Sealing lighting device component assembly with solder glass preform by using infrared radiation

• US 7,040,121 B2
• Filed: 10/31/2002
• Issued: 05/09/2006
• Est. Priority Date: 10/31/2002
• Status: Expired due to Fees

• Current Assignee: Corning Incorporated
• Original Assignee: Corning Incorporated
• Inventors: Canale, Joseph E., Tuttle, Clayton L. II, Cooch, Stephen L., Haynes, William L.
• Primary Examiner(s): LOPEZ, CARLOS N
• Application Number:
  US10/284,588
• Publication Number:
  US 20040083760A1
• Time in Patent Office: 1,286 Days
• Field of Search: 65/34, 65/36, 65/42, 313331-333, 313/317, 313/318.1, 313/323, 445/29, 445/35, 445/46, 445/23, 445 24- 25, 445/44, 445/73, 501 73- 77, 501/79
• US Class Current: 65/34
• CPC Class Codes: C03C 3/066 containing zinc
• CPC Class Codes: C03C 3/074 containing zinc
• CPC Class Codes: H01J 9/26 Sealing together parts of vessels
• CPC Class Codes: H01J 9/32 Sealing leading-in conductors

Abstract

Disclosed is a method for sealing and affixing a component assembly for an electrical lighting device to a glass lamp envelope. The assembly used in the process comprises the component, such as an electrode lead wire and a solder glass perform. The process is useful, for example, in hermetically sealing and affixing lamp components, such as electrical lead wires and exhaust tubulation, to a low pressure fluorescent discharge lamp envelope having phosphor coating already applied thereto. The present invention is particularly suitable for lamp envelope made of borosilicate glass having a CTE from 0 to 300° C. in the range of 30–45×10⁻⁷° C.⁻¹.

Claims

1. A process for hermetically sealing a component to a lamp envelope of a lighting device made of glass having a CTE C₁ from 0 to 300°

C., comprising the following steps;

(i) providing a component assembly comprising the component to be sealed with the lamp envelope and an infrared absorbing solder glass preform enclosing and bonded to the portion of the component to be hermetically sealed and affixed to the glass lamp envelope, wherein solder glass of the preform has a before-sealing softening point T_s over 500°

C., an after-sealing CTE C₂ from 0 to 300°

C. in the range of C₁±

10×

10<sup>−

7</sup>°

C.<sup>−

1</sup>, and is capable of forming a hermetic sealing of the component with the lamp envelope upon being heated to a temperature over its before-sealing softening point;

(ii) attaching the component assembly to a hole of the lamp envelope through which the component is to be sealed and affixed to the lamp envelope; and

(iii) heating the solder glass preform locally using infrared radiation to a temperature higher than the before-sealing softening point T_s of the solder glass to effect a hermetic sealing,

wherein the solder glass preform is formed from a devitrifying solder glass consisting essentially of a B₂O₃—

SiO₂—

PbO—

ZnO glass containing CuO and/or Fe₂O₃, having a before-sealing softening point in the range of 550–

700°

C., an after-sealing CTE C₂ from 0 to 300°

C. in the range of 32–

40×

10<sup>−

7</sup>°

C.<sup>−

1</sup> and a devitrifying temperature T_d in the range of 630–

750°

C.

2. A process in accordance with claim 1, wherein the glass envelope is made of borosilicate glass having a CTE C₁ in the range of 30–

45×

10<sup>−

7</sup>°

C.<sup>−

1</sup> from 0 to 300°

C., and a phosphor coating has been applied to the glass envelope before sealing thereof.

3. A process in accordance with claim 1, wherein the solder glass preform is formed from a solder glass consisting essentially, by weight percentage on an oxide basis, of:

0–

2% of Al₂O₃, 15–

25% of B₂O₃, 1–

5% of CuO, 0–

5% of Fe₂O₃, 0–

7% of PbO, 10–

16% of SiO₂ and 55–

65% ZnO, and having a before-sealing softening point in the range of 600–

650°

C., an after-sealing CTE C₂ from 0 to 300°

C. in the range of 34–

38×

10<sup>−

7</sup>°

C.<sup>−

1</sup> and a devitrifying temperature T_d in the range of 650–

700°

C.

