Diffusion barrier coatings having graded compositions and devices incorporating the same

• US 7,015,640 B2
• Filed: 09/11/2002
• Issued: 03/21/2006
• Est. Priority Date: 09/11/2002
• Status: Expired due to Term

• Current Assignee: BOE Technology Group Co., Ltd.
• Original Assignee: General Electric Company
• Inventors: Schaepkens, Marc, Flanagan, Kevin Warner
• Primary Examiner(s): Santiago, Mariceli
• Application Number:
  US10/065,018
• Publication Number:
  US 20040046497A1
• Time in Patent Office: 1,287 Days
• Field of Search: 313/498, 313502-512, 445/24, 428/690
• US Class Current: 313/506
• CPC Class Codes: B82Y 20/00 Nanooptics, e.g. quantum optics or photonic crystals
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: C23C 16/30 Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
• CPC Class Codes: G02F 1/133305 Flexible substrates, e.g. plastics, organic film
• CPC Class Codes: G02F 2201/50 Protective arrangements
• CPC Class Codes: H10K 2101/80 Composition varying spatially, e.g. having a spatial gradient
• CPC Class Codes: H10K 2102/311 Flexible OLED
• CPC Class Codes: H10K 2102/331 Nanoparticles used in non-emissive layers, e.g. in packaging layer
• CPC Class Codes: H10K 50/125 specially adapted for multicolour light emission, e.g. for emitting white light
• CPC Class Codes: H10K 50/844 Encapsulations
• CPC Class Codes: H10K 50/854 comprising scattering means
• CPC Class Codes: H10K 59/877 comprising scattering means
• CPC Class Codes: Y10T 428/12021 having composition or density gradient or differential porosity
• CPC Class Codes: Y10T 428/1321 Polymer or resin containing [i.e., natural or synthetic]
• CPC Class Codes: Y10T 428/1352 Polymer or resin containing [i.e., natural or synthetic]
• CPC Class Codes: Y10T 428/24802 Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
• CPC Class Codes: Y10T 428/31667 Next to addition polymer from unsaturated monomers, or aldehyde or ketone condensation product

Abstract

A composite article comprises a substrate having at least a substrate surface and a graded-composition coating disposed on a substrate surface. The composition of the coating material varies substantially continuously across its thickness. The coating reduces the transmission rates of oxygen, water vapor, and other chemical species through the substrate such that the composite article can be used effectively as a diffusion barrier to protect chemically sensitive devices or materials. An organic light-emitting device incorporates such a composite article to provide an extended life thereto.

Claims

1. A light-emitting device comprising:

a flexible substantially transparent substrate having a first substrate surface and a second substrate surface, at least one of said substrate surface being coated with a graded-composition barrier coating comprising an inorganic and an organic material, a composition of which varies substantially continuously across a thickness thereof; and

an organic electroluminescent (“

EL”

) member which comprises an organic EL layer disposed between two electrodes and is disposed on said flexible substantially transparent substrate.

2. The light-emitting device according to claim 1 further comprising a substantially transparent film having a second graded-composition barrier coating disposed thereon, said substantially transparent film being disposed on said organic EL member opposite to said flexible transparent substrate.

3. The light-emitting device according to claim 1, wherein said flexible substantially transparent substrate comprises a polymeric material selected from the group consisting of polyethyleneterephthalate, polyacrylates, polycarbonate, silicone, epoxy resins, silicone-functionalized epoxy resins, polyester, polyimide, polyetherimide, polyethersulfone, polyethyelenenapthalene, polynorbonene, and poly(cyclic olefins).

4. The light-emitting device according to claim 1, wherein said coating material is selected from the group consisting of organic, inorganic, ceramic materials, and combinations thereof.

5. The light-emitting device according to claim 4, wherein said inorganic and ceramic materials are selected from the group consisting of oxide, nitride, carbide, boride, and combinations thereof of elements of Groups IIA, IIIA, IVA, VA, VIA, VIIA, IB, and IIB, metals of Groups IIIB, IVB, and VB, and rare-earth metals.

6. The light-emitting device according to claim 1 further comprising a reflective layer disposed on said organic EL layer, said reflective layer comprising a material selected from the group consisting of metals, metal oxides, metal nitrides, metal carbides, metal oxynitrides, metal oxycarbides, and combinations thereof.

