Optical devices having flakes suspended in a host fluid to provide a flake/fluid system providing flakes with angularly dependent optical properties in response to an alternating current electric field due to the dielectric properties of the system

• US 7,042,617 B2
• Filed: 04/02/2003
• Issued: 05/09/2006
• Est. Priority Date: 04/02/2003
• Status: Expired due to Fees

• Current Assignee: University of Rochester
• Original Assignee: University of Rochester
• Inventors: Jacobs, Stephen D., Kosc, Tanya Z., Marshall, Kenneth L.
• Primary Examiner(s): Sugarman, Scott J.
• Assistant Examiner(s): HANIG, RICHARD E
• Application Number:
  US10/405,163
• Publication Number:
  US 20040196226A1
• Time in Patent Office: 1,133 Days
• Field of Search: 359/272, 359/273, 349/16
• US Class Current: 359/272
• CPC Class Codes: G02F 1/172 based on a suspension of orientable dipolar particles, e.g. suspended particles displays

Abstract

Optical devices utilizing flakes (also called platelets) suspended in a host fluid have optical characteristics, such as reflective properties, which are angular dependent in response to an AC field. The reflectivity may be Bragg-like, and the characteristics are obtained through the use of flakes of liquid crystal material, such as polymer liquid crystal (PLC) materials including polymer cholesteric liquid crystal (PCLC) and polymer nematic liquid crystal (PNLC) material or birefringent polymers (BP). The host fluid may be propylene carbonate, poly(ethylene glycol) or other fluids or fluid mixtures having fluid conductivity to support conductivity in the flake/host system. AC field dependent rotation of 90° can be obtained at rates and field intensities dependent upon the frequency and magnitude of the AC field. The devices are useful in providing displays, polarizers, filters, spatial light modulators and wherever switchable polarizing, reflecting, and transmission properties are desired.

Claims

1. An optical device comprising a suspension of flakes with angularly dependent optical properties, the suspending liquid having a conductivity that differs from the conductivity of the material of the flakes and having a magnitude of at least about 10⁻

7 Mho/cm.

2. The device according to claim 1 further comprising a switchable AC field, and means of including electrodes across said suspension for angular reorientation of said flakes or particles to change said characteristic when said field is applied.

3. The device according to claim 2 wherein said AC field has a frequency in the range from several Hz to thousands of Hz.

4. The device according to claim 3 wherein said field intensity varies from several to hundreds of mV_rms/μ

m.

5. The device according to claim 4 wherein the magnitudes of said frequency and said field intensity have dependent relationship.

6. The device according to claim 2 wherein said suspension is characterized by the time for said angular reorientation having an inverse quadratic dependence upon the magnitude of said AC field.

7. The device according to claim 1 wherein said flakes have Bragg-like angular-dependent reflective properties.

8. The device according to claim 1 wherein said flakes are of material selected from the group consisting of polymer nematic liquid crystal (PNLC), polymer cholesteric liquid crystal (PCLC) birefringent polymer (BP), and other polymer liquid crystal (PLC).

9. The device according to claim 8 wherein said PLC flakes are polymer cholesteric liquid crystal (PCLC) material.

10. The device according to claim 9 wherein said PCLC material is selected from the group consisting of cyclic polysiloxane liquid crystal polymer, cross-linkable polysiloxane polymer and cross-linkable acrylate polymer.

11. The device according to claim 7 wherein said flakes are PCLC material having a pitch gradient to present said Bragg-like reflectivity.

12. The device according to claim 1 wherein said host fluid has a conductivity in the range from about 10⁻

7 to 10<sup>−

4</sup> Mho/cm.

13. The device according to claim 12 wherein said conductivity is at least 10⁻

6 Mho/cm.

14. The device according to claim 13 wherein said host fluid is selected from the group consisting of polypylene carbonate and poly(ethylene glycol), silicone oils with conductive dopants sufficient to obtain said conductivity, and a miscible mixture of the foregoing fluids.

15. The device according to claim 13 wherein said host fluid is propylene carbonate having a conductivity of about 10⁻

6 Mho/cm.

16. The device according to claim 13 wherein said host fluid is poly(ethylene glycol) having a conductivity of about 2×

10<sup>−

6</sup> Mho/cm.

17. The device according to claim 13 wherein said host fluid is a mixture of 50 wt % poly(ethylene glycol) and 50 wt % propylene carbonate.

18. The device according to claim 13 wherein said host fluid is 50 wt % silicone oil and 50 wt % propylene carbonate.

19. The device according to claim 13 wherein said flakes or platelets are PCLC material.

20. The device according to claim 1 wherein said flake density in the suspending host fluid is at least about 2 wt %.

21. The device according to claim 20 wherein said flake density in the suspending host fluid is in the range from about 2–

10 wt %.

22. An optical device comprising a suspension of flakes which are of polymer liquid crystal material and have angularly dependent optical properties in response to an AC field in response to the dielectric properties of the suspension of flakes.

23. The device according to claim 22 wherein said polymer liquid crystal material is one of polymer nematic liquid crystal (PNLC) or polymer cholesteric liquid crystal (PCLC).

24. The device according to claim 22 further comprising means for controlling angular reorientation of said flakes to change said optical properties when said AC field is applied.

25. The device according to claim 22 wherein said AC field has a frequency in the range from several Hz to thousands of Hz.

26. The device according to claim 22 wherein said optical properties represent reflective properties of said flakes.

27. The device according to claim 22 wherein said AC field has a magnitude and a frequency, and said response of said flakes to said AC field is in accordance with at least the magnitude and frequency of said AC field.

28. The device according to claim 27 wherein said response of said flakes to said AC field is further in accordance with the shape of said flakes.

29. The device according to claim 27 wherein said dielectric properties are provided by said suspension being provided by a fluid having a conductivity that differs from the conductivity of said flakes.

30. The device of claim 22 wherein said dielectric properties are provided by a dielectric permittivity relationship of said flakes and a medium in which said flakes are suspended.

31. The device of claim 22 wherein said dielectric properties are provided by the dielectric constant of said flakes and a medium in which said flakes are suspended.

32. An optical device comprising a suspension of flakes which are of birefringent polymer material having dielectric properties which provide said flakes with angularly dependent optical properties in response to an AC field.

33. The device according to claim 32 further comprising means for controlling angular reorientation of said flakes to change said optical properties when said AC field is applied.

34. The device according to claim 32 wherein said AC field has a frequency in the range from several Hz to thousands of Hz.

35. The device according to claim 32 wherein said optical properties represent reflective properties of said flakes.

36. The device according to claim 32 wherein said AC field has a magnitude and a frequency, and said response of said flakes to said AC field is in accordance with at least the magnitude and frequency of said AC field.

37. The device according to claim 36 wherein said response of said flakes to said AC field is further in accordance with the shape of said flakes.

38. The device according to claim 32 wherein said dielectric properties are provided by said suspension being provided by a fluid having a conductivity that differs from the conductivity of said flakes.

39. The device of claim 32 wherein said dielectric properties are provided by a dielectric permittivity relationship of said flakes and a medium in which said flakes are suspended.

40. The device of claim 32 wherein said dielectric properties are provided by the dielectric constant of said flakes and a medium in which said flakes are suspended.