Methods of controlling nanoparticle growth

• US 7,033,415 B2
• Filed: 04/02/2004
• Issued: 04/25/2006
• Est. Priority Date: 04/02/2003
• Status: Expired due to Fees

• Current Assignee: Northwestern University
• Original Assignee: Northwestern University
• Inventors: Mirkin, Chad A., Jin, Rongchao, Cao, YunWei Charles, Métraux, Gabriella S.
• Primary Examiner(s): WYSZOMIERSKI, GEORGE P
• Application Number:
  US10/817,754
• Publication Number:
  US 20050188789A1
• Time in Patent Office: 753 Days
• Field of Search: None
• US Class Current: 75/345
• CPC Class Codes: B22F 1/052 characterised by a mixture of particles of different sizes or by the particle size distribution
• CPC Class Codes: B22F 1/054 Nanosized particles
• CPC Class Codes: B22F 1/0545 Dispersions or suspensions of nanosized particles
• CPC Class Codes: B22F 1/0553 Complex form nanoparticles, e.g. prism, pyramid, octahedron
• CPC Class Codes: B22F 2202/11 Use of irradiation
• CPC Class Codes: B22F 2998/00 Supplementary information concerning processes or compositions relating to powder metallurgy
• CPC Class Codes: B22F 2999/00 Aspects linked to processes or compositions used in powder metallurgy
• CPC Class Codes: B22F 9/24 starting from liquid metal compounds, e.g. solutions
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites

Abstract

The invention provides new types of plasmon-driven growth mechanism for silver nanostructures involving the fusion of triangular nanoprisms. This mechanism, which is plasmon excitation-driven and highly cooperative, produces bimodal particle size distributions. In these methods, the growth process can be selectively switched between bimodal and unimodal distributions using dual beam illumination of the nanoparticles. This type of cooperative photo-control over nanostructure growth enables synthesis of monodisperse nanoprisms with a preselected edge length in the 30–120 nm range simply by using one beam to turn off bimodal growth and the other (varied over the 450–700 nm range) for controlling particle size.

Claims

1. A method of forming nanoprisms comprising exposing silver particles to light having a narrow band of wavelengths in the range of between about 400 nm and about 700 nm, said wavelengths capable of exciting a dipole plasmon mode of the silver particles to form silver nanoprisms having a bimodal size distribution.

2. The method of claim 1, wherein the silver particles are present in a colloid.

3. The method of claim 2, wherein the colloid comprises a reducing agent.

4. The method of claim 3, wherein the reducing agent is NaBH₄.

5. The method of claim 2, wherein the colloid comprises a stabilizing agent.

6. The method of claim 5, wherein the stabilizing agent is bis(p-sulfonatophenyl)phenylphospine dehydrate dipotassium.

7. The method of claim 2, wherein the colloid comprises a stabilizing agent and a surfactant.

8. The method of claim 7, wherein the surfactant is trisodium citrate.

9. The method of claim 7, wherein the ratio of the stabilizing agent to the surfactant is about 0.3:

1.

10. The method of claim 1, wherein the silver particles have a diameter of less than about 15 nm.

11. The method of claim 1, wherein the silver particles have a diameter of less than about 10 nm.

12. The method of claim 1, wherein the silver particles have a diameter of between about 2 nm and about 6 nm.

13. The method of claim 1, wherein the silver particles have a diameter of about 4.8 nm.

14. The method of claim 1, wherein the nanoprisms are single crystalline.

15. The method of claim 1, wherein the nanoprisms have a {111} crystal face on a base plane of the nanoprism and a {110} crystal face on a side plane of the nanoprism.

16. The method of claim 1, wherein the step of exposing is conducted for a period of less than about 60 hours.

17. The method of claim 1, wherein the wavelength of the light is in the range of between about 530 nm and about 570 nm.

18. The method of claim 1, wherein the wavelength of the light is about 550 nm.

19. The method of claim 1, wherein the wavelength of light is about 532.8 nm.

20. The method of claim 1, wherein the silver nanoprisms display plasmon bands having λ

max at 640 nm and 1065 nm.

21. The method of claim 1, wherein the silver nanoprisms display plasmon bands having λ

max at 340 nm and 470 nm.

22. The method of claim 1, wherein the silver nanoprisms display a plasmon band having λ

max at 640 nm.

23. A method of forming a nanoprism comprising exposing silver particles to a primary and a secondary wavelength of light and exciting a dipole plasmon mode in the silver particles with the primary wavelength of light and a quadrupole resonance mode of the nanoprism with the secondary wavelength of light to form silver nanoprisms having a unimodal size distribution, wherein the primary and secondary wavelengths of light comprise narrow bands of wavelengths of light.

24. The method of claim 23, wherein the secondary wavelength of light is about 340 nm.

25. The method of claim 24, wherein the primary wavelength of light is in the range of about 450 nm and about 700 nm.

26. The method of claim 25, wherein the primary wavelength of light is in the range of about 430 nm and about 470 nm and the nanoprisms have an edge length between about 31 nm and about 45 nm.

27. The method of claim 25, wherein the primary wavelength of the light is in the range of about 470 nm and about 510 nm and the nanoprisms have an edge length between about 53 nm and about 57 nm.

28. The method of claim 25, wherein the primary wavelength of the light is in the range of about 500 nm and about 540 nm and the nanoprisms have an edge length between about 53 nm and about 71 nm.

29. The method of claim 25, wherein the primary wavelength of light is in the range of about 530 nm and about 570 nm and the nanoprisms have an edge length between about 64 nm and about 80 nm.

30. The method of claim 25, wherein the primary wavelength of light is in the range of about 580 nm and about 620 nm and the nanoprisms have an edge length between about 84 nm and 106 nm.

31. The method of claim 25, wherein the primary wavelength of light is in the range of about 650 nm and about 690 nm and the nanoprisms have an edge length between about 106 nm and 134 nm.