Photo-functional powder and applications thereof

• US 7,060,643 B2
• Filed: 12/28/2001
• Issued: 06/13/2006
• Est. Priority Date: 12/28/2000
• Status: Expired due to Fees

• Current Assignee: Showa Denko KK (Resonac Holdings Corp.)
• Original Assignee: Showa Denko KK (Resonac Holdings Corp.)
• Inventors: Tanaka, Jun, Ueyoshi, Yoshinori, Sanbayashi, Masayuki, Hagihara, Hiroyuki
• Primary Examiner(s): Bell, Mark L.
• Assistant Examiner(s): Hailey, Patricia L
• Application Number:
  US10/028,721
• Publication Number:
  US 20020160910A1
• Time in Patent Office: 1,628 Days
• Field of Search: 502/208, 502/350, 501/162, 423/311, 423/312, 423/314, 524/414, 524/417, 428/403
• US Class Current: 502/162
• CPC Class Codes: B01J 21/063 Titanium; Oxides or hydroxides thereof
• CPC Class Codes: B01J 27/1806 with alkaline or alkaline earth metals
• CPC Class Codes: B01J 31/06 containing polymers organometallic polymers B01J31/123; polymer-bound organometallic complexes B01J31/165; coordination polymers B01J31/1691
• CPC Class Codes: B01J 35/30 characterised by their physical properties
• CPC Class Codes: B01J 35/39 Photocatalytic properties
• CPC Class Codes: B01J 35/58 Fabrics or filaments
• CPC Class Codes: B01J 37/0215 Coating
• CPC Class Codes: C01G 23/07 Producing by vapour phase processes, e.g. halide oxidation
• CPC Class Codes: C01P 2006/12 Surface area
• CPC Class Codes: C09C 1/3661 Coating
• CPC Class Codes: Y10T 428/2991 Coated

Abstract

A condensed phosphate containing an alkaline earth metal is caused to be present on the surface of titanium dioxide fine particles, and as a result, the condensed phosphate is firmly coupled with the fine particles and is barely liberated from the surface of the fine particles into a medium such as a binder or a resin. As a result, photo-functional particles exhibiting durability and dispersion stability are obtained. By use of the photo-functional particles, a powder and a slurry exhibiting excellent photo-functional property, durability, dispersion stability, and hydrophilicity are produced. In addition, by use of the powder and slurry, a polymer composition, a coating agent, a photo-functional formed article, and a photo-functional structure are produced.

Claims

1. Photo-functional particles characterized by comprising titanium dioxide and a condensed phosphate containing an alkaline earth metal which is present on the surface of the titanium dioxide.

2. Photo-functional particles according to claim 1, wherein the titanium dioxide has a particle size falling within a range of about 0.001 to about 0.1 μ

m.

3. Photo-functional particles according to claim 1, wherein the titanium dioxide contains at least one crystal form selected from the group consisting of anatase, rutile, and brookite.

4. Photo-functional particles according to claim 1, wherein the condensed phosphate is at least one species selected from the group consisting of a polyphosphate, a metaphosphate, and an ultraphosphate.

5. Photo-functional particles according to claim 1, wherein the condensed phosphate is a pyrophosphate.

6. Photo-functional particles according to claim 1, wherein the alkaline earth metal is at least one species selected from among Mg and Ca.

13. An aqueous slurry comprising photo-functional particles as recited in any one of claims 1 through 6.

14. An aqueous slurry according to claim 13, which has a pH of about 5 to about 9.

15. An aqueous slurry according to claim 13, wherein, when the slurry contains the photo-functional particles in an amount of 10 mass %, the slurry has a transmittance of at least about 20% at a wavelength of 550 nm and an optical length of 2 mm.

16. A coating agent comprising an aqueous slurry as recited in claim 13.

25. A photo-functional structure comprising, on its surface, photo-functional particles as recited in any one of claims 1 through 6.

26. A hydrophilic structure comprising a surface layer containing photo-functional particles as recited in any one of claims 1 through 6, wherein the surface of the layer exhibits hydrophilicity.

27. A structure according to claim 25, which is at least one member selected from the group consisting of building materials, machinery, vehicles, glass products, electric appliances, agriculture materials, electronic apparatus, tools, tableware, bath products, toiletry products, furniture, clothing, cloth products, fibers, leather products, and paper products, sporting goods, futon, containers, eyeglasses, signboards, piping, wiring, brackets, sanitary material, and automobile parts.

7. A photo-functional powder comprising photo-functional particles, the particles comprising titanium dioxide and a condensed phosphate containing an alkaline earth metal which is present on the surface of the titanium dioxide.

8. A photo-functional powder according to claim 7, wherein the titanium dioxide has a primary particle size falling within a range of about 0.001 to about 0.1 μ

m.

9. A photo-functional powder according to claim 7, wherein the titanium dioxide contains at least one crystal form selected from the group consisting of anatase, rutile, and brookite.

10. A photo-functional powder according to claim 7, wherein the condensed phosphate is at least one species selected from among a polyphosphate, a metaphosphate, and an ultraphosphate.

11. A photo-functional powder according to claim 7, wherein the condensed phosphate is a pyrophosphate.

12. A photo-functional powder according to claim 7, wherein the alkaline earth metal is at least one species selected from among Mg and Ca.

17. An organic polymer composition comprising a photo-functional powder as recited in claim 7.

18. An organic polymer composition according to claim 17, which contains the photo-functional powder in an amount of about 0.01 to about 80 mass % on the basis of the entire mass of the composition.

19. An organic polymer composition according to claim 17, wherein the organic polymer of the composition is at least one species selected from the group consisting of a synthetic thermoplastic resin, a synthetic thermosetting resin, and a natural resin.

20. A coating material comprising an organic polymer composition as recited in any one of claims 17 through 19.

21. A compound comprising an organic polymer composition as recited in any one of claims 17 through 19.

22. A masterbatch for a formed article selected from among fiber, film, and plastic formed articles, comprising an organic polymer composition as recited in any one of claims 17 through 19 containing the photo-functional powder.

23. A photo-functional formed article which is formed from an organic polymer composition as recited in any one of claims 17 through 19 containing the photo-functional powder.

24. A photo-functional formed article according to claim 23, which is selected from among fiber, film, and plastic formed articles.