Aqueous coating compositions

• US 7,049,352 B2
• Filed: 09/26/2002
• Issued: 05/23/2006
• Est. Priority Date: 10/10/2001
• Status: Expired due to Term

• Current Assignee: Covestro NV (Covestro Deutschland AG)
• Original Assignee: Avecia Limited
• Inventors: Satgurunathan, Rajasingham, Bouman, Jan, Gould, Alan Jack
• Primary Examiner(s): EGWIM, KELECHI CHIDI
• Application Number:
  US10/488,040
• Publication Number:
  US 20040260005A1
• Time in Patent Office: 1,335 Days
• Field of Search: 525/902, 525/298, 525/70, 523/201, 524/502
• US Class Current: 523/201
• CPC Class Codes: C08F 285/00 Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C09D 151/003 grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds C09D151/04, C09D151/06 take precedence
• CPC Class Codes: C09D 151/04 grafted on to rubbers
• CPC Class Codes: Y10S 525/902 Core-shell

Abstract

Pigmented aqueous coating composition providing good blocking and elasticity properties comprises a blend of a seeded multistage polymer latex(es) having at least one soft and at least one hard polymer phases and a non-film-forming polymer latex(es), the seed polymer(s) having a Tg≧10° C. lower than that of the hard polymer phase(s) and preferably having a Tg≧10° C. higher than that of the soft polymer phase(s), and the multistage polymer(s) preferably having amino functionality incorporated by an imination reaction.

Claims

1. Pigment-containing aqueous coating composition which provides a pigmented coating having a pigment volume concentration (PVC) in the range of from 15 to 35% and an elasticity value of at least 30%;

wherein said aqueous coating composition comprises;

a seeded multistage polymer latex(es) (A) blended with a non-film forming polymer latex(es) (B), the amount of (A) in the blend corresponding to 75 to 98 weight % of the multistage polymer(s) of (A) based on total weight of the polymers of (A) and (B), and the amount of (B) in the blend corresponding to 2 to 25 weight % of the polymer(s) of (B) based on the total weight of the polymers of (A) and (B);

and wherein with regard to the seeded multistage polymer latex(es) (A);

(a) the multistage polymer(s) thereof comprises 50 to 90 wt % of at least one soft polymer phase having a Tg ≦

25°

C. and 10 to 50 wt % of at least one hard polymer phase having a Tg ≧

30°

C.;

(b) the multistage polymer latex(es) has been prepared in the presence of a seed polymer latex(es), the amount of said seed polymer latex(es) corresponding to 1 to 20 wt % of the seed polymer(s) of the latex(es) based on the weight of the multistage polymer(s); and

(c) the seed polymer(s) having a Tg which is at least 10°

C. lower than the Tg of said hard polymer phase(s) of the multistage polymer(s).

2. Composition according to claim 1 wherein the seed polymer has a Tg which is at least 10°

C. higher than the Tg of said at least one soft polymer phase of the multistage polymer(s).

3. Composition according to claim 1 wherein the multistage polymer(s) bears amino functional groups incorporated by an imination reaction.

4. Composition according to claim 1 wherein the PVC is within the range of from 15 to 30%.

5. Composition according to claim 1 wherein the elasticity value is within the range of from 30 to 130%.

6. Composition according to claim 1 wherein in the blend of the seeded multistage polymer latex(es) (A) and the non-film-forming polymer latex(es) (B) the amount of (A) in the blend corresponds to 80 to 98% by weight of solid polymer material of (A) based on the total weight of the polymers of (A) and (B), and the amount of (B) in the blend corresponds to 2 to 20% by weight of solid polymer material of (B) based on the total weight of the polymers of (A) and (B).

7. Composition according to claim 1 wherein at least one of said at least one soft polymer and/or at least one hard polymer of the multistage polymer(s) is crosslinked.

8. Composition according to claim 1 wherein seeded multistage polymer(s) comprises 2 or more soft polymers.

9. Composition according to claim 1 wherein seeded multistage polymer(s) comprises 2 or more hard polymers.

10. Composition according to claim 1 having 2 or more multistage polymer latexes.

11. Composition according to claim 1 having 2 or more non-film-forming latexes.

12. Composition according to claim 1 wherein said composition includes a combination(s) of oligomer(s) and higher molecular weight polymer(s).

13. Composition according to claim 12 wherein said combination(s) provides one or more of a seed polymer(s), a soft polymer(s) of multistage polymer(s), a hard polymer of multistage polymer(s), and a non-film-forming polymer(s).

14. Composition according to claim 1 wherein said composition is free of coalescent agent.

15. Composition according to claim 1 wherein the polymer solids content of the seeded multistage polymer latex(es) of (A) is in the range of from 30 to 65 wt %.

16. Composition according to claim 1 wherein the amount of seed latex(es) corresponds to 1 to 15 wt % of the seed polymer(s) (solid) of the seed latex(es) based on the weight of the multistage polymer(s) (solid).

17. Composition according to claim 1 wherein the seed polymer latex(es) is preformed.

18. Composition according to claim 1 wherein the seed polymer latex(es) is formed in-situ.

19. Composition according to claim 1 wherein the seed polymer(s) is crosslinked.

20. Composition according to claim 1 wherein the multistage polymer(s) of (A) comprises 60 to 90 wt % of said at least one soft polymer phase and 10 to 40 wt % of said at least one hard polymer phase.

