Chemically cross-linked cellulose fiber and method of making same

• US 7,074,301 B2
• Filed: 06/11/2002
• Issued: 07/11/2006
• Est. Priority Date: 06/11/2002
• Status: Expired due to Fees

• Current Assignee: Rayonier Performance Fibers, LLC (Rayonier Advanced Materials, Inc.)
• Original Assignee: Rayonier Products and Financial Services Company
• Inventors: Chmielewski, Harry J., Hamed, Othman A., McBee, Dana B.
• Primary Examiner(s): HUG, ERIC J
• Application Number:
  US10/166,254
• Publication Number:
  US 20030230391A1
• Time in Patent Office: 1,491 Days
• Field of Search: 162/9, 162/72, 162/90, 162/91, 162/95, 162/141, 162146-149, 162135-137, 162/158, 162/164.1, 162165-167, 162/157.6, 162/168.1, 162/183, 162/100, 162/109, 162/111, 162/188, 811/61, 811/64, 604374-376, 604/378, 604/358, 604/367, 604/372, 264/121, 264/128, 424/402
• US Class Current: 162/157.6
• CPC Class Codes: A61F 13/15203 Properties of the article, e.g. stiffness or absorbency chemical aspects A61L15/00
• CPC Class Codes: A61F 13/53 characterised by the absorbing medium A61F13/20 takes precedence
• CPC Class Codes: C08B 15/10 Crosslinking of cellulose
• CPC Class Codes: C08H 8/00 Macromolecular compounds derived from lignocellulosic materials pretreatment thereof B27N
• CPC Class Codes: D06M 13/12 Aldehydes; Ketones
• CPC Class Codes: D06M 13/207 Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
• CPC Class Codes: D06M 2101/06 cellulosic
• CPC Class Codes: D21C 9/002 by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives

Abstract

The present invention relates to cross-linked cellulosic fiber having improved absorbency characteristics when compared to conventional cross-linked fibers. The cross-linked cellulosic fiber is obtainable by reacting pulp in the sheet or fluff form with one or more reagents selected from organic molecule having acid and aldehyde functional groups “acid aldehydes.” The invention also relates to a method of producing the cross-linked fiber. The method includes heating the treated cellulosic fibers to promote intrafiber cross-linking. The cross-linked fibers are characterized by having an improved centrifuge retention capacity, fluid acquisition rate, resiliency, absorbent capacity, absorbency under load, and other absorbent properties. The inventive cross-linked fibers are useful in forming absorbent composites, and in particular absorbent cores for use in absorbent articles.

Claims

1. A cross-linked cellulosic fiber having a centrifuge retention capacity of less than about 0.48 grams of a 0.9% by weight saline solution per gram of fiber, and a third acquisition insult time of less than 10 seconds.

2. The cross-linked fibers of claim 1, wherein the fibers have an absorption capacity of at least about 9.0 g saline/g fiber.

3. The cross-linked fibers of claim 1, wherein the fibers have a dry bulk of at least about 12 cm³/g fiber.

4. The cross-linked fibers of claim 1, wherein the fibers have a centrifuge retention of not more than 0.45 g saline/g fiber.

5. The cross-linked fibers of claim 1, wherein the fibers have a free swell of at least about 10.0 g saline/g fiber.

6. The cross-linked fiber of claim 1, wherein the fibers have knots and knits contents of less than about 5%.

7. The cross-linked cellulosic fibers of claim 1, wherein the cellulose fiber is a wood pulp fiber selected from the group consisting of hardwood pulp, softwood cellulose pulp obtained from a Kraft or sulfite chemical process, and combinations or mixtures thereof.

8. The cross-linked cellulosic fibers of claim 7, wherein the hardwood cellulose pulp is selected from the group consisting of gum, maple, oak, eucalyptus, poplar, beech, aspen, and combinations and mixtures thereof.

9. The cross-linked cellulosic fiber of claim 7, wherein the soft cellulose pulp is selected from the group consisting of Southern pine, White pine, Caribbean pine, Western hemlock, spruce, Douglas fir, and mixtures and combinations thereof.

10. The cross-linked cellulosic fibers of claim 1, wherein the cellulosic fiber is derived from one or more component selected from the group consisting of cotton linters, bagasse, kemp, flax, grass, and combinations and mixtures thereof.

11. The cross-linked fiber of claim 1, wherein the fibers have an ISO Brightness of greater than 80%.

12. A cross-linked cellulosic fiber prepared by contacting a cellulosic fiber with one or more cross-linking agents, whereby the fiber has a centrifuge retention capacity of less than about 0.48 grams of a 0.9% by weight saline solution per gram of fiber, and a third acquisition insult time of less than 10 seconds.

