Process and composition for making multi-layer golf balls using rigid uncrosslinked shells

• US 7,033,532 B2
• Filed: 11/25/2003
• Issued: 04/25/2006
• Est. Priority Date: 03/26/1998
• Status: Expired due to Fees

• Current Assignee: Acushnet Company (FILA Holdings Corp.)
• Original Assignee: Acushnet Company (FILA Holdings Corp.)
• Inventors: Bissonnette, Laurent C., Pasqua, Samuel A. Jr., Desimas, Antonio U.
• Primary Examiner(s): Lee, Edmund H.
• Application Number:
  US10/720,137
• Publication Number:
  US 20040106468A1
• Time in Patent Office: 882 Days
• Field of Search: 264/248, 264/250, 264/279.1, 264/320, 264/328.1
• US Class Current: 264/248
• CPC Class Codes: A63B 2225/30 Maintenance
• CPC Class Codes: A63B 37/0003 Golf balls
• CPC Class Codes: A63B 37/0051 Materials other than polybutadienes; Constructional details
• CPC Class Codes: A63B 37/0052 Liquid cores
• CPC Class Codes: A63B 37/0069 Flexural modulus; Bending stiffness
• CPC Class Codes: A63B 37/0076 Multi-piece balls, i.e. having two or more intermediate layers
• CPC Class Codes: A63B 37/0086 Flexural modulus; Bending stiffness
• CPC Class Codes: B29C 43/18 incorporating preformed parts or layers, e.g. compression moulding around inserts or for coating articles B29C43/206 takes precedence
• CPC Class Codes: B29D 99/0042 Producing plain balls hollow balls B29D22/04
• CPC Class Codes: B29L 2031/54 Balls
• CPC Class Codes: B29L 2031/546 Golf balls
• CPC Class Codes: C08F 285/00 Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 51/04 grafted on to rubbers
• CPC Class Codes: C08L 53/00 Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 53/02 of vinyl-aromatic monomers and conjugated dienes

Abstract

A multi-layer golf ball and methods for preparing a portion thereof including a core having at least one core layer, a mantle having at least one layer including an amount of reinforcing polymer component and a resilient polymer component disposed concentrically adjacent the core, and at least one cover layer disposed concentrically adjacent the mantle, wherein the layer of the mantle is sufficiently rigid to inhibit the resilient polymer component from substantially altering shape prior to crosslinking. The invention also includes an elastomeric composition including a polybutadiene having a high molecular weight average and a predominantly 1,4-cis content, a free-radical initiator, and a reinforcing polymer component having a sufficiently low viscosity at a mixing temperature to permit substantially uniform dispersion of the polymer component with the polybutadiene and having a crystalline melting point sufficiently low to permit mixing while avoiding substantial crosslinking.

Claims

1. A method of forming at least a portion of a golf ball core which comprises:

mixing a resilient polymer component, a free-radical initiator, and a reinforcing polymer component to provide an uncrosslinked first mixture having a flexural modulus greater than about 3.5 MPa;

forming the first mixture into a plurality of shells in a desired shape, wherein the reinforcing polymer component imparts sufficient rigidity to the shells to maintain the desired shape until the first mixture is crosslinked;

providing a center;

assembling at least two shells from the plurality of shells concentrically about the center to form a first mantle layer, wherein the first mantle layer and center together form the golf ball core; and

applying sufficient heat and pressure to the core for a time sufficient to at least partially crosslink the first mixture in the at least two shells, thereby curing at least a portion of the golf ball core.

2. The method of claim 1, wherein the step of forming the first mixture comprises forming the first mixture into a plurality of shells having an ellipsoidal shape.

3. The method of claim 1, which further comprises selecting the resilient polymer component to have a molecular weight average of between about 50,000 to 1,000,000.

4. The method of claim 1, which further comprises selecting the reinforcing polymer component to have a crystalline melting temperature between 35°

C. to 120°

C.

5. The method of claim 1, wherein the first mixture is formed into a plurality of shells by injection molding.

6. The method of claim 1, wherein the step of forming the first mixture into a plurality of shells in a desired shape comprises compression molding the first mixture.

7. The method of claim 1, wherein the golf ball core has a midpoint and the center of the core is disposed within about 0.5 mm from the midpoint.

8. The method of claim 1, which further comprises adjusting the flexural modulus of the uncrosslinked first mixture to at least about 7 MPa.

9. The method of claim 1, wherein the step of mixing a resilient polymer component, a free-radical initiator, and a reinforcing polymer component to provide an uncrosslinked first mixture further comprises selecting components to provide a crosslinked first mixture having a loss tangent of less than about 0.15 at −

60°

C. and less than about 0.05 at 30°

C. and a tensile storage modulus of greater than about 100 MPa at −

60°

C. and greater than about 50 MPa at 30°

C., each when measured at 1 Hz and one percent strain.

10. The method of claim 1, wherein the reinforcing polymer component has a melting temperature of about 35°

C. to about 120°

C.

11. The method of claim 1, wherein the golf ball core comprises a solid center or liquid center, and optionally comprises elastic windings about the solid center or liquid center.

12. The method of claim 1, which further comprises forming at least one additional layer about the center prior to assembling the at least two shells from the plurality of shells concentrically about the center, after assembling the at least two shells concentrically about the center, or after heating the golf ball core.

13. The method of claim 12, wherein the additional layer is formed around the core after heating the core to provide a cover disposed concentrically about the golf ball core.

14. A method of forming a golf ball, comprising:

mixing a resilient polymer component and a reinforcing polymer component to provide an uncrosslinked first mixture having a flexural modulus of greater than 3.5 MPa, wherein the reinforcing polymer component has a sufficiently low glass transition temperature to permit mixing of the reinforcing polymer component and the resilient polymer component while avoiding substantial crosslinking;

forming the first mixture into a plurality of shells in a desired shape, wherein the reinforcing polymer component imparts sufficient rigidity to the plurality of shells to maintain the desired shape until the first mixture is crosslinked;

providing a center;

assembling at least two shells from the plurality of shells concentrically about the center to form a first mantle layer, wherein the first mantle layer and center together form a golf ball core; and

applying sufficient heat and pressure to the golf ball core for a time sufficient to at least partially crosslink the first mixture in the at least two shells, thereby curing at least a portion of the golf ball core; and

forming a golf ball cover disposed about the golf ball core.

15. The method of claim 14, wherein the step of forming the golf ball cover comprises the steps of:

providing a cover material, wherein the cover material comprises urethane, balata, a partially neutralized ionomer, or a fully neutralized ionomer; and

forming the cover material about the golf ball core.

16. The method of claim 14, further comprising the steps of:

providing a crosslinking agent; and

mixing the crosslinking agent with the first mixture.

17. The method of claim 14, further comprising the steps of:

providing a free radical initiator; and

mixing the free radical initiator with the first mixture.

18. The method of claim 17, wherein the free-radical initiator is an organic peroxide.

19. The method of claim 14, wherein the reinforcing polymer component comprises a block copolymer ether/ester, an acrylic polyol, a transpolyisoprene, a transpolybutadiene, a 1,2-polybutadiene, an ethylene-vinyl acetate copolymer, a polyethylene or copolymer thereof, or a cyclooctene.

20. The method of claim 16, wherein the crosslinking agent comprises a metallic salt selected from the group consisting of an unsaturated fatty acid, a monocarboxylic acid, and mixtures thereof.