Method for detecting heat exchanger tube failures and their location when using input/loss performance monitoring of a recovery boiler
DCFirst Claim
1. A method for quantifying the operation of a recovery boiler burning black liquor fuel bearing sodium compounds through knowledge of when its heat exchanger leaks working fluid into the combustion gas path producing a tube leakage, the method for quantifying the operation comprising the steps of:
- monitoring the recovery boiler burning black liquor fuel bearing sodium compounds by one of the Input/Loss methods,developing a mathematical model of the combustion process incorporating terms commonly associated with black liquor fuel combustion including sodium compounds and terms associated with sources of working fluid flows into the combustion gas path including tube leakage resulting in a stoichiometric model of the combustion process, anddetermining the tube leakage based on the stoichiometric model of the combustion process resulting in a stoichiometrically determined tube leakage.
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Abstract
This invention relates to a recovery boiler as used by the pulp and paper industry burning black liquor, and, more particularly, to a method for rapid detection of tube failures and the location of the affect heat exchanger within the recovery boiler, without need for direct instrumentation, thereby preventing more serious equipment damage, preventing boiler explosion, preventing injury to operators and minimizing repair time on the affected heat exchanger. This method is applicable to Input/Loss methods of monitoring recovery boilers.
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Citations
74 Claims
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1. A method for quantifying the operation of a recovery boiler burning black liquor fuel bearing sodium compounds through knowledge of when its heat exchanger leaks working fluid into the combustion gas path producing a tube leakage, the method for quantifying the operation comprising the steps of:
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monitoring the recovery boiler burning black liquor fuel bearing sodium compounds by one of the Input/Loss methods, developing a mathematical model of the combustion process incorporating terms commonly associated with black liquor fuel combustion including sodium compounds and terms associated with sources of working fluid flows into the combustion gas path including tube leakage resulting in a stoichiometric model of the combustion process, and determining the tube leakage based on the stoichiometric model of the combustion process resulting in a stoichiometrically determined tube leakage. - View Dependent Claims (2, 3, 4)
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5. A method for quantifying the operation of a recovery boiler burning black liquor fuel bearing sodium compounds when being monitored by one of the Input/Loss methods through knowledge of when its heat exchanger leaks working fluid into the combustion gas path producing a tube leakage, the method for quantifying the operation comprising the steps of:
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developing a mathematical model of the combustion process incorporating terms commonly associated with the combustion of black liquor fuel including sodium compounds and terms associated with sources of working fluid flows into the combustion gas path including tube leakage resulting in a stoichiometric model of the combustion process, selecting a set of minimization techniques applicable to the recovery boiler burning black liquor fuel, and a set of routine inputs and convergence criteria to the minimization techniques, selecting a Choice Operating Parameter of tube leakage flow rate, selecting a set of routine Choice Operating Parameters, determining a set of System Effect Parameters applicable to the recovery boiler burning black liquor fuel whose functionalities are sensitive to tube leakage flow rate, determining a set of Reference System Effect Parameters applicable to the set of System Effect Parameters, determining an objective function which allows the minimization of differences between the set of System Effect Parameters and the set of Reference Systems Effect Parameters by optimizing the selection of Choice Operating Parameters, resulting in a mathematical model of the combustion process based on System Effect Parameters, and, wherein the step of determining the tube leakage comprises; minimizing the objective function resulting in a set of optimized Choice Operating Parameters including the tube leakage flow rate, and reporting the tube leakage flow rate such that corrective action may take place. - View Dependent Claims (6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21)
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22. A method for quantifying the operation of a thermal system burning a fossil fuel, including a recovery boiler, producing effluents from combustion when being monitored on-line by one of the Input/Loss methods, said effluents from combustion influenced by an air leakage, the method comprising the steps of:
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selecting one of the Input/Loss methods resulting in a selected Input/Loss method, selecting a set of effluent concentrations associated with the thermal system based on available instrumentation resulting in a set of available plant effluent concentrations, obtaining a ratio of effluent concentrations based on an effluent concentration obtained before the air leakage and on an effluent concentration obtained after the air leakage, resulting in an obtained ratio across the air leakage, and establishing an air pre-heater leakage factor which describes the effects of the air leakage into the thermal system based on the obtained ratio across the air leakage. - View Dependent Claims (23, 24, 25, 26, 27, 28, 29, 30)
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31. A method for quantifying the operation of a recovery boiler burning black liquor fuel when being monitored by one of the Input/Loss methods through knowledge of a stoichiometric mechanism of how a heat exchanger could be leaking a tube leakage flow rate into the combustion gas path, the method for quantifying the operation comprising the steps of:
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developing a mathematical model of the combustion process incorporating terms commonly associated with fossil fuel combustion and terms associated with sources of working fluid flows into the combustion gas path including tube leakage, obtaining a set of Choice Operating Parameters, obtaining a set of Reference Fuel Characteristics, obtaining a fuel chemistry of the fuel being combusted by the recovery boiler using one of the Input/Loss methods, the mathematical model of the combustion process;
the set of Choice Operating Parameters, and the set of Reference Fuel Characteristics, said fuel chemistry resulting in a set of fuel concentrations,establishing a set of concentration limits for each fuel constituent based on Reference Fuel Characteristics, testing the set of fuel concentrations against the set of concentration limits resulting in a trip mechanism indicating the stoichiometric reason how a heat exchanger leaks a tube leakage flow rate into the combustion gas path, and reporting the trip mechanism to the operator of the recovery boiler.
