Optical compensatory sheet comprising polymer film

• US 7,105,212 B2
• Filed: 04/18/2003
• Issued: 09/12/2006
• Est. Priority Date: 04/19/2002
• Status: Active Grant

• Current Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Original Assignee: Fuji Photo Film Co Limited (Fujifilm Holdings Corporation)
• Inventors: Ito, Yoji
• Primary Examiner(s): Pyon, Harold
• Assistant Examiner(s): HON, SOW FUN
• Application Number:
  US10/508,864
• Publication Number:
  US 20050123693A1
• Time in Patent Office: 1,243 Days
• Field of Search: 428/1.1, 428/1.3, 428/1.33, 349117-119, 349/12, 349/162, 345/104, 345/173, 252/299.01
• US Class Current: 428/1.3
• CPC Class Codes: C08J 2301/12 Cellulose acetate
• CPC Class Codes: C08J 5/18 Manufacture of films or sheets
• CPC Class Codes: C08L 101/12 characterised by physical features, e.g. anisotropy, viscosity or electrical conductivity liquid crystal materials or compositions C09K19/00
• CPC Class Codes: C09K 2323/03 Viewing layer characterised by chemical composition
• CPC Class Codes: C09K 2323/035 Ester polymer, e.g. polycarbonate, polyacrylate or polyester
• CPC Class Codes: G02B 1/04 made of organic materials, e.g. plastics G02B1/08 takes precedence
• CPC Class Codes: G02B 5/208 for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation
• CPC Class Codes: G02B 5/3083 Birefringent or phase retarding elements G02B5/3008, G02B5/3016 take precedence; systems for polarisation control G02B27/286; manufacturing phase modulating patterns by lithographic processes G03F7/001

Abstract

A polymer film is used as an optical compensatory sheet or a support thereof. The polymer film contains a rod-like compound. The rod-like compound in the form of a solution gives an ultraviolet absorption spectrum. In the spectrum, the wavelength of λmax at the maximum absorption peak is shorter than 250 nm. The spectrum of the rod-like compound is measured when the rod-like compound is in the form of solution. The polymer film has an Rth retardation value of Rth450 measured at the wavelength of 450 nm in the range of 30 to 160 nm. The polymer film also has an Rth retardation value of Rth590 measured at the wavelength of 590 nm in the range of 50 to 200 nm. The values of the Rth450 and Rth590 satisfy the condition of Rth590-Rth450≧2 nm.

Claims

1. An optical compensatory sheet which consists of a polymer film containing a rod-shaped compound, which gives an ultraviolet absorption spectrum, in which the wavelength of λ

max at the maximum absortion peak is shorter than 250 nm, wherein said spectrum of the rod-shaped compound is measured when the rod-shaped compound is in the form of a solution, wherein the polymer film has an Rth retardation value of Rth450 measured at the wavelength of 450 nm in the range of 30 to 160 nm, and an Rth retardation value of Rth590 measured at the wavelength of 590 nm in the range of 50 to 200 nm, said values of the Rth450 and Rth590 satisfying the condition of Rth590-Rth450≧

2 nm.

2. The optical compensatory sheet of claim 1, wherein the polymer film has an Re retardation value of Re450 measured at the wavelength of 450 nm in the range of 10 to 60 nm, and an Re retardation value of Re590 measured at the wavelength of 590 nm in the range of 20 to 70 nm, said values of Re450 and Re590 satisfying the condition of Re590-Re450≧

2 nm.

3. The optical compensatory sheet of claim 1, wherein the polymer film is made of cellulose ester.

4. The optical compensatory sheet of claim 1, wherein the polymer film is a film stretched with a stretching ratio of 3 to 100%.

5. The optical compensatory sheet of claim 1, wherein the rod-shaped compound has a linear molecular structure.

6. The optical compensatory sheet of claim 1, wherein the rod-shaped compound is a liquid crystal.

7. The optical compensatory sheet of claim 1, wherein the rod-shaped compound is represented by the formula (III):

Ar¹-L¹-Ar² 

 

(III)

in which each of Ar¹ and Ar² independently is an aromatic group; and

L¹ is a divalent linking group selected from the group consisting of an alkylene group, an alkenylene group, an alkynylene group, a divalent saturated heterocyclic group, —

O—

, —

CO— and

a combination thereof.