4. A process in accordance with claim 1, wherein the glass envelope is made of a borosilicate glass having the following composition, expressed in terms of weight percentage on an oxide basis calculated from the glass batch:

77.4% SiO₂, 15.4% B₂O₃, 1.9% Al₂O₃ and 5.3% Na₂O, and having a CTE of approximately 38×

10<sup>−

7</sup>°

C.<sup>−

1</sup> from 0 to 300°

C.

5. A process in accordance with claim 2, wherein the glass envelope is preheated to a temperature below 600°

C. before step (iii).

6. A process in accordance with claim 5, wherein the glass envelope is preheated to a temperature between about 550–

585°

C.

7. A process in accordance with claim 1, wherein the component to be sealed and affixed to the glass envelope is a beaded electrode lead wire.

8. A process in accordance with claim 7, wherein the beaded electrode lead wire has an inner lead, an outer lead and an intermediate lead, and the intermediate lead has a hermetically sealed solder glass bead therewith.

9. A process in accordance with claim 8, wherein the solder glass bead of the beaded lead wire is bonded and attached to the solder glass preform by sintering at a temperature lower than the before-sealing softening point T_s of the solder glass preform.

10. A process in accordance with claim 9, wherein the solder glass preform has a shape directly receivable by or capable of covering the hole of the glass envelope through which the solder glass preform beaded electrode wire assembly is to be sealed and affixed to the lamp envelope.

11. A process in accordance with claim 10, wherein the solder glass preform enclosing the lead wire consists of two integrated parts P₁ and P₂ having different cross-sectional sizes, P₁ has a smaller cross-sectional size receivable by the hole of the lamp envelope through which the component assembly is to be sealed and affixed, and part P₂ has a larger cross-sectional size capable of covering the hole when P₁ is inserted into and received by the hole.

12. A process in accordance with claim 2, wherein the component to be sealed and affixed is a borosilicate glass tubulation having a CTE C₃ in the range of C₁±

10×

10<sup>−

7</sup>.

13. A process in accordance with claim 12, wherein the tubulation is bonded to the solder glass preform by sintering at a temperature below the before-sealing softening temperature T_s of the solder glass of the preform.

14. A process in accordance with claim 13, wherein the component enclosed by the solder glass preform is to be affixed to the lamp envelope as an exhaust tubulation.

15. A process in accordance with claim 13, wherein the solder glass preform enclosing the tubulation has a shape receivable by or capable of covering the hole of the lamp envelope through which the component assembly is to be sealed and affixed.

16. A process in accordance with claim 13, wherein the solder glass preform enclosing the tubulation consists of two integrated parts P₁ and P₂ having different cross-sectional sizes, P₁ has a smaller cross-sectional size receivable by the hole of the lamp envelope through which the component assembly is to be sealed and affixed, and part P₂ has a larger cross-sectional size capable of covering the hole when P₁ is inserted into and received by the hole.

17. A process in accordance with claim 15 or 16, wherein the component assembly to be sealed and affixed to the lamp envelope further comprises a beaded electrode lead wire placed inside the tubulation, the beaded lead wire and the tubulation are chosen and placed in a manner such that upon prior or further heating of the tubulation, a hermetic seal can be effected between the beaded lead wire and the tubulation without causing substantial heating to the glass envelope to which the assembly is to be sealed and affixed.

18. A process in accordance with claim 1, wherein the heating time in step (iii) is less than 5 minutes.

19. A process in accordance with claim 18, wherein the heating time in step (iii) is less than 3 minutes.

20. A process in accordance with claim 19, wherein the heating time in step (iii) is less than 1 minute.

21. A process in accordance with claim 18, wherein the infrared radiation source is a linear focused infrared light beam.

22. A process in accordance with claim 21, wherein multiple infrared radiation sources are used to provide multiple linear light beams converging on the solder glass preform.