Structured fluid compositions for electrophoretically frustrated total internal reflection displays

• US 7,079,304 B2
• Filed: 01/23/2004
• Issued: 07/18/2006
• Est. Priority Date: 01/23/2004
• Status: Expired due to Fees

• Current Assignee: The Lubrizol Corporation (Berkshire Hathaway Incorporated)
• Original Assignee: The Lubrizol Corporation (Berkshire Hathaway Incorporated)
• Inventors: Kornbrekke, Ralph E., Jones, Robert N., Lawate, Saurabh S.
• Primary Examiner(s): Spector, David N.
• Application Number:
  US10/764,070
• Publication Number:
  US 20050164103A1
• Time in Patent Office: 907 Days
• Field of Search: 204/450, 359/296, 359/297, 345/107, 430/32, 430/38, 252/583
• US Class Current: 359/296
• CPC Class Codes: B01J 13/0034 Additives, e.g. in view of promoting stabilisation or peptisation
• CPC Class Codes: B82Y 20/00 Nanooptics, e.g. quantum optics or photonic crystals
• CPC Class Codes: C09K 23/017 Mixtures of compounds
• CPC Class Codes: G02F 1/167 by electrophoresis
• CPC Class Codes: G02F 1/1677 Structural association of cells with optical devices, e.g. reflectors or illuminating devices
• CPC Class Codes: G02F 2202/36 Micro- or nanomaterials
• CPC Class Codes: G02F 2203/026 attenuated or frustrated internal reflection

Abstract

A structured fluid composition comprising:

• • (a) a low refractive index liquid;
  • (b) particles including light absorbing charged particles such as pigments, non-light absorbing uncharged particles such as teflon, silica, alumina and combinations thereof; and
  • (c) at least one additive selected from the group consisting of a dispersant, a charging agent, a surfactant, a flocculating agent, a polymer, and combination thereof;
    for use in a TIR electronic display.

The inventive composition improves the long-term stability, response time and visible appearance of image displays which electrophoretically frustrate total internal reflection (TIR).

Claims

1. A structured fluid compositio1n comprising:

(a) a low refractive index liquid;

(b) particles selected from the group consisting of light absorbing particles, and non-light absorbing or very low light absorbing particles;

wherein said non-light absorbing or very low light absorbing particles absorbing particles help to create a structured colloidal suspension, and wherein the particles interact through colloidal forces without encapsulating the fluid in isolated compartments; and

(c) at least one additive selected from the group consisting of

(i) a dispersant,

(ii) a charging agent,

(iii) a surfactant,

(iv) a flocculating agent,

(v) a polymer, and

(vi) combinations thereof;

wherein the particles have a sufficient number of functional groups of either acid or base, to allow the dispersant to form a tightly packed mono-layer, and wherein the dispersant has the complementary acid or basic functional group to interact with the particles surface and a molecular structure resulting in a strong interaction between the particles surface and the dispersant to inhibit agglomeration, resulting in a stable suspension that is not agglomerated having ionically charged light absorbing particles, and forming an interactive structure which inhibits motion therein.

2. The composition of claim 1 wherein the liquid electrophoretic medium is comprised of substantially fluorinated oils.

3. The composition of claim 2 wherein the fluorinated oil is perfluorinated.

4. The composition of claim 1 wherein the particles occupy from about 1 to about 75% by weight of the electrophoretic suspension.

5. The composition of claim 1 wherein the light absorbing particles comprise a blue pigment, red pigment, brown pigment, black pigment or combinations thereof.

6. The composition of claim 5 where the blue pigment is selected from a group consisting of chromophthal blue, metal containing phthalo blue, metal free phthalo blue indigo blue and combinations thereof.

7. The composition of claim 5 where the red pigment is selected from a group consisting of monastral red.

8. The composition of claim 5 where the black pigment is selected from a group consisting of carbon black, modified carbon black, iron oxide, aniline black and combinations thereof.

9. The composition of claim 1 wherein the light absorbing particles comprise a mixture of two or more pigment particles to enhance the optical properties, wherein the frustration of total internal reflection is improved by the collective absorption of different wavelengths of light.

10. The composition of claim 1 wherein the composition results in a colloidal structure with a non-Newtonian rheology.

11. The composition of claim 1 wherein the composition results in a colloidal structure which has a yield stress.

12. The composition of claim 1 wherein the particle has a surface treatment selected from the group consisting of reaction with an oxidizing or reducing chemical, reaction with a chemical that covalently bonds to the surface, grafting onto the surface with a plasma containing small molecules with various functional groups or mixtures thereof resulting in improved response time and as herein the dispersant forms a tightly packed monolayer adsorbed on the particle surface resulting in less particle agglomeration.

13. The composition of claim 1 wherein the particles are suspended and have at least two distinct particle size distributions one in the range of about 200 nm to about 500 nm and the other in the range of about 10 nm to about 100 nm.

14. The composition of claim 1 wherein the particles are coupled via reaction with a coupling agent and wherein the coupling agent is bi-functional.

15. The composition of claim 1 wherein the dispersant has only an acidic functional group or a basic functional group.

16. The composition of claim 1 wherein the ratio of dispersant to pigment ranges from about 0.1 to about 3.

17. The composition in claim 1 wherein the concentration of pigment particles is adjusted to maintain small particle separation distance in a homogeneous dispersion so that the distance that the particles move to produce a color change in TIR is small, resulting in a fast response time in producing an image.

18. The composition of claim 1 where the pigment concentration is high enough to enable rapid color change in an electric field.

19. The composition in claim 1 wherein the concentration of components is adjusted to cause a yield stress to impede motion under low shear forces, but with a small enough yield stress to enable rapid motion of particles in a low electric field.

20. The composition of claim 1 wherein the colloidal structure is due to weak flocculation.

21. The composition in claim 1 where the charging agent, dispersant or surfactant forms inverse micelles which increase the particle charge thereby improving the structure and response time of the mixture.

22. The composition of claim 1 wherein the light absorbing particles are pigment and the non light absorbing particles comprise teflon, silica, alumina or mixtures thereof.

23. The composition of claim 1 wherein the light absorbing particles are pigment and the non light absorbing particles comprise teflon, silica, alumina or mixtures thereof.