Method and system for extraction of zein from corn

• US 7,045,607 B2
• Filed: 08/06/2004
• Issued: 05/16/2006
• Est. Priority Date: 05/18/1999
• Status: Expired due to Fees

• Current Assignee: Board of Trustees of The University of Illinois
• Original Assignee: Board of Trustees of The University of Illinois
• Inventors: Cheryan, Munir
• Primary Examiner(s): Carlson, Karen Cochrane
• Assistant Examiner(s): ROOKE, AGNES BEATA
• Application Number:
  US10/913,790
• Publication Number:
  US 20050049400A1
• Time in Patent Office: 648 Days
• Field of Search: 530/350, 530/412, 530/414
• US Class Current: 530/414
• CPC Class Codes: A23D 9/04 Working-up
• CPC Class Codes: A23J 1/142 by extracting with organic solvents
• CPC Class Codes: A23V 2002/00 Food compositions, function of food ingredients or processes for food or foodstuffs
• CPC Class Codes: A23V 2300/34 Membrane process
• CPC Class Codes: C11B 1/00 Production of fats or fatty oils from raw materials
• CPC Class Codes: C11B 1/10 by extracting
• CPC Class Codes: C11B 1/108 after-treatment, e.g. of miscellae
• CPC Class Codes: C11B 3/008 by filtration, e.g. including ultra filtration, dialysis C11B3/005 takes precedence

Abstract

A corn product removal process for removing zein and/or oil from dry-milled corn. Oils and/or zein are extracted from corn using ethanol. Corn solids are separated from the ethanol, oil and zein mixture produced by extracting. Thereafter, the ethanol, oil and zein mixture is membrane filtered to restrain zein from the mixture and pass an oil and ethanol mixture. The zein and/or oil may be concentrated and purified.

Claims

1. A process for removing zein from corn, the process comprising:

extracting the zein from the corn using an amount of an ethanol solution to produce an extraction solution including oils, zein, corn solids, and ethanol;

separating corn solids from the extraction solution;

membrane filtering the extraction solution to restrain zein concentrate from the extraction solution and passing a permeate including ethanol, said membrane filtering including ultrafiltration;

wherein a ratio between the amount of ethanol solution and the corn in said extracting is between about 10;

1 and about 1;

1 volume/weight;

wherein the concentration in the ethanol solution in said extracting is between about 60% and about 90% ethanol by volume;

wherein said extracting occurs at a temperature between about 25°

C. and about 65°

C.

2. The process of claim 1, wherein the corn comprises whole, raw corn.

3. The process of claim 2, further comprising, before said extracting, dry grinding the whole, raw corn.

4. The process of claim 2 wherein said extracting comprises extracting from dry milled corn.

5. The process of claim 1, further comprising purifying zein concentrate obtained in said membrane filtering.

6. The process of claim 5, wherein said purifying comprises evaporating ethanol and water from the zein concentrate.

7. The process of claim 5, wherein said purifying comprises precipitating zein.

8. The process of claim 7, wherein said precipitating comprises adding cold water to said zein concentrate to lower ethanol concentration below approximately 40 percent.

9. The process of claim 5, wherein said purifying comprises diafiltering the zein concentrate using an ethanol solution.

10. The process of claim 9, wherein the ethanol in the ethanol solution for said purifying is between about 70–

100% by volume.

11. The process of claim 10, wherein a remainder of the ethanol solution comprises water.

12. The process of claim 1, wherein said membrane filtering comprises diafiltering.

13. The process of claim 1, further comprising:

membrane filtering the restrained zein concentrate to purify the zein concentrate.

14. The process of claim 13, wherein said membrane filtering the restrained zein concentrate comprises diafiltering the restrained zein concentrate.

15. The process of claim 14, wherein diafiltering the restrained zein concentrate uses a fresh solvent having ethanol.

16. The process of claim 15, wherein the fresh solvent includes ethanol in a concentration greater than the ethanol in the ethanol solution used in said extracting.

17. The process of claim 1, wherein said extracting occurs at a temperature of about 50°

C.

18. The process of claim 1, wherein said extracting takes place over a period of between 0.5 and 2 hours.

19. The process of claim 1, wherein said extracting takes place over a period of about 0.5 hours.

20. The process of claim 1, wherein the corn is not wet milled before said extracting.

21. The process of claim 1, further comprising:

processing the permeate including ethanol to provide recycled ethanol.

22. The process of claim 21, wherein the recycled ethanol is used for diafiltering the zein concentrate.