Electrochromic devices based on lithium insertion

• US 7,042,615 B2
• Filed: 05/19/2003
• Issued: 05/09/2006
• Est. Priority Date: 05/17/2002
• Status: Active Grant

• Current Assignee: Regents of the University of California (University of California)
• Original Assignee: Regents of the University of California (University of California)
• Inventors: Richardson, Thomas J.
• Primary Examiner(s): Dang, Hung
• Assistant Examiner(s): TRA, TUYEN Q
• Application Number:
  US10/441,855
• Publication Number:
  US 20040021921A1
• Time in Patent Office: 1,086 Days
• Field of Search: 359/265, 359/266, 359/267, 359/268, 359/269, 359/270, 359/271, 359/272, 359/273, 359/274, 359/275, 252/582, 252/586
• US Class Current: 359/265
• CPC Class Codes: G02F 1/1524 Transition metal compounds

Abstract

Electrochromic devices having as an active electrode materials comprising Sb, Bi, Si, Ge, Sn, Te, N, P, As, Ga, In, Al, C, Pb, I and chalcogenides are disclosed. The addition of other metals, i.e. Ag and Cu to the active electrode further enhances performance.

Claims

1. A switching device capable of undergoing a reversible change in light transmittance or reflectance, comprising:

a counter electrode, an electrolyte layer and an active electrode, wherein;

said electrolyte layer is disposed between the counter electrode and the active electrode, said electrolyte layer comprising either an alkali or alkaline earth metal ion; and

said active electrode comprises at least one element chosen from the group consisting of Sb, Bi, Si, Ge, Sn, Te, N, P, As, Ga, In, Al, C, Pb and I, and wherein upon the application of a current to the switching device, a compound comprising at least either an alkali or alkaline earth metal ion and an element of the active electrode is formed as part of the active electrode.

2. The switching device as claimed in claim 1, wherein the alkali metal ion is Li.

3. The switching device as claimed in claim 2, wherein upon the application of a current to the switching device, the compound formed is selected from the group consisting of Li₂Sb, Li₃Sb, Li₂Bi and Li₃Bi.

4. The switching device as claimed in either of claims 1, 2 or 3, further comprising:

a glass layer and a transparent conducting oxide layer disposed between the glass layer and the counter electrode.

5. The switching device as claimed in claim 1, wherein:

the active electrode comprises either Ag or Cu in an amount of from about 1 wt % to about 70 wt %.

6. The switching device as claimed in claim 1, wherein:

the active electrode comprises either Ag or Cu in an amount of from about 12 wt % to about 50 wt %.

7. The switching device as claimed in claim 1, wherein:

the active electrode consists essentially of at least one element chosen from the group consisting of Sb, Bi, Si, Ge, Sn, Te, N, P, As, Ga, In, Al, C, Pb, I and alloys thereof.

8. A switching device capable of undergoing a reversible change in light transmittance or reflectance, comprising:

a counter electrode, an electrolyte layer and an active electrode, wherein;

said electrolyte layer is disposed between the counter electrode and the active electrode, said electrolyte layer comprising either an alkali or alkaline earth metal ion; and

said active electrode comprises a transition metal chalcogenide, and wherein upon the application of a current to the switching device, a compound comprising at least either an alkali or alkaline earth metal ion and the transition metal chalcogenide of the active electrode is formed as part of the active electrode.

9. The switching device as claimed in claim 8, wherein the electrolyte layer comprises Li ions.

10. The switching device as claimed in either of claims 8 or 9, further comprising:

a glass layer and a transparent conducting oxide layer disposed between the glass layer and the active electrode.

11. The switching device as claimed in claim 8, wherein:

the active electrode comprises a compound chosen from the group consisting of TiS₂, NbSe₂, and NbTe₂.

12. The switching device as claimed in claim 8, wherein:

the active electrode comprises either Ag or Cu in an amount of from about 1 wt % to about 70 wt %.

13. The switching device as claimed in claim 8, wherein:

the active electrode comprises either Ag or Cu in an amount of from about 12 wt % to about 50 wt %.

14. The switching device as claimed in claim 8, wherein:

the active electrode consists essentially of transition metal chalcogenide and alloys thereof.

15. The switching device as claimed in claim 14, wherein:

the active electrode consists essentially of a compound chosen from the group consisting of TiS₂, NbSe₂, and NbTe₂.