System and method for recovery of C2+ hydrocarbons contained in liquefied natural gas

• US 7,069,743 B2
• Filed: 02/20/2002
• Issued: 07/04/2006
• Est. Priority Date: 02/20/2002
• Status: Expired due to Term

• Current Assignee: Pilot Intellectual Property LLC (Hero Technologies, Inc.)
• Original Assignee: Eric Prim
• Inventors: Prim, Eric
• Primary Examiner(s): DOERRLER, WILLIAM CHARLES
• Application Number:
  US10/079,254
• Publication Number:
  US 20030158458A1
• Time in Patent Office: 1,595 Days
• Field of Search: 62/502, 626/18, 626/20
• US Class Current: 62/620
• CPC Class Codes: C07C 7/04 by distillation
• CPC Class Codes: F25J 2200/02 in a single pressure main column system
• CPC Class Codes: F25J 2200/74 Refluxing the column with at least a part of the partially condensed overhead gas
• CPC Class Codes: F25J 2205/02 using simple phase separation in a vessel or drum
• CPC Class Codes: F25J 2230/08 Cold compressor, i.e. suction of the gas at cryogenic temperature and generally without afterstage-cooler
• CPC Class Codes: F25J 2230/60 the fluid being hydrocarbons or a mixture of hydrocarbons
• CPC Class Codes: F25J 2235/60 the fluid being (a mixture of) hydrocarbons
• CPC Class Codes: F25J 3/0214 Liquefied natural gas
• CPC Class Codes: F25J 3/0233 separation of CnHm with 1 carbon atom or more
• CPC Class Codes: F25J 3/0238 separation of CnHm with 2 carbon atoms or more

Abstract

A processing method and system for separating methane-rich and ethane-rich components from an LNG stream. The LNG stream is preheated against a distillation column overhead vapor stream and against an overhead vapor product prior to entering the column. The overhead vapor product is methane-rich. The LNG stream may further be preheated against the column bottoms and another heating medium. The method may also include compressing the methane-rich product, condensing it against the LNG stream, and pumping it. The system may also comprise third and fourth heat exchangers configured to preheat the LNG stream with the bottoms product and the heating medium. Further, the system may provide for compressing the overhead vapor product prior to the its exchanging heat with the LNG stream and a pump for pumping condensed overhead vapor product. Additionally, the system generates all of the required reflux by cross exchanging the column overhead with the incoming LNG stream.

Claims

1. A system for processing a liquefied natural gas feed comprising:

a distillation column configured for multistage separation of said liquefied natural gas feed and configured to produce an overhead vapor stream and an ethane-rich product;

a first heat exchanger configured to exchange heat between said overhead vapor stream of said distillation column and said liquefied natural gas feed, said first heat exchanger being configured to produce a first heated liquefied natural gas feed and a condensed overhead vapor stream;

a separator configured to separate said condensed overhead vapor stream into an overhead vapor product and a liquid stream;

a second heat exchanger configured to exchange heat between said first heated liquefied natural gas feed and said overhead vapor product.

2. The system of claim 1 wherein said second heat exchanger is configured to condense said overhead vapor product.

3. A system for processing a liquefied natural gas feed comprising:

a distillation column configured for multistage separation of said liquefied natural gas feed and configured to produce an overhead vapor stream and an ethane-rich product;

a first heat exchanger configured to exchange heat between said overhead vapor stream of said distillation column and said liquefied natural gas feed, said first heat exchanger being configured to produce a first heated liquefied natural gas feed and a condensed overhead vapor stream;

a separator configured to separate said condensed overhead vapor stream into an overhead vapor product and a liquid stream;

a second heat exchanger configured to exchange heat between said first heated liquefied natural gas feed and said overhead vapor product; and

a compressor configured to compress said overhead vapor product before said overhead vapor product exchanges heat in said second heat exchanger.

