Structured fluid compositions for electrophoretically frustrated total internal reflection displays

• US 7,116,467 B2
• Filed: 10/11/2005
• Issued: 10/03/2006
• Est. Priority Date: 01/23/2004
• Status: Active Grant

• Current Assignee: The Lubrizol Corporation (Berkshire Hathaway Incorporated)
• Original Assignee: The Lubrizol Corporation (Berkshire Hathaway Incorporated)
• Inventors: Kornbrekke, Ralph E., Jones, Robert N., Lawate, Saurabh S.
• Primary Examiner(s): Spector, David N.
• Application Number:
  US11/247,710
• Publication Number:
  US 20060056009A1
• Time in Patent Office: 357 Days
• Field of Search: 204/450, 252/583, 345/345, 359/296, 359/297, 430/32, 430/38
• US Class Current: 359/296
• CPC Class Codes: B01J 13/0034 Additives, e.g. in view of promoting stabilisation or peptisation
• CPC Class Codes: B82Y 20/00 Nanooptics, e.g. quantum optics or photonic crystals
• CPC Class Codes: C09K 23/017 Mixtures of compounds
• CPC Class Codes: G02F 1/167 by electrophoresis
• CPC Class Codes: G02F 1/1677 Structural association of cells with optical devices, e.g. reflectors or illuminating devices
• CPC Class Codes: G02F 2202/36 Micro- or nanomaterials
• CPC Class Codes: G02F 2203/026 attenuated or frustrated internal reflection

Abstract

A structured fluid composition comprising:

• • (a) a low refractive index liquid;
  • (b) particles including light absorbing charged particles such as pigments, non-light absorbing uncharged particles such as teflon, silica, alumina and combinations thereof; and
  • (c) at least one additive selected from the group consisting of a dispersant, a charging agent, a surfactant, a flocculating agent, a polymer, and combination thereof;
    for use in a TIR electronic display.

The inventive composition improves the long-term stability, response time and visible appearance of image displays which electrophoretically frustrate total internal reflection (TIR).

Claims

1. An electronically addressable display, comprising:

(a) a transparent upper front sheet;

(b) a lower sheet that is essentially parallel to and spaced from the upper front sheet;

(c) a structured electrophoretic suspension substantially filling the space between the sheets which structure is controlled by the composition of the suspension, wherein the composition comprises a low refractive index liquid;

a light absorbing particles;

particles which are not light absorbing; and

at least one additive selected from the group consisting of a dispersant, a charging agent, a surfactant, a flocculating agent, a polymer, and combination thereof; and

(d) a means for applying a voltage across the suspension for controllably compressing the suspension away from the inward surface of the front sheet to either form a thin particle free liquid layer to allow total internal reflection or a layer with a higher concentration of particles to frustrate total internal reflection at the inward surface of light rays passing through the front sheet.

2. The display of claim 1 wherein the composition is a structured fluid composition comprising:

(a) a low refractive index liquid;

(b) particles selected from the group consisting of light absorbing particles;

non-light absorbing particles or very low light-absorbing, particles wherein the non-light absorbing particles help to create a structured colloidal suspension; and

wherein the particles interact through colloidal forces without encapsulating the fluid in isolated compartments; and

(c) at least one additive selected from the group consisting of

(i) a dispersant,

(ii) a charging agent,

(iii) a surfactant,

(iv) a flocculating agent,

(v) a polymer, and

(vi) combination thereof;

wherein the particle has a sufficient number of functional groups of either acid or base, to allow the dispersant to form a tightly packed mono-layer, and wherein the dispersant has the complementary acid or basic function group to interact with the particle surface and a molecular structure resulting in a strong interaction between the particle surface and the dispersant to inhibit agglomeration,

resulting in a stable suspension that is not agglomerated, having ionically charged light absorbing particles, and forming an interactive structure which inhibits motion therein, wherein the liquid electrophoretic medium is comprised of substantially fluorinated oils.

3. The display of claim 2 wherein the liquid electrophoretic medium is comprised of substantially fluorinated oils.

4. The display of claim 2 wherein the particles of the composition occupy from about 1 to about 75% by weight of the electrophoretic suspension.

5. The display of claim 2 wherein the particles of the composition comprise a blue pigment, red pigment, brown pigment, black pigment and combinations thereof.

6. The display of claim 5 comprising a mixture of two or more pigment particles to enhance the optical properties, wherein the frustration of total internal reflection is improved by the collective absorption of different wavelengths of light.

7. The display of claim 2 wherein the composition results in a colloidal structure with a non-Newtonian rheology.

8. The display of claim 2 wherein the composition results in a colloidal structure which has a yield stress.

9. The display of claim 2 wherein the particles of the composition have a surface treatment selected from the group consisting of reaction with an oxidizing or reducing chemical, reaction with a chemical that covalently bonds to the surface, grafting onto the surface with a plasma containing small molecules with various functional groups or mixtures thereof resulting in improved response time and as herein the dispersant forms a tightly packed monolayer adsorbed on the particle surface resulting in less particle agglomeration.

10. The display of claim 2

(a) wherein the particles of the composition have a sufficient number of functional groups of either acid or base, to allow a dispersant to form a tightly packed mono-layer, and

(b) wherein the dispersant has the complementary acid or basic functional group to interact with the particle surface and a molecular structure resulting in a strong interaction between the particle surface and the dispersant to inhibit agglomeration.

11. The display of claim 2 wherein the particles of the composition are suspended and have at least two distinct particle size distributions one in the range of about 200 nm to about 500 nm and the other in the range of about 10 nm to about 100 nm.

12. The display of claim 2 wherein the dispersant has only an acidic functional group or a basic functional group.

13. The display of claim 2 wherein the ratio of dispersant to pigment ranges from about 0.1 to about 3.

14. The display in claim 2 wherein the concentration of pigment particles is adjusted to maintain small particle separation distance in a homogeneous dispersion so the distance that particles must move to produce a color change in TIR is small, in a fast response time in producing an image.

15. The display of claim 2 where the pigment concentration is high enough to enable rapid color change in an electric field.

16. The display in claim 2 wherein the charging agent, dispersant or surfactant forms inverse micelles which increase the particle charge thereby improving the structure and response time of the mixture.

17. The display of claim 2 wherein the light absorbing particles are pigment and the non light absorbing particles comprise teflon, silica, alumina or mixtures thereof.