Compositions for golf equipment

• US 7,138,475 B2
• Filed: 06/02/2004
• Issued: 11/21/2006
• Est. Priority Date: 08/27/2002
• Status: Expired due to Term

• Current Assignee: Acushnet Company (FILA Holdings Corp.)