Chemically cross-linked cellulosic fiber and method of making same

• US 7,094,318 B2
• Filed: 10/28/2003
• Issued: 08/22/2006
• Est. Priority Date: 06/11/2002
• Status: Expired due to Fees

• Current Assignee: Rayonier Performance Fibers, LLC (Rayonier Advanced Materials, Inc.)
• Original Assignee: Rayonier Products and Financial Services Company
• Inventors: Chmielewski, Harry J., Hamed, Othman A., McBee, Dana B.
• Primary Examiner(s): HUG, JOHN ERIC
• Application Number:
  US10/694,348
• Publication Number:
  US 20040084159A1
• Time in Patent Office: 1,029 Days
• Field of Search: 162/9, 162/90, 162/100, 162/157.6, 162/168.1, 162/111, 162/158, 162/72, 162/91, 162/95, 162/141, 162146-149, 162135-137, 162/164.1, 162165-167, 162/183, 811/64, 811/61, 604374-376, 604/378, 604/358, 604/367, 604/372
• US Class Current: 162/146
• CPC Class Codes: A61F 13/15203 Properties of the article, e.g. stiffness or absorbency chemical aspects A61L15/00
• CPC Class Codes: A61F 13/53 characterised by the absorbing medium A61F13/20 takes precedence
• CPC Class Codes: C08B 15/10 Crosslinking of cellulose
• CPC Class Codes: C08H 8/00 Macromolecular compounds derived from lignocellulosic materials pretreatment thereof B27N
• CPC Class Codes: D06M 13/12 Aldehydes; Ketones
• CPC Class Codes: D06M 13/207 Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
• CPC Class Codes: D06M 2101/06 cellulosic
• CPC Class Codes: D21C 9/002 by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives

Abstract

The present invention relates to cross-linked cellulosic fiber having improved absorbency characteristics when compared to conventional cross-linked fibers. The cross-linked cellulosic fiber is obtainable by reacting pulp in the sheet or fluff form with one or more reagents selected from organic molecule having acid and aldehyde functional groups “acid aldehydes.” The invention also relates to a method of producing the cross-linked fiber. The method includes heating the treated cellulosic fibers to promote intrafiber cross-linking. The cross-linked fibers are characterized by having an improved centrifuge retention capacity, fluid acquisition rate, resiliency, absorbent capacity, absorbency under load, and other absorbent properties. The inventive cross-linked fibers are useful in forming absorbent composites, and in particular absorbent cores for use in absorbent articles.

Claims

1. An absorbent article comprising a crosslinked cellulosic fiber having a centrifuge retention capacity of less than about 0.48 grams of a 0.9% by weight saline solution per gram of fiber and a third-insult acquisition time of less than 10 seconds.

2. The absorbent article of claim 1, wherein the absorbent article is at least one article selected from the group consisting of infant diapers, feminine care products, training pants, and adult incontinence briefs.

3. The absorbent article of claim 1 comprising a liquid penetrable top sheet, a liquid impenetrable back sheet, an acquisition layer, and an absorbent structure, wherein the acquisition layer is disposed beneath the top sheet, and the absorbent structure is located between the acquisition layer and the back sheet.

4. The absorbent article of claim 3, wherein the acquisition layer comprises the cross-linked fiber.

5. The absorbent article of claim 3, wherein the absorbent structure comprises a composite of superabsorbent polymer and cellulosic fiber.

6. The absorbent article of claim 5, wherein the superabsorbent polymer is selected from the group consisting of polyacrylate polymers, starch graft copolymers, cellulose graft copolymers, cross-linked carboxymethylcellulose derivatives, and mixtures and combinations thereof.

7. The absorbent article of claim 5, wherein the superabsorbent polymer is in the form of fiber, flakes, or granules.

8. The absorbent article of claim 5, wherein the superabsorbent polymer is present in an amount of from about 20 to about 60% by weight, based on the total weight of the absorbent structure.

9. The absorbent article of claim 5, wherein the cellulosic fiber comprises the cross-linked cellulosic fiber.

10. The absorbent article of claim 9, wherein the cellulosic fiber comprises a mixture of the cross-linked cellulosic fiber and cellulosic fiber.

11. The absorbent article of claim 10, wherein the cellulosic fiber is a wood pulp fiber selected from the group consisting of hardwood pulp, softwood cellulose pulp obtained from a Kraft or sulfite chemical process, caustic treated wood pulp, rayon, cotton linters, and combinations or mixtures thereof.

12. The absorbent article of claim 10, wherein the cross-linked cellulosic fiber is present in the mixture of fibers in an amount of from about 1 to 70% by weight, based on the total weight of the total fiber.

13. The absorbent article of claim 12, wherein the cross-linked cellulosic fiber is present in an amount of from about 10 to 40% by weight, based on the total weight of the total fiber.

14. The absorbent article of claim 10, wherein the mixture of cellulosic fiber is present in an amount of from about 10 to about 80% by weight, based on the total weight of the absorbent structure.

15. The absorbent article claim 10, wherein the mixture of cellulosic fiber is present in an amount of from about 20 to about 60% by weight, based on the total weight of the absorbent structure.