21. Composition according to claim 1, wherein said at least one soft polymer of the multistage polymer(s) has Tg≦

20°

C.

22. Composition according to claim 1 wherein said at least one hard polymer of the multistage polymer(s) has a Tg≧

40°

C.

23. Composition according to claim 1 wherein the Tg of the non-film-forming polymer(s) is within the range of from 40 to 140°

C.

24. Composition according to claim 1 wherein the average particle size of the seed polymer(s) is ≦

80 nm.

25. Composition according to claim 1 wherein the average particle size of the seeded multistage polymer(s) is ≦

250 nm.

26. Composition according to claim 1 wherein said at least one hard polymer of the multistage polymer(s) is derived from a monomer composition(s) comprising 50 to 78 wt % of at least one monomer selected from methyl methacrylate, styrene, ethyl methacrylate, and isobutyl methacrylate;

20 to 48 wt % of at least one monomer selected from n-butyl acrylate, n-butyl methacrylate, ethyl acrylate and 2-ethylhexyl acrylate ; and

2 to 6 wt % of at least monomer selected from acrylic acid, methacrylic acid and beta carboxyethyl acrylate.

27. Composition according to claim 1 wherein said at least one soft polymer of the multistage polymer(s) is derived from a monomer composition comprising 50 to 78 wt % of at least one monomer selected from n-butyl acrylate, n-butyl methacrylate, ethyl acrylate, and 2-ethylhexyl acrylate;

20 to 48 wt % of at least one monomer selected from methyl methacrylate, styrene, ethyl methacrylate, and isobutyl methacrylate; and

2 to 6 wt % of at least one monomer selected from acrylic acid, methacrylic acid, and beta carboxyethyl acrylate.

28. Composition according to claim 1 wherein the non-film-forming polymer(s) is derived from a monomer composition(s) comprising 80 to 94 wt % of at least one monomer selected from methyl methacrylate, styrene, ethyl methacrylate and isobutyl methacryalate;

5 to 19 wt % of at least one monomer selected from n-butyl methacrylate, n-butyl acrylate, ethyl acrylate and 2-ethylhexyl acrylate; and

1 to 6 wt % of at least one monomer selected from acrylic acid and methacrylic acid.

33. A pigmented coating derived from an aqueous coating composition according to claim 1.

34. A pigmented coating according to claim 33 which has good early water and alkali resistance.

35. Method of coating a substrate which comprises applying an aqueous coating composition according to claim 1 to a substrate and causing or allowing the aqueous carrier medium of the composition to be removed.

36. Coated substrate which has been prepared by applying an aqueous composition according to claim 1 and causing or allowing the carrier medium of the composition to become removed.

37. Composition according to claim 26 or claim 27 wherein at least a proportion of the polymer-bound carboxylic acid groups is iminated to provide amino groups.

29. Method for making a pigment-containing aqueous coating composition which method comprises:

(1) forming a seeded multistage polymer latex(es) (A) by conducting a multistage polymer emulsion polymerisation(s) in the presence of a seed polymer latex(es), wherein;

(i) the multistage polymer(s) of (A) comprises 50 to 90 wt % of at least one soft polymer phase having a Tg of ≦

25°

C., and 10 to 50 wt % of at least one hard polymer phase having a Tg of ≧

30 

C.;

(ii) the seed polymer(s) of (A) has a Tg which is at least 10°

C. lower than the Tg of said at least one hard polymer phase of the multistage polymer;

(iii) the multistage polymer latex(es) is formed in the presence of 1 to 20 wt % of the seed polymer(s) based on the weight of the multistage polymer(s);

(2) blending said seeded multistage polymer latex(es) (A) with a non-film-forming polymer latex(es) (B), the amount of (A) in the blend corresponding to 75 to 98% by weight of the polymers of (A) based on the total weight of the polymers of (A) and (B), and the amount of (B) in the blend corresponding to 2 to 25% by weight of polymer of (B) based on the total weight of the polymers of (A) and (B);

(3) formulating said seeded multistage polymer latex(es) (A) and said non-film-forming polymer latex(es) (B) blended therewith, with a particulate pigment in an amount to provide a pigment volume concentration (PVC) in a pigmented coating formed from the coating composition within the range of from 15 to 35%; and

wherein further pigmented coatings formed from the coating composition have an elasticity value of at least 30%.

30. Method according to claim 29 wherein the seed polymer(s) has a Tg which is at least 10°

C. than the Tg of said at least one soft polymer phase of the multistage polymer.

31. Method according to either claim 29 or claim 30 wherein the multistage polymer(s) employed bears amino functional groups incorporated by an imination reaction.

32. Method according to either claim 29 or claim 30 wherein all polymers of the composition are vinyl polymers made by an aqueous emulsion polymerisation process, and the amount of surfactant employed in the emulsion polymerisation(s) to make the multistage polymer(s) is ≦

4 wt % based on the total weight of monomers used for both the soft and hard phase polymers of the multistage polymer(s).