Capillary devices for determination of surface characteristics and contact angles and methods for using same

• US 7,024,921 B2
• Filed: 11/06/2003
• Issued: 04/11/2006
• Est. Priority Date: 11/06/2002
• Status: Expired due to Fees

• Current Assignee: Stephen P. Sutton
• Original Assignee: Stephen P. Sutton
• Inventors: Sutton, Stephen P.
• Primary Examiner(s): Garber, Charles
• Application Number:
  US10/703,107
• Publication Number:
  US 20040187565A1
• Time in Patent Office: 887 Days
• Field of Search: 73/540.4, 73/540.5, 73/540.6, 73/540.7, 73/540.8, 73/540.9, 73/644.8, 73/645.2
• US Class Current: 73/54.04
• CPC Class Codes: G01N 13/02 Investigating surface tension of liquids
• CPC Class Codes: G01N 2013/0208 by measuring contact angle

Abstract

Devices are presented which allow determination of unknown surface properties through the creation of a channel capillary, comprised in part of the subject surface or surfaces, and measurement of the capillary pressure created by a test fluid within the resultant channel. In various embodiments of the invention, a channel is created in a reference material which is bonded, through some mechanism, to the test surface in order to create a narrow capillary channel. In other embodiments of the invention, the capillary channel is created with test surfaces on either side of standoff strips which space the surfaces a precise distance from one another. Methods are presented for using these capillaries through immersion, along their length, in a bath of test fluid, such that the resultant fluid level provides a measure of capillary pressure. Being, in part, a consequence of the contact angle between the test fluid and the surface or surfaces under consideration, the capillary pressure is a convenient measure of surface properties inherently related to printability, affinity for adhesives, surface contamination by foreign substances, surface roughness, and the like. Devices are presented which allow measurement of test fluid height within the capillary, both in situations where a static equilibrium is achieved, and in situations where a dynamic contact angle is operative as the fluid rises or falls within the capillary.

Claims

1. A reference channel capillary device comprising:

an open capillary channel embedded within a surface of a supportive materials system, the capillary channel having a cross sectional geometry sufficient to create an open channel, the capillary device being configured to form a closed capillary against an adjacent surface, wherein said supportive materials system comprises a thermoplastic elastomer plasticized with mineral oil.

2. A reference channel capillary device as defined in claim 1, wherein the surface in which the open capillary channel is embedded is configured to adhere to an adjacent surface.

3. A reference channel capillary device as defined in claim 2, wherein the surface in which the open capillary channel is embedded includes an adhesive coating.

4. A reference channel capillary device as defined in claim 2, wherein the supportive materials system comprises a polymer having adhesive properties that enables the surface of the supportive materials system to adhere to an adjacent surface.

5. A reference channel capillary device as defined in claim 1, wherein the open capillary channel is embedded within a planar surface.

6. A reference channel capillary device as defined in claim 1, wherein the open capillary channel is embedded within a curved surface.

7. A reference channel capillary device as defined in claim 1, wherein the open capillary channel is embedded within a planar surface and has a rectangular cross section with a depth of less than about 0.020 inches and a width greater than 10 times the depth.

8. A reference channel capillary device as defined in claim 1, wherein the supportive materials system is made from a polymer.

9. A reference channel capillary device as defined in claim 1, wherein the supportive materials system comprises glass.

10. A reference channel capillary device as defined in claim 1, wherein the supportive materials system comprises a ceramic material.

11. A reference channel capillary device as defined in claim 1, wherein the supportive materials system comprises a metal.

12. A reference channel capillary device as defined in claim 1, wherein the supportive materials system comprises a semiconductor.

13. A reference channel capillary device as defined in claim 1, wherein the device is transparent or translucent.

14. A reference channel capillary device as defined in claim 1, wherein a surface of the capillary channel is coated with a layer of material through electrodeposition, evaporation, sputtering, plasma treatment, or chemical vapor deposition.

15. A reference channel capillary device as defined in claim 1, wherein a surface of the capillary channel comprises a polymer which is bonded to the supportive materials system.

16. A reference channel capillary device as defined in claim 1, wherein the supportive materials system is made from a material comprising a styrene ethylene-butylene styrene block copolymer.

17. A reference channel capillary device as defined in claim 16, wherein the styrene ethylene-butylene styrene block copolymer is mixed with a mineral oil and a paraffin wax.

18. A reference channel capillary device comprising:

an open capillary channel embedded within a supportive materials system, the capillary channel having a cross sectional geometry sufficient to create an open channel, the capillary device being configured to form a closed capillary against an adjacent surface, the capillary device further being configured to be placed against a curved adjacent surface for forming the closed capillary, the supportive materials system being made from a material comprising a thermoplastic elastomer plasticized with mineral oil.

19. A reference channel capillary device as defined in claim 18, wherein the device is transparent or translucent.

20. A reference channel capillary device as defined in claim 18, wherein a surface of the capillary channel is coated with a layer of material through electrodeposition, evaporation, sputtering, plasma treatment, or chemical vapor deposition.

21. A reference channel capillary device as defined in claim 18, wherein a surface of the capillary channel comprises a polymer which is bonded to the supportive materials system.

22. A reference channel capillary device comprising:

an open capillary channel defined by a planar surface of a supportive materials system, the capillary device being configured to form a closed capillary against an adjacent planar surface, the capillary channel having a rectangular cross section with a depth of less than about 0.02 inches and a width greater than about 10 times the depth, the supportive materials system being made from a material comprising a polymer, a glass, a semiconductor, a ceramic, a metal, a thermoplastic elastomer plasticized with mineral oil, or mixtures thereof.

23. A reference channel capillary device as defined in claim 22, wherein the device is transparent or translucent.

24. A reference channel capillary device as defined in claim 22, wherein a surface of the capillary channel is coated with a layer of material through electrodeposition, evaporation, sputtering, plasma treatment, or chemical vapor deposition.

25. A reference channel capillary device as defined in claim 22, wherein a surface of the capillary channel comprises a polymer which is bonded to the supportive materials system.

26. A spacer wall capillary device comprising a first spacer element spaced from a second spacer element, the spacer elements being configured to be attached to two opposing adjacent surfaces, the spacer elements holding the surfaces apart thereby producing a capillary, said spacer elements comprise a thermoplastic elastomer plasticized with mineral oil.

27. A spacer wall capillary device, as defined in claim 26, wherein the spacer elements have a thickness of less than about 0.020 inches.

28. A spacer wall capillary device as defined in claim 26, wherein the two spacer elements are initially held some distance apart by a support to facilitate application and creation of a capillary between parallel surfaces.

29. A spacer wall capillary device as defined in claim 26, wherein the spacer elements are made from a material comprising sheets of a polymer, a metal, a ceramic, a glass, or a semiconductor.