8. The optical compensatory sheet of claim 7, wherein the rod-shaped compound is represented by the formula (IV):

Ar¹-L²-X-L³-Ar² 

 

(IV)

in which each of Ar¹ and Ar² independently is an aromatic group;

each of L² and L³ independently is a divalent linking group selected from the group consisting of an alkylene group, —

O—

, —

CO— and

a combination thereof; and

X is 1 ,4-cyclohexylene, vinylene or ethynylene.

9. An image display device comprising an optical compensatory sheet, wherein the optical compensatory sheet consists of a polymer film containing a rod-shaped compound, which gives an ultraviolet absorption spectrum, in which the wavelength of λ

max at the maximum absorption peak is shorter than 250 nm, wherein said spectrum of the rod-shaped compound is measured when the rod-shaped compound is in the form of a solution, wherein the polymer film has an Rth retardation value of Rth450 measured at the wavelength of 450 nm in the range of 30 to 160 nm, and an Rth retardation value of Rth590 measured at the wavelength of 590 nm in the range of 50 to 200 nm, said values of the Rth450 and Rth590 satisfying the condition of Rth590-Rth450≧

2 nm.

10. A polarizing plate comprising a pair of transparent protective films and a polarizing membrane provided between the transparent protective films, wherein at least one of the protective films is an optical compensatory sheet which consists of a polymer film containing a rod-shaped compound, which gives an ultraviolet absorption spectrum, in which the wavelength of λ

max at the maximum absorption peak is shorter than 250 nm, wherein said spectrum of the rod-shaped compound is measured when the rod-shaped compound is in the form of a solution, wherein the polymer film has an Rth retardation value of Rth450 measured at the wavelength of 450 nm in the range of 30 to 160 nm, and an Rth retardation value of Rth590 measured at the wavelength of 590 nm in the range of 50 to 200 nm, said values of the Rth450 and Rth590 satisfying the condition of Rth590-Rth450≧

2 nm, and wherein the optical compensatory sheet and the polarizing membrane are so placed that the transmission axis of the membrane is parallel or perpendicular to the slow axis of the polymer film.

11. An image display device comprising a polarizing plate, said polarizing plate comprising a pair of transparent protective films and a polarizing membrane provided between the transparent protective films, wherein at least one of the protective films is an optical compensatory sheet which consists of a polymer film containing a rod-shaped compound, which gives an ultraviolet absorption spectrum, in which the wavelength of λ

max at the maximum absorption peak is shorter than 250 nm, wherein said spectrum of the rod-shaped compound is measured when the rod-shaped compound is in the form of a solution, wherein the polymer film has an Rth retardation value of Rth450 measured at the wavelength of 450 nm in the range of 30 to 160 nm, and an Rth retardation value of Rth590 measured at the wavelength of 590 nm in the range of 50 to 200 nm, said values of the Rth450 and Rth590 satisfying the condition of Rth590-Rth450≧

2 nm, and wherein the optical compensatory sheet and the polarizing membrane are so placed that the transmission axis of the membrane is parallel or perpendicular to the slow axis of the polymer film.

12. An optical compensatory sheet which comprises an optically anisotropic layer and a polymer film, said optically anisotropic layer being formed from a liquid crystal compound, and wherein said polymer film contains a rod-shaped compound, which gives an ultraviolet absorption spectrum, in which the wavelength of λ

max at the maximum absorption peak is shorter than 250 nm, wherein said spectrum of the rod-shaped compound is measured when the rod-shaped compound is in the form of a solution, wherein the polymer film has an Rth retardation value of Rth450 measured at the wavelength of 450 nm in the range of 30 to 160 nm, and an Rth retardation value of Rth590 measured at the wavelength of 590 nm in the range of 50 to 200 nm, said values of the Rth450 and Rth590 satisfying the condition of Rth590-Rth450≧

2 nm.

13. The optical compensatory sheet of claim 12, wherein the polymer film has an Re retardation value of Re450 measured at the wavelength of 450 nm in the range of 10 to 60 nm, and an Re retardation value of Re590 measured at the wavelength of 590 nm in the range of 20 to 70 nm, said values of the Re450 and Re590 satisfying the condition of Re590-Re450≧

2 nm.

