Electrically conductive oil-based mud

• US 7,112,557 B2
• Filed: 10/09/2003
• Issued: 09/26/2006
• Est. Priority Date: 08/27/2001
• Status: Expired due to Term

• Current Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Original Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Inventors: Thaemlitz, Carl Joseph
• Primary Examiner(s): Tucker, Philip C.
• Application Number:
  US10/681,979
• Publication Number:
  US 20040116303A1
• Time in Patent Office: 1,083 Days
• Field of Search: 507/116, 507/136, 507/103, 507/138
• US Class Current: 507/116
• CPC Class Codes: C09K 8/32 Non-aqueous well-drilling compositions, e.g. oil-based
• CPC Class Codes: E21B 47/00 Survey of boreholes or wells monitoring pressure or flow of drilling fluid E21B21/08
• CPC Class Codes: G01V 3/20 operating with propagation of electric current
• CPC Class Codes: Y02A 90/30 Assessment of water resources

Abstract

An electrically conductive oil mud meeting the fluid requirements for resistive logging tools and a method for preparing such mud is disclosed. The fluid has been optimized to deliver performance in a manner as similar to that of a traditional invert emulsion drilling fluid as is practical while still maintaining the required electrical conductivity for resistivity-based logging tools. This electrically conductive oil-based mud comprises a polar synthetic ester base and complimentary ester surfactants, one being more oil soluble, the other being more water soluble. The surfactants interact synergistically to provide dense packing of micelles at the palisade layer. This fluid is oil-wetting to solids, and in general behaves like a traditional oil mud.

Claims

1. A drilling fluid comprising a polar base oil and complimentary fatty acid surfactants blended or combined such that the base oil and the surfactants comprise the oil based layer of an invert emulsion, wherein the base oil and the surfactants comprise about 90 volume percent of the emulsion and calcium chloride brine comprises the water phase of the emulsion, wherein said complimentary fatty acid surfactants are selected from the group consisting of sorbitan esters, sorbitan ester derivatives, ethoxylated sorbitan esters, ethoxylated sorbitan ester derivatives, and combinations thereof, and wherein at least one of the complimentary fatty acid surfactants is more water soluble than another and at least one of the complimentary fatty acid surfactants is more oil soluble than another, such that the surfactants form micelles in quantities providing a staggered arrangement and denser concentration in the palisade layer of the drilling fluid than either surfactant would form alone, such that the drilling fluid has sufficient electrical conductivity to facilitate resistance-based wellbore logging while also having utility as an oil-based drilling fluid.

3. The drilling fluid of claim 1 wherein said polar base oil is a synthetic ester based oil.

4. The drilling fluid of claim 1 further comprising a fluid loss additive.

5. The drilling fluid of claim 4 wherein said fluid loss additive is selected from the group consisting of:

oleic acid;

qunternary ammuonium compounds;

calcium carbonates;

styrene butadiene; and

combinations thereof.

13. The drilling fluid of claim 1 wherein said fluid effects said electrical conductivity over a broad temperature range.

2. An electrically conductive drilling fluid comprising a polar ester oil-base, a sorbitan ester derivative surfactant, and an ethoxylated sorbitan ester derivative surfactant, wherein said surfactants are in quantities sufficient to create micelles having enhanced concentration in the palisade layer, and wherein said polar ester oil-base comprises a monocarboxylic acid ester of a C₂ to C₁₂ monofunctional alkanol.

6. The drilling fluid of claim 2 wherein said micelles in the palisade layer are packed sufficiently close to yield a rigid surfactant film.

7. The drilling fluid of claim 2 wherein said fluid is prepared by formulating an invert emulsion comprising said base oil to which is added said ethoxylated sorbitan ester derivative followed by said sorbitan ester derivative.

8. The drilling fluid of claim 7 wherein said emulsion comprises about 85 to about 95 volume percent ester and about 5 to about 15 volume percent brine.

9. The drilling fluid of claim 8 wherein said volume percent ester comprises said ester base oil, said sorbitan ester derivative, and said ethoxylated sorbitan ester derivative.

10. The drilling fluid of claim 2 wherein said sorbitan ester has the formula:

11. The drilling fluid of claim 2 wherein said ethoxylated sorbitan ester has a formula die same as or similar to:

12. The drilling fluid of claim 2 wherein said sorbitan ester derivative and said ethoxylated sorbitan ester derivative are complimentary.