Modification of surfaces in order to increase the surface tension

• US 7,025,836 B1
• Filed: 01/23/2001
• Issued: 04/11/2006
• Est. Priority Date: 12/04/1997
• Status: Expired due to Term

• Current Assignee: Roche Diagnostics GmbH (Roche Holding AG)
• Original Assignee: Roche Diagnostics GmbH (Roche Holding AG)
• Inventors: Zimmer, Volker, Braun, Hans-Peter
• Primary Examiner(s): Ip, Sikyin
• Application Number:
  US09/555,618
• Time in Patent Office: 1,904 Days
• Field of Search: 148/277, 73/644.8, 73/645.2
• US Class Current: 148/277
• CPC Class Codes: C23C 14/5853 Oxidation
• CPC Class Codes: C23C 22/68 using aqueous solutions with pH between 6 and 8
• CPC Class Codes: C23C 8/02 Pretreatment of the material to be coated C23C8/04 takes precedence

Abstract

A process is provided for the production of a surface coating as well as the use of surface coatings to increase the surface tension of objects. The surface coating is obtained by depositing a layer of at least one element that can be oxidized with water or an alloy that can be oxidized with water. Subsequently, the deposited layer is subjected to boiling water or water vapor. The element is generally derived from the following group of elements: Al, Si, Ti, V, Cr, Mn, Fe, Co, Ni, Zn, Ga, Ge, Zr, Nb, Cd, In, Sn, Sb.

Claims

1. Method of increasing the surface tension of at least one solid object, the method comprising the steps of:

providing at least a portion of an analytical test element that is formed to transport a sample liquid from a sample application site to a determination site, the test element including a polyester foil having a surface of an element that can be oxidized with water or an alloy that can be oxidized with water that defines the at least one solid object having a surface,

depositing a layer of at least one element that can be oxidized with water or an alloy that can be oxidized with water on the surface of the polyester foil that defines the solid object to form a deposited layer, and

subsequently applying boiling water or water vapour on the deposited layer, whereby the resulting deposited layer is solid and more hydrophilic than the surface of the polyester foil that defines the solid object.

2. Method of claim 1, wherein the element is derived from at least one element selected from the group consisting of Al, Si, Ti, V, Cr Mn, Fe, Co, Ni, Zn, Ga, Ge, Zr, Nb, Cd, In, Sn, Sb.

3. Method of claim 2, wherein the element is derived from at least one element selected from the group consisting of Al, Si, Ti, Zr.

4. Method of claim 3, wherein the element is Al.

5. Method of claim 1, wherein the alloy contains at least two components selected from the group of elements consisting of Al, Si, Ti, V, Cr, Mn, Fr, Co, Ni, Zn, Ga, Ge, Zr, Nb, Cd, In, Sn, Sb.

6. Method of claim 1, wherein the alloy contains at least one component selected from a first group of elements consisting of Al, Si, Ti, V, Cr, Mn, Fe, Co, Ni, Zn, Ga, Ge, Zr, Nb, Cd, In, Sn, Sb, which are alloyed with at least one element selected from a second group of elements consisting of Mg, Ca, Sr, Ba.

7. Method of claim 6, wherein the alloy contains at least one component selected from a first group consisting of Al, Si, Ti, Zr, which is alloyed with at least one element selected from a second group consisting of Mg, Ca, Sr, Ba.

8. Method of claim 7, wherein the alloy is composed of Al which is alloyed with at least one element selected from the group consisting of Mg, Ca, Sr, Ba.

9. Method of claim 1, wherein the deposited layer has a thickness between 1 nm and 500 nm.

10. Method of claim 1, wherein the oxide layer has a thickness between 0.1 nm and 500 nm.

11. Method of claim 10, wherein the oxide layer has a thickness between 10 nm and 100 nm.

12. Method of claim 2, wherein the deposited layer has a thickness between 1 nm and 500 nm.

13. Method of claim 2, wherein the oxide layer has a thickness between 0.1 nm and 500 nm.

14. Method of claim 5, wherein the deposited layer has a thickness between 1 nm and 500 nm.

15. Method of claim 5, wherein the oxide layer has a thickness between 0.1 nm and 500 nm.

16. Method of claim 6, wherein the deposited layer has a thickness between 1 nm and 500 nm.

17. Method of claim 6, wherein the oxide layer has a thickness between 0.1 nm and 500 nm.

18. Method of increasing the surface tension of at least one solid object, the method comprising the steps of:

providing at least a portion of an analytical test element that is formed to transport a sample liquid from a sample application site to a determination site, the test element including a polyester foil having a surface of an element that can be oxidized with water or an alloy that can be oxidized with water that defines the at least one solid object having a surface,

depositing on the surface of the polyester foil a layer of at least one element that can be oxidized with water or an alloy that can be oxidized with water and

subsequently applying superheated water vapour to the deposited layer, whereby the resulting deposited layer is solid and more hydrophilic than the surface of the polyester foil the defines the solid object.

19. Method of claim 18, wherein the element is derived from the elements selected from the group consisting of Al, Si, Ti, V, Cr, Mn, Fe, Co, Ni, Zn, Ga, Ge, Zr, Nb, Cd, In, Sn, Sb.

20. Method of claim 18, wherein the alloy contains at least two components selected from elements in the group consisting of Al, Si, Ti, V, Cr, Mn, Fe, Co, Ni, Zn, Ga, Ge, Zr, Nb, Cd, In, Sn, Sb.

21. Method of claim 18, wherein the alloy contains at least one component selected from a first group consisting of Al, Si, Ti, V, Cr, Mn, Fe, Co, Ni, Zn, Ga, Ge, Zr, Nb, Cd, In, Sn, Sb.

22. Method of claim 18, wherein the deposited layer has a thickness between 1 nm and 500 nm.

23. Method of claim 18, wherein the oxide layer has a thickness between 0.1 nm and 500 nm.