13. A cross-linked cellulosic fiber cross-linked by a cross-linking agent selected from one or more acid aldehyde organic molecules containing aldehyde and carboxylic acid functional groups, whereby the fiber has a centrifuge retention capacity of less than about 0.60 grams of a 0.9% by weight saline solution per gram of fiber, and a third acquisition insult time of less than 10 seconds.

14. The cross-linked cellulosic fiber of claim 13, wherein the acid aldehyde cross-linking agent is selected from the group consisting of glyoxylic acid, succinic semialdehyde, and mixtures and combinations thereof.

15. The cross-linked cellulosic fiber of claim 14, wherein a mixture of cross-linking agents is used, the mixture of cross-linking agents comprising a primary cross-linking agent and at least one secondary cross-linking agent.

16. The cross-linked cellulosic fiber of claim 15, wherein the primary cross-linking agent is selected from the group consisting of glyoxylic acid, succinic semialdehyde, and mixtures and combinations thereof.

17. The cross-linked cellulosic fiber of claim 15, wherein the secondary cross-linking agent is at least one polyepoxide having a substituent selected from the group consisting of hydrogen;

hydrophobic saturated, unsaturated, cyclic saturated, cyclic unsaturated, branched, unbranched alkyl groups; and

mixtures and combinations thereof.

18. The cross-linked celtulosic fiber of claim 17, wherein the polyepoxide is selected from the group consisting of 1,4 cyclohoxanedimethanol diglycidyl ether, diglycidyl 1,2-cyclohexanedicrboxylate, N,N-diglycidylaniline, N,N-diglcidyl-4-glycidyloxyaniline, diglycidyl 1,2,3,4-tetrahydrophthalate, glyccrol propoxylate triglycidyl ether, and mixtures and combinations thereof.

19. The cross-linked cellulosic fiber of claim 15, wherein the secondary cross-linking agent is one or more C₂–

C₉ polycarboxylic acids selected from the group consisting of butantetracarbocylic acid, citric acid, itaconic acid, maleic acid, tartaric acid, and glutaric acid.

20. The cross-linked cellulosic fiber of claim 15, wherein the secondary cross-linking agent is one or more polycarboxylic acids selected from the group consisting of polyacrylic acid, polymaleic acid, polyitaconic acid, polyaspartic acid, and polymethacrylic acid.

21. The cross-linked cellulosic fiber of claim 13, wherein the fibers have an absorption capacity of at least about 9.0 g saline/g fiber.

22. The cross-linked fibers of claim 13, wherein the fibers have a dry bulk of at least about 12 cm³/g fiber.

23. The cross-linked fibers of claim 13, wherein the fibers have a centrifuge retention of not more than 0.5 g saline/g fiber.

24. The cross-linked fibers of claim 13, wherein the fibers have a free swell of at least about 10.0 g saline/g fiber.

25. The cross-linked fiber of claim 13, wherein the fibers have knots and knits contents of less than about 5%.

26. The cross-linked cellulosic fiber of claim 13, wherein the cellulose fiber is a wood pulp fiber selected from the group consisting of hardwood pulp, softwood cellulose pulp obtained from a Kraft or sulfite chemical process, and combinations or mixtures thereof.

27. The cross-linked cellulosic fiber of claim 26, wherein the hardwood cellulose pulp is selected from the group consisting of gum, maple, oak, eucalyptus, poplar, beech, aspen, and combinations and mixtures thereof.

28. The cross-linked cellulosic fiber of claim 26, wherein the soft cellulose pulp is selected from the group consisting of Southern pine, White pine, Caribbean pine, Western hemlock, spruce, Douglas fir, and mixtures and combinations thereof.

29. The cross-linked cellulosic fiber of claim 13, wherein the cellulosic fiber is derived from one or more component selected from the group consisting of cotton linters, bagasse, kemp, flax, grass, and combinations and mixtures thereof.

30. The cross-linked cellulosic fiber of claim 15, wherein the mixture of cross-linking agents is a mixture selected from the group consisting of:

a mixture of glyoxylic acid and citric acid;

a mixture of glyoxylic acid and polymaleic acid; and

a mixture of glyoxylic acid, citric acid, and polymaleic acid.

31. The cross-linked cellulosic fiber of claim 15, wherein the mixture of cross-linking agents is a mixture selected from the group consisting of:

a mixture of glyoxylic acid and citric acid;

a mixture of glyoxylic acid and a terpolymer of maleic acid, vinyl acetate, and ethyl acrylate; and

a mixture of glyoxylic acid, citric acid, and a terpolymer of maleic acid, vinyl acetate, and ethyl acrylate.