Electro-optic displays

• US 7,116,466 B2
• Filed: 07/26/2005
• Issued: 10/03/2006
• Est. Priority Date: 07/27/2004
• Status: Active Grant

• Current Assignee: E Ink Holdings Incorporated
• Original Assignee: E Ink Holdings Incorporated
• Inventors: Paolini, Richard J. Jr., Honeyman, Charles Howie, Whitesides, Thomas H., McCreary, Michael M.
• Primary Examiner(s): THOMPSON, TIMOTHY J
• Application Number:
  US11/161,179
• Publication Number:
  US 20060023296A1
• Time in Patent Office: 434 Days
• Field of Search: 359/296, 359/243, 359/240, 359/290, 345/107, 204/478, 204/485
• US Class Current: 359/296
• CPC Class Codes: G02F 1/133345 Insulating layers G02F1/1335, G02F1/1337, G02F1/135, G02F1/136 take precedence
• CPC Class Codes: G02F 1/167 by electrophoresis
• CPC Class Codes: G02F 1/16756 Insulating layers
• CPC Class Codes: G02F 2201/52 RGB geometrical arrangements
• CPC Class Codes: G02F 2203/01 transmissive
• CPC Class Codes: G09G 3/344 based on particles moving in a fluid or in a gas, e.g. electrophoretic devices electrophoretic devices per se G02F1/167

Abstract

An electrophoretic display comprises an electrophoretic medium having a plurality of charged particles suspended in a suspending fluid, and two electrodes disposed on opposed sides of the electrophoretic medium. At least one of the electrodes is light-transmissive and forming a viewing surface. The display has a closed optical state in which the charged particles are spread over substantially the entire viewing surface so that light cannot pass through the medium, and an open optical state in which the electrophoretic particles form chains extending between the electrodes so that light can pass through the electrophoretic medium. Insulating layers are disposed between the electrodes and the electrophoretic medium. Similarly electrophoretic displays are provided equipped with color filter arrays or reflectors.

Claims

1. An electrophoretic display comprising:

an electrophoretic medium having a plurality of charged particles suspended in a suspending fluid and confined within a plurality of capsules, the capsules being held within a polymeric binder, and

two electrodes disposed on opposed sides of the electrophoretic medium, at least one of the electrodes being light-transmissive and forming a viewing surface through which an observer can view the display,

the display having a closed optical state in which the charged particles are spread over substantially the entire viewing surface so that light cannot pass through the electrophoretic medium, and an open optical state in which the electrophoretic particles form chains extending between the electrodes so that light can pass through the electrophoretic medium,

the display further comprising insulating layers disposed between the electrodes and the electrophoretic medium.

2. An electrophoretic display according to claim 1 wherein at least some of the charged particles are electrically conductive.

3. An electrophoretic display according to claim 2 where in the electrically conductive particles comprise carbon black.

4. An electrophoretic display according to claim 1 wherein at least one of the insulating layers has a volume resistivity of about 10⁹ to about 10¹¹ ohm cm.

5. An electrophoretic display according to claim 1 wherein the insulating layer remote from the viewing surface is formed by an adhesive layer.

6. An electrophoretic display according to claim 1 wherein at least one of the insulating layers is comprised of the binder and/or the walls of the capsules.

7. An electrophoretic display according to claim 1 further comprising voltage supply means for applying voltages to the two electrodes, the voltage supply means being arranged to supply both a high frequency alternating current voltage effective to drive the display to its open optical state and a low frequency alternating or direct current voltage effective to drive the display to its closed optical state.

8. An electrophoretic display according to claim 7 wherein the high frequency alternating current voltage has a frequency in the range of about 200 to about 1000 Hz, and the low frequency alternating or direct current voltage has a frequency in the range of 0 to about 50 Hz.

9. An electrophoretic display according to claim 7 wherein the voltage supply means is further arranged to supply at least one intermediate frequency alternating current voltage having a frequency intermediate those of the high frequency alternating current voltage and the low frequency alternating or direct current voltage, the intermediate frequency alternating current voltage being effective to drive the display to a gray state intermediate the open and closed optical states of the display.