14. The optical compensatory sheet of claim 12, wherein the polymer film is made of cellulose ester.

15. The optical compensatory sheet of claim 12, wherein the polymer film is a film stretched with a stretching ratio of 3 to 100%.

16. The optical compensatory sheet of claim 12, wherein the rod-shaped compound has a linear molecular structure.

17. The optical compensatory sheet of claim 12, wherein the rod-shaped compound is a liquid crystal.

18. The optical compensatory sheet of claim 12, wherein the rod-shaped compound is represented by the formula (III):

Ar¹-L¹-Ar² 

 

(III)

in which each of Ar¹ and Ar² independently is an aromatic group; and

L¹ is a divalent linking group selected from the group consisting of an alkylene group, an alkenylene group, an alkynylene group, a divalent saturated heterocyclic group, —

O—

, —

CO— and

a combination thereof.

19. The optical compensatory sheet of claim 18, wherein the rod-shaped compound is represented by the formula (IV):

Ar¹-L²-X-L³-Ar² 

 

(IV)

in which each of Ar¹ and Ar² independently is an aromatic group;

each of L² and L³ independently is a divalent linking group selected from the group consisting of an alkylene group, —

O—

, —

CO— and

a combination thereof and X is 1,4-cyclohexylene, vinylene or ethynylene.

20. An image display device comprising an optical compensatory sheet, wherein the optical compensatory sheet comprises an optically anisotropic layer and a polymer film, said optically anisotropic layer being formed from a liquid crystal compound, and wherein said polymer film contains a rod-shaped compound, which gives an ultraviolet absorption spectrum, in which the wavelength of λ

max at the maximum absorption peak is shorter than 250 nm, wherein said spectrum of the rod-shaped compound is measured when the rod-shaped compound is in the form of a solution, wherein the polymer film has an Rth retardation value of Rth450 measured at the wavelength of 450 nm in the range of 30 to 160 nm, and an Rth retardation value of Rth590 measured at the wavelength of 590 nm in the range of 50 to 200 nm, said values of the Rth450 and Rth590 satisfying the condition of Rth590-Rth450≧

2 nm.

21. A polarizing plate comprising a pair of transparent protective films and a polarizing membrane provided between the transparent protective films, wherein at least one of the protective films is an optical compensatory sheet which comprises an optically anisotropic layer and a polymer film, said optically anisotropic layer being formed from a liquid crystal compound, and wherein said polymer film contains a rod-shaped compound, which gives an ultraviolet absorption spectrum, in which the wavelength of λ

max at the maximum absorption peak is shorter than 250 nm, wherein said spectrum of the rod-shaped compound is measured when the rod-shaped compound is in the form of a solution, wherein the polymer film has an Rth retardation value of Rth450 measured at the wavelength of 450 nm in the range of 30 to 160 nm, and an Rth retardation value of Rth590 measured at the wavelength of 590 nm in the range of 50 to 200 nm, said values of the Rth450 and Rth590 satisfying the condition of Rth590-Rth450≧

2 nm, and wherein the optical compensatory sheet and the polarizing membrane are so placed that the transmission axis of the membrane is parallel or perpendicular to the slow axis of the polymer film.

22. An image display device comprising a polarizing plate, said polarizing plate comprising a pair of transparent protective films and a polarizing membrane provided between the transparent protective films, wherein at least one of the protective films is an optical compensatory sheet which comprises an optically anisotropic layer and a polymer film, said optically anisotropic layer being formed from a liquid crystal compound, and wherein said polymer film contains a rod-shaped compound, which gives an ultraviolet absorption spectrum, in which the wavelength of λ

max at the maximum absorption peak is shorter than 250 nm, wherein said spectrum of the rod-shaped compound is measured when the rod-shaped compound is in the form of a solution, wherein the polymer film has an Rth retardation value of Rth450 measured at the wavelength of 450 nm in the range of 30 to 160 nm, and an Rth retardation value of Rth590 measured at the wavelength of 590 nm in the range of 50 to 200 nm, said values of the Rth450 and Rth590 satisfying the condition of Rth590-Rth450≧

2 nm, and wherein the optical compensatory sheet and the polarizing membrane are so placed that the transmission axis of the membrane is parallel or perpendicular to the slow axis of the polymer film.