7. The light-emitting device according to claim 1, wherein said organic EL layer comprises a material selected from the group consisting of poly(n-vinylcarbazole), poly(alkylfluorene), poly(paraphenylene), polysilanes, derivatives thereof, mixtures thereof and copolymers thereof.

8. The light-emitting device according to claim 1, wherein said organic EL layer comrprises a material selected from the group consisting of 1,2,3-tris{n-(4-diphenylaminophenyl) phenylamino}benzene, phenylanthracene, tetraarylethene, coumarin, rubrene, tetraphenylbutadiene, anthracene, perylene, coronene, aluminum-(picolymethylketone)-bis{2,6-di(t-butyl)phenoxides}, scandium-(4-methoxy-picolymethylketone)-bis(acetylacetonate), aluminum-acetylacetonate, gallium-acetylacetonate, and indium-acetylacetonate.

9. The light-emitting device according to claim 1 further comprising a light-scattering layer, said layer comprising scattering particles dispersed in a substantially transparent matrix and being disposed on a surface of said substrate opposite to said organic EL member.

10. The light-emitting device according to claim 9 further comprising particles of a photoluminescent (“

PL”

) material mixed with scattering particles in said light-scattering layer, wherein said PL material is selected from the group consisting of (Y<sub>1−

x</sub>CE_x)₃Al₅O₁₂;

(Y<sub>1−

x−

y</sub>Gd_xCe_y)₃Al₅O₁₂;

(Y<sub>1−

x</sub>Ce_x)₃(Al<sub>1−

y</sub>Ga_y)O₁₂;

(Y<sub>1−

x−

y</sub>Gd_xCe_y)(Al<sub>5−

z</sub>Ga_z)O₁₂;

(Gd<sub>1−

x</sub>Ce_x)Sc₂Al₃O₁₂;

Ca₈Mg(SiO₄)₄Cl₂;

Eu²⁺,Mn²⁺;

GdBO₃;

Ce³⁺,Tb³⁺;

CeMgAl₁₁O₁₉;

Tb³⁺;

Y₂SiO₅;

Ce<sup>3+,Tb3+;

BaMg</sup>₂Al₁₆O₂₇;

Eu²⁺,Mn²⁺;

Y₂O₃;

Bi³⁺,Eu³⁺;

Sr₂P₂O_7;

Eu²⁺,Mn²⁺;

SrMgP₂O₇;

Eu²⁺,Mn²⁺;

(Y, Gd)(V, B)O₄;

Eu³⁺;

3.5MgO0.5MgF₂GeO₂;

Mn⁴⁺ (magnesium fluorogemanate);

BaMg₂Al₁₆O₂₇;

Eu²⁺;

Sr₅(PO₄)₁₀Cl₂;

Eu²⁺;

(Ca, Ba, Sr)(Al, Ga)₂S₄;

Eu²⁺;

(Ba, Ca, Sr)₅(PO₄)₁₀(Cl, F)₂;

Eu²⁺,Mn²⁺;

Lu₃Al₅O₁₂;

Ce³⁺;

Tb₃Al₅O₁₂;

Ce³⁺; and

mixtures thereof;

wherein 0≦

x≦

1,0≦

y≦

1, 0≦

z≦

5 and x+y≦

1.

11. The light-emitting device according to claim 9 further comprising at least an organic PL material dispersed in said scattering layer, said organic PL material being capable of absorbing at least a portion of electromagnetic (“

EM”

) radiation emitted by said organic EL material and emitting EM radiation in a visible spectrum.

12. The light-emitting device according to claim 1, wherein said organic EL member further comprises at least an additional layer disposed between one of said electrodes and said organic EL layer, said additional layer performing at least a function selected from the group consisting of electron injection enhancement, electron transport enhancement, hole injection enhancement, and hole transport enhancement.

13. The light-emitting device according to claim 1 wherein the composition of said graded-composition barrier coating varies across a thickness thereof such that a graph of the percent composition of one of the components of the coating versus the depth of the coating has plural peaks.