10. An electrophoretic display according to claim 1 wherein the suspending fluid has dissolved or dispersed therein a polymer having an intrinsic viscosity of η

in the suspending fluid and being substantially free from ionic or ionizable groups in the suspending fluid, the polymer being present in the suspending fluid in a concentration of from about 0.5η

<sup>−

1</sup> to about 2.0η

<sup>−

1</sup>.

11. An electrophoretic display according to claim 10 wherein the polymer is a polyisobutylene.

12. An electrophoretic display comprising:

an electrophoretic medium having a plurality of charged particles suspended in a suspending fluid, and

two electrodes disposed on opposed sides of the electrophoretic medium, at least one of the electrodes being light-transmissive and forming a viewing surface through which an observer can view the display,

the display having a closed optical state in which the charged particles are spread over substantially the entire viewing surface so that light cannot pass through the electrophoretic medium, and an open optical state in which the electrophoretic particles form chains extending between the electrodes so that light can pass through the electrophoretic medium,

the display further comprising insulating layers disposed between the electrodes and the electrophoretic medium, at least one of the insulating layers having a volume resistivity of about 10⁹ to about 10¹¹ ohm cm.

13. An electrophoretic display comprising:

an electrophoretic medium having a plurality of charged particles suspended in a suspending fluid, and

two electrodes disposed on opposed sides of the electrophoretic medium, at least one of the electrodes being light-transmissive and forming a viewing surface through which an observer can view the display,

the display having a closed optical state in which the charged particles are spread over substantially the entire viewing surface so that light cannot pass through the electrophoretic medium, and an open optical state in which the electrophoretic particles form chains extending between the electrodes so that light can pass through the electrophoretic medium,

the display further comprising insulating layers disposed between the electrodes and the electrophoretic medium, the insulating layer remote from the viewing surface being formed by an adhesive layer.

14. An electrophoretic display comprising:

an electrophoretic medium having a plurality of charged particles suspended in a suspending fluid, the charged particles and the suspending fluid being present as a plurality of discrete droplets held within a continuous phase comprising a polymeric binder, and

two electrodes disposed on opposed sides of the electrophoretic medium, at least one of the electrodes being light-transmissive and forming a viewing surface through which an observer can view the display,

the display having a closed optical state in which the charged particles are spread over substantially the entire viewing surface so that light cannot pass through the electrophoretic medium, and an open optical state in which the electrophoretic particles form chains extending between the electrodes so that light can pass through the electrophoretic medium,

the display further comprising insulating layers disposed between the electrodes and the electrophoretic medium.

15. An electrophoretic display according to claim 14 in which the continuous phase forms walls separating a plurality of cells in which the charged particles and the suspending fluid are confined.

16. An electrophoretic display according to claim 14 wherein at least some of the charged particles are electrically conductive.

17. An electrophoretic display according to claim 16 wherein the electrically conductive particles comprise carbon black.

18. An electrophoretic display according to claim 14 wherein at least one of the insulating layers has a volume resistivity of about 10⁹ to about 10¹¹ ohm cm.

19. An electrophoretic display according to claim 14 wherein the insulating layer remote from the viewing surface is formed by an adhesive layer.

20. An electrophoretic display according to claim 14 further comprising voltage supply means for applying voltages to the two electrodes, the voltage supply means being arranged to supply both a high frequency alternating current voltage effective to drive the display to its open optical state and a low frequency alternating or direct current voltage effective to drive the display to its closed optical state.

21. An electrophoretic display according to claim 20 wherein the high frequency alternating current voltage has a frequency in the range of about 200 to about 1000 Hz, and the low frequency alternating or direct current voltage has a frequency in the range of 0 to about 50 Hz.

22. An electrophoretic display according to claim 20 wherein the voltage supply means is further arranged to supply at least one intermediate frequency alternating current voltage having a frequency intermediate those of the high frequency alternating current voltage and the low frequency alternating or direct current voltage, the intermediate frequency alternating current voltage being effective to drive the display to a gray state intermediate the open and closed optical states of the display.