4. The system of claim 3 further comprising a pump configured to pressurize said condensed overhead vapor product.

5. A system for processing a liquefied natural gas feed comprising:

a distillation column configured for multistage separation of said liquefied natural gas feed and configured to produce an overhead vapor stream and an ethane-rich product;

a first heat exchanger configured to exchange heat between said overhead vapor stream of said distillation column and said liquefied natural gas feed, said first heat exchanger being configured to produce a first heated liquefied natural gas feed and a condensed overhead vapor stream;

a separator configured to separate said condensed overhead vapor stream into an overhead vanor product and a liquid stream;

a second heat exchanger configured to exchange heat between said first heated liquefied natural gas feed and said overhead vapor product so as to produce a second heated liquefied natural gas feed; and

a third heat exchanger, said third heat exchanger being configured to exchange heat between said ethane-rich product and said second heated liquefied natural gas feed.

6. The system of claim 5 wherein said third heat exchanger is configured to produce a third heated liquefied natural gas feed and wherein said system further comprises a fourth heat exchanger configured to heat said third heated liquefied natural gas feed to a desired energy level for feed to said distillation column.

7. The system of claim 6 further comprising a compressor configured to compress said overhead vapor product prior to said overhead vapor product entering said second heat exchanger and wherein said second heat exchanger is configured to condense said overhead vapor product.

8. A system for separating a liquefied natural gas stream into a methane-rich product and an ethane-rich product, said system comprising:

a distillation column configured to fractionate said liquefied natural gas stream into an overhead vapor and said ethane-rich product;

a compressor configured to compress said methane-rich product;

a condenser configured to substantially condense said methane-rich product against said liquefied natural gas stream;

a first heat exchanger configured to exchange heat from said overhead vapor with said liquefied natural gas stream before said liquefied natural gas stream is heated by any other heat exchanger; and

a second heat exchanger configured to exchange heat from said ethane-rich product with said liquefied natural gas stream after said liquefied natural gas stream has been heated in said condenser.

9. A method for recovering ethane and heavier components from liquefied natural gas, the method comprising the steps of:

(a) preheating said liquefied natural gas;

(b) fractionating said liquefied natural gas into a overhead vapor stream and an ethane-rich product;

(c) compressing a portion of the overhead vapor stream to form a compressed overhead vapor product stream; and

(d) substantially condensing the compressed overhead vapor product stream;

wherein step (a) comprises exchanging heat from said overhead vapor stream with said liquefied natural gas so as to form a condensed overhead vapor stream;

wherein the condensed overhead vapor stream is separated into an overhead vapor product and a liquid stream;

wherein step (c) comprises compressing the overhead vapor product; and

wherein step (d) comprises exchanging heat from the compressed overhead vapor product with said liquefied natural gas.

10. The method of claim 9 wherein step (a) further comprises exchanging heat from said ethane-rich product with said liquefied natural gas.

11. The method of claim 10 wherein step (a) further comprises exchanging heat from said overhead vapor stream, the compressed overhead vapor product, and said ethane-rich product with said liquefied natural gas sequentially in order as listed.

12. A method for preheating liquefied natural gas for feed to a distillation column, wherein said distillation column produces an overhead vapor, and a bottoms product, the method comprising the steps of:

(a) exchanging heat from said overhead vapor with said liquefied natural gas so as to form a condensed overhead vapor stream;

(b) separating the condensed overhead vapor stream into an overhead vapor product and a liquid stream;

(c) compressing the overhead vapor product so as to form a compressed overhead vapor product; and

(d) exchanging heat from said compressed overhead vapor product with said liquefied natural gas.

13. The method of claim 12, further comprising:

(c) exchanging heat from said bottoms product with said liquefied natural gas.

14. The method of claim 12 wherein step (b) comprises condensing substantially all of said overhead vapor product.

15. The method of claim 14 wherein step (a) comprises condensing a portion of said overhead vapor.

16. The method of claim 12 wherein step (a) is performed before step (b).

17. The method of claim 14 further comprising:

(c) pumping said condensed overhead vapor product.