14. The light-emitting device according to claim 13 wherein said plural peaks are substantially the same height.

15. The light-emitting device according to claim 13 wherein the plurality of peaks is at least three.

16. The light-emitting device according to claim 15 wherein the height of the peaks changes as a function of depth.

17. A light-emitting device comprising:

a flexible substantially transparent substrate having a first substrate surface and a second substrate surface, at least one of said substrate surface being coated with a graded-composition barrier coating comprising an inorganic and an organic material, a composition of which varies substantially continuously across a thickness thereof; and

an organic electroluminescent (“

EL”

) member which comprises an organic EL layer disposed between two electrodes and is disposed on said flexible substantially transparent substrate;

wherein said flexible substantially transparent substrate comprises a polymeric material selected from the group consisting of polyethyleneterephthalate, polyacrylates, polycarbonate, silicone, epoxy resins, silicone-functionalized epoxy resins, polyester, polyimide, polyetherimide, polyethersulfone, polyethylenenapthalene, polynorbonene, and poly(cyclic olefins);

said coating material is selected from the group consisting of organic, inorganic, ceramic materials, and combinations thereof; and

said organic EL layer comprises a material selected from the group consisting of poly(n-vinylcarbazole), poly(alkylfluorene), poly(paraphenylene), polysilanes, derivatives thereof, mixtures thereof copolymers thereof, 1,2,3-tris{n-(4diphenylaminophenyl) phenylamino }benzene, phenylanthracene, tetraarylethene, coumarin, rubrene, tetraphenylbutadiene, anthracene, perylene, coronene, aluminum-(picolymethylketone)-bis{2,6-di(t-butyl)phenoxides}, scandium-(4-methoxy-picolymethylketone)-bis(acetylacetonate), aluminum-acetylacetonate, gallium-acetylacetonate, and indium-acetylacetonate.

18. A light-emitting device comprising:

a flexible substantially transparent substrate having a first substrate surface and a second substrate surface, at least one of said substrate surface being coated with a graded-composition barrier coating comprising an inorganic and an organic material, a composition of which varies substantially continuously across a thickness thereof;

an organic electroluminescent (“

EL”

) member which comprises an organic EL layer disposed between two electrodes and is disposed on said flexible substantially transparent substrate;

a reflective layer disposed on said organic EL member opposite to said substrate; and

a substantially transparent film having second graded-composition barrier coating disposed on said reflective layer opposite to said organic EL member;

wherein said flexible substantially transparent substrate and said substantially transparent film comprise a polymeric material selected from the group consisting of polyethyleneteraphthalate, polyacrylates, polycarbonate, silicone, epoxy resins, silicone-funcationalized epoxy resins, polyester, polyimide, polyetherimide, polyethersulfone, polyethylenenapthalene, polynorbonene, and poly(cyclic olefins);

said first and second graded-composition baffler coating material comprise a material independently selected from the group consisting of organic, inorganic, ceramic materials, and combinations thereof; and

said organic EL layer comprises a material selected from the group consisting of poly(n-vinylcarbazole), poly(alkylfluorene), poly(paraphenylene), polysilanes, derivatives thereof, mixtures thereof, copolymers thereof, 1,2,3-tris{n-(4-diphenylaminophenyl)phenylamino}benzene, phenylanthracene, tetraarylethene, coumarin, rubrene, tetraphenylbutadiene, anthracene, perylene, coronene, aluminum-(picolymethylketone)-bis{2,6-di(t-butyl)phenoxides}, scandium-(4-methoxy-picolymethylketone)-bis(acetylacetonate), aluminum-acetylacetonate, gallium-acetylacetonate, and indium-acetylacetonate.

19. The light-emitting device according to claim 18 further comprising a scattering layer disposed on said substantially transparent substrate opposite to said organic EL member, said scattering layer comprising scattering particles and particles of a PL material dispersed in a substantially transparent matrix.

20. A method for making a light-emitting device, said method comprising:

providing a flexible substantially transparent substrate having a first substrate surface and a second substrate surface, at least one of said substrate surface being coated with a first graded-composition barrier coating comprising an inorganic and an organic material, a composition of which varies substantially continuously across a thickness thereof; and

disposing an organic EL member which comprises an organic EL layer disposed between two electrodes on said flexible substantially flexible substrate.

21. The method for making a light-emitting device according to claim 20, wherein said disposing said organic EL member comprises forming a first electrode by depositing a first electrically conducting material on said graded-composition barrier coating;

depositing said organic EL layer on said first electrode; and

forming a second electrode by depositing a second electrically conducting material on said organic EL layer.

22. The method for making a light-emitting device according to claim 20 further comprising disposing a reflective layer on said organic EL member opposite to said substantially transparent substrate.

23. The method for making a light-emitting device according to claim 22 further comprising disposing a substantially transparent film that is coated with a second graded-composition barrier coating on said reflective layer.

24. The method for making a light-emitting device according to claim 20 further comprising disposing a scattering layer on a surface of said substrate, said EM-radiaition conversion layer comprising particles of a PL material dispersed in a substantially transparent matrix.

25. The method for making a light-emitting device according to claim 20, further comprising disposing a second graded-barrier coating on said organic EL member opposite to said substantially transparent substrate.

26. The method for making a light-emitting device according to claim 20, further comprising disposing a second flexible substrate on said organic EL member, said second substrate having a second graded-composition barrier coating thereon.

27. A method for making a light-emitting device, said method comprising:

providing a flexible substantially transparent substrate having a first substrate surface and a second substrate surface;

depositing a first graded-composition barrier coating comprising an inorganic and an organic material on at least one of said substrate surface, a composition of said first barrier coating varying substantially continuously across a thickness thereof, said depositing being carried out by a method selected from the group consisting of plasma-enhanced chemical-vapor deposition, radio-frequency plasma-enhanced chemical-vapor deposition, expanding thermal-plasma chemical-vapor deposition, sputtering, reactive sputtering, electron-cyclotron-resonance plasma-enhanced chemical-vapor deposition, and inductively-coupled plasma-enhanced chemical-vapor deposition;

disposing an organic EL member which comprises an organic EL layer disposed between two electrodes on said flexible substantially flexible substrate; and

disposing a substantially transparent film that is coated with a second graded-composition barrier coating on said organic EL member, said second graded-composition barrier coating having a composition that varies substantially continuously across a thickness thereof and being deposited on said film by a method selected from the group consisting of plasma-enhanced chemical-vapor deposition, radio-frequency plasma-enhanced chemical-vapor deposition, expanding thermal-plasma chemical-vapor deposition, sputtering, reactive sputtering, electron-cyclotron-resonance plasma-enhanced chemical-vapor deposition, and inductively-coupled plasma-enhanced chemical-vapor deposition, and combinations thereof.

28. The method for making a light-emitting device according to claim 27 further comprising disposing a reflective layer between said organic EL member and said coated substantially transparent film.

29. A method for making a light-emitting device, said method comprising:

providing a flexible substantially transparent substrate having a first substrate surface and a second substrate surface;

depositing a first graded-composition barrier coating comprising an inorganic and an organic material on at least one of said substrate surface, a composition of said first barrier coating varying substantially continuously across a thickness thereof, said depositing being carried out by a method selected from the group consisting of plasma-enhanced chemical-vapor deposition, radio-frequency plasma-enhanced chemical-vapor deposition, expanding thermal-plasma chemical-vapor deposition, sputtering, reactive sputtering, electron-cyclotron-resonance plasma-enhanced chemical-vapor deposition, and inductively-coupled plasma-enhanced chemical-vapor deposition;

disposing an organic EL member which comprises an organic EL layer disposed between two electrodes on said flexible substantially flexible substrate; and

disposing a substantially transparent film that is coated with a second graded-composition barrier coating on said organic EL member, said second graded-composition barrier coating having a composition that varies substantially continuously across a thickness thereof and being deposited on said film by a method selected from the group consisting of plasma-enhanced chemical-vapor deposition, radio-frequency plasma-enhanced chemical-vapor deposition, expanding thermal-plasma chemical-vapor deposition, sputtering, reactive sputtering, electron-cyclotron-resonance plasma-enhanced chemical-vapor deposition, inductively-coupled plasma-enhanced chemical-vapor deposition, and combinations thereof;

wherein said depositing a first graded-composition barrier coating on at least one of said substrate surface is carried out such that at least a portion of a material of said coating penetrates into said substrate.