23. An electrophoretic display according to claim 14 wherein the suspending fluid has dissolved or dispersed therein a polymer having an intrinsic viscosity of η

in the suspending fluid and being substantially free from ionic or ionizable groups in the suspending fluid, the polymer being present in the suspending fluid in a concentration of from about 0.5η

<sup>−

1</sup> to about 2.0η

<sup>−

1</sup>.

24. An electrophoretic display according to claim 23 wherein the polymer is a polyisobutylene.

25. An electrophoretic display comprising:

an electrophoretic medium having a plurality of charged particles suspended in a suspending fluid, and

two electrodes disposed on opposed sides of the electrophoretic medium, at least one of the electrodes being light-transmissive and forming a viewing surface through which an observer can view the display,

the display having a closed optical state in which the charged particles are spread over substantially the entire viewing surface so that light cannot pass through the electrophoretic medium, and an open optical state in which the electrophoretic particles form chains extending between the electrodes so that light can pass through the electrophoretic medium,

the display further comprising insulating layers disposed between the electrodes and the electrophoretic medium; and

voltage supply means for applying voltages to the two electrodes, the voltage supply means being arranged to supply both a high frequency alternating current voltage effective to drive the display to its open optical state and a low frequency alternating or direct current voltage effective to drive the display to its closed optical state.

26. An electrophoretic display according to claim 25 wherein the high frequency alternating current voltage has a frequency in the range of about 200 to about 1000 Hz, and the low frequency alternating or direct current voltage has a frequency in the range of 0 to about 50 Hz.

27. An electrophoretic display according to claim 25 wherein the voltage supply means is further arranged to supply at least one intermediate frequency alternating current voltage having a frequency intermediate those of the high frequency alternating current voltage and the low frequency alternating or direct current voltage, the intermediate frequency alternating current voltage being effective to drive the display to a gray state intermediate the open and closed optical states of the display.

28. An electrophoretic display according to claim 25 wherein at least some of the charged particles are electrically conductive.

29. An electrophoretic display according to claim 28 wherein the electrically conductive particles comprise carbon black.

30. An electrophoretic display according to claim 25 wherein at least one of the insulating layers has a volume resistivity of about 10⁹ to about 10¹¹ ohm cm.

31. An electrophoretic display according to claim 25 wherein the insulating layer remote from the viewing surface is formed by an adhesive layer.

32. An electrophoretic display according to claim 25 wherein the suspending fluid has dissolved or dispersed therein a polymer having an intrinsic viscosity of η

in the suspending fluid and being substantially free from ionic or ionizable groups in the suspending fluid, the polymer being present in the suspending fluid in a concentration of from about 0.5η

<sup>−

1</sup> to about 2.0η

<sup>−

1</sup>.

33. An electrophoretic display according to claim 32 wherein the polymer is a polyisobutylene.

34. An electrophoretic display comprising:

an electrophoretic medium having a plurality of charged particles suspended in a suspending fluid, the suspending fluid having dissolved or dispersed therein a polymer having an intrinsic viscosity of η

in the suspending fluid and being substantially free from ionic or ionizable groups in the suspending fluid, the polymer being present in the suspending fluid in a concentration of from about 0.5η

<sup>−

1</sup> to about 2.0η

<sup>−

1</sup>; and

two electrodes disposed on opposed sides of the electrophoretic medium, at least one of the electrodes being light-transmissive and forming a viewing surface through which an observer can view the display,

the display having a closed optical state in which the charged particles are spread over substantially the entire viewing surface so that light cannot pass through the electrophoretic medium, and an open optical state in which the electrophoretic particles form chains extending between the electrodes so that light can pass through the electrophoretic medium,

the display further comprising insulating layers disposed between the electrodes and the electrophoretic medium.

35. An electrophoretic display according to claim 34 wherein the polymer is a polyisobutylene.