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32. A method for quantifying the operation of a recovery boiler burning black liquor fuel when being monitored by one of the Input/Loss methods through knowledge of a stoichiometric mechanism of how a heat exchanger could be leaking a tube leakage flow rate into the combustion gas path, the method for quantifying the operation comprising the steps of:
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developing a mathematical model of the combustion process incorporating terms commonly associated with fossil fuel combustion and terms associated with sources of working fluid flows into the combustion gas path including tube leakage, selecting a set of minimization techniques applicable to the recovery boiler burning black liquor fuel, processing a set of routine inputs and convergence criteria to the minimization techniques, assuming a tube leakage flow rate is zero, selecting a set of routine Choice Operating Parameters, determining a set of System Effect Parameters applicable to the recovery boiler burning black liquor fuel whose functionalities effect the determination of system efficiency, determining a set of Reference System Effect Parameters applicable to the set of System Effect Parameters, determining an objective function applicable to the recovery boiler, the set of routine Choice Operating Parameters, the set of System Effect Parameters and the set of Reference System Effect Parameters, optimizing the set of routine Choice Operating Parameters based on the mathematical model of the combustion process, the set of minimization techniques, and the objective function such that convergence is met resulting in a set of converged Choice Operating Parameters, determining a fuel chemistry of the fuel being combusted by the recovery boiler using one of the Input/Loss methods, the mathematical model of the combustion process, the set of converged Choice Operating Parameters, and Reference Fuel Characteristics resulting in a fuel elemental composition, a fuel ash fraction and a fuel water fraction said composition and fractions resulting in a set of fuel concentrations, establishing a set of concentration limits for the set of fuel concentrations based on Reference Fuel Characteristics, testing the set of fuel concentrations against the set of concentration limits resulting in a trip mechanism indicating the stoichiometric reason how a heat exchanger leaks a tube leakage flow rate into the combustion gas path, and reporting the trip mechanism to the operator of the recovery boiler. - View Dependent Claims (33)
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34. A method for quantifying the operation of a recovery boiler burning black liquor fuel in a combustion process through knowledge of when one of its heat exchangers, whose tubes contain working fluid heated by products of combustion, has a tube leak of working fluid mixing with the products of combustion, the method for quantifying the operation comprising the steps of:
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selecting a neural network technology applicable to the recovery boiler, selecting a set of routine inputs and database for the neural network technology, selecting a set of Choice Operating Parameters including tube leakage flow rate, and, wherein the step of determining the tube leakage comprises the step of; optimizing the set of Choice Operating Parameters including tube leakage flow rate using the neural network technology, and the set of routine inputs and database such that convergence is met resulting in a set of converged Choice Operating Parameters including a tube leakage flow rate, and reporting the tube leakage flow rate such that corrective action may take place. - View Dependent Claims (35, 36, 37)
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38. A method for quantifying the operation of a recovery boiler burning black liquor fuel when being monitored by one of the Input/Loss methods coincident with one of its heat exchangers leaking its working fluid into the combustion gas path producing a tube leakage flow, the method for quantifying the operation by identification of the leaking heat exchanger comprising the steps of:
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identifying a set of heat exchangers descriptive of the recovery boiler as employed to transfer net energy flow to the working fluid from the combustion gases resulting in a set of identified heat exchangers, obtaining a set of Operating Parameters applicable to the set of identified heat exchangers, analyzing a set of net energy flows to the working fluid from the combustion gases based on the set of identified heat exchangers, the set of Operating Parameters and the tube leakage flow rate, each analyzed set descriptive of the recovery boiler and wherein each analyzed set the tube leakage flow rate is assigned to a different heat exchanger, resulting in an analyzed set of heat exchangers, determining a reference key comparative parameter for the recovery boiler, obtaining a set of key comparative parameters associated with each identified heat exchanger, applicable with the reference key comparative parameter, and based on the analyzed set of heat exchangers, determining a set of deviations between the set of key comparative parameters and the reference key comparative parameter, determining an identification of the leaking heat exchanger based on the set of deviations, and reporting to the operator of the recovery boiler the identification of the leaking heat exchanger such that corrective action may take place. - View Dependent Claims (39, 40, 41, 42)
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43. A method for quantifying the operation of a recovery boiler burning a fossil fuel in a combustion process through knowledge of when one of its heat exchangers, whose tubes contain working fluid heated by products of combustion, has a tube leak of working fluid mixing with the products of combustion, the method for quantifying the operation comprising the steps of:
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monitoring the recovery boiler using one of the Input/Loss methods, developing a mathematical model of the combustion process incorporating terms commonly associated with the combustion process and terms associated with sources of working fluid mixing with the products of combustion including tube leakage, determining a tube leakage based on the mathematical model of the combustion process, and reporting the tube leakage such that corrective action may take place. - View Dependent Claims (44, 45, 46, 47, 48)
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49. A method for quantifying the operation of a recovery boiler burning a black liquor fuel in a combustion process through knowledge of when one of its heat exchangers, whose tubes contain working fluid heated by products of combustion, has a tube leak of working fluid mixing with the products of combustion, the method for quantifying the operation comprising:
determining a location of the heat exchanger within the recovery boiler with the tube leak based on the working fluid'"'"'s energy flow by assigning the tube leak to different heat exchangers. - View Dependent Claims (50, 51, 52, 53, 54)
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55. A method for quantifying the operation of a thermal system burning a fossil fuel, including a recovery boiler, having a heat exchangers/combustion region producing combustion products, the method comprising the steps of:
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before on-line operation, installing an explicit mathematical model of the combustion process; and
thereafteroperating on-line while using the explicit mathematical model of the combustion process, the step of operating on-line comprising the steps of measuring a set of measurable operating parameters, including at least effluent concentrations of O2 and CO2, these measurements being made at a location downstream of the heat exchangers/combustion region of the thermal system, obtaining an effluent concentration of H2O, if reference fuel characteristics indicate fuel water is not predictable, as an obtained effluent H2O, obtaining an air pre-heater leakage factor, and computing a fuel chemistry as a function of the explicit mathematical model of the combustion process, the set of measurable operating parameters, the obtained effluent H2O, and the air pre-heater leakage factor. - View Dependent Claims (56, 57, 58, 59)
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60. A method for quantifying the operation of a recovery boiler burning black liquor fuel in which a fossil fuel is supplied at a flow rate to a heat exchangers/combustion region and combusted to produce hot combustion gases, which heats a working fluid then exits through an exhaust stack, the method comprising the following steps:
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performing an off-line operation comprising the steps of obtaining reference fuel characteristics, obtaining current measurements of the system'"'"'s operating parameters, and performing an on-line operation comprising the steps of measuring the useful output of the system, obtaining fuel data and characteristics, the step of obtaining fuel data including the step of obtaining composite fuel concentrations and composite heating value, if multiple fuels are used, introducing fuel concentrations and heating values to a mathematical model of the recovery boiler, obtaining routine systems operational parameters, obtaining values of the effluents O2, CO2, H2O and SO2, obtaining the ambient concentration of O2, obtaining air pre-heater leakage and dilution factors, computing molar moisture-ash-free fractions of fuel carbon and fuel water as explicit stoichiometric solutions, dependent at least in part on the reference fuel characteristics, the effluents O2, CO2, H2O and SO2, ambient concentration of O2, and air pre-heater leakage and dilution factors, finding the molar moisture-ash-free fractions of fuel nitrogen, oxygen, hydrogen, sulfur, sodium, potassium and chloride, converting the molar moisture-ash-free fuel concentrations to a molar dry base, then to a molar As-Fired wet base, and finally to As-Fired wet weight fractions, to obtain a complete and consistent computed As-Fired fuel chemistry, computing a heating value based on a moisture-ash-free weight base, then converted to a dry base, and then to a weight-based As-Fired heating value, and executing the mathematical model of the recovery boiler using the fuel information and the concentration of effluent O2 to produce consistent stoichiometric values of effluent CO2, SO2 and H2O values, the moles of fuel per basis moles of dry gaseous effluent, and at least the following self-consistent thermal performance parameters;
As-Fired fuel flow, effluent flow, emission rates, boiler efficiency, and over-all system thermal efficiency. - View Dependent Claims (61, 62)
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63. A method for quantifying the operation of a recovery boiler burning black liquor fuel having a heat exchangers/combustion region producing combustion products, the method comprising the steps of:
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before on-line operation, the steps of obtaining a set of reference fuel characteristics, and developing explicit mathematical models of the combustion process involving at least stoichiometric balances; and
thereafteroperating on-line, the step of operating on-line including the steps of measuring a set of measurable operating parameters, including at least effluent concentrations of O2 and CO2, these measurements being made at a location downstream of the heat exchangers/combustion region of the recovery boiler, obtaining an effluent concentration of H2O if the set of reference fuel characteristics indicates that fuel water is not predictable, as an obtained effluent H2O, obtaining a concentration of O2 in the ambient air entering the recovery boiler, obtaining an air pre-heater leakage factor, calculating a set of fuel chemistry concentrations including elemental fuel constituents, fuel water and fuel inerts, as a function of the set of reference fuel characteristics, explicit mathematical models of the combustion process, the set of measurable operating parameters, the obtained effluent H2O, the concentration of O2 in the ambient air entering the recovery boiler, and the air pre-heater leakage factor. - View Dependent Claims (64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74)
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Specification