36, wherein the chill roll is set at a temperature of between about 10 and about 50 degrees Celsius while the film is being formed.

50. The method of claim 36, wherein the base polymer comprises a styrene content of between about 15% and about 45% by weight.

51. The method of claim 36, wherein the base polymer comprises a styrene content of between about 18% and about 30% by weight.

52. The method of claim 36, wherein the solid phase composition further comprises a low softening paint additive having a softening point of less than 80 degrees Celsius and a viscosity of loss than 1000 cps at 182 degrees Celsius, present in an amount between about 0% and about 20% by weight.

53. The method of claim 36, wherein the solid phase composition further comprises an antioxidant in an amount between about 0.1% and about 1.0% by weight.

54. The method of claim 36, comprising forming the film into a plurality of extruded strands.

55. A garment having an elastomeric adhesive composition therein which is made by a process comprising:

forming a solid phase composition of between about 55% and about 63% by weight base polymer selected from the group consisting of polystyrene-polyethylene-polypropylene-polystyrene (SEPS) block copolymer, styrene-isoprene-styrene (SIS), styrene-butadiene-styrene (SBS) block copolymer, and combinations thereof and a high softening point tackifier resin which includes at least one type of hydrocarbon selected from a group consisting of petroleum distillates, rosin, rosin esters, polyterpenes deeerived from wood, polyterpenes derived from synthetic chemicals, and combinations thereof;

having a softening point of at least 80 degrees Celsius and a viscosity of at least 1500 cps at 182 degrees Celsius;

forming a liquid phase composition by heating the solid phase composition, wherein the liquid phase composition has a viscosity of about 5,000 to 80,000 cps at between 177 and 204 degrees Celsius;

forming a film by extruding the liquid phase composition onto a chill roll;

peeling the film off the chill roll while stretching the film; and

applying the film between first and second facing sheets, thereby permanently bonding the first and second facing sheets to one another and providing elasticity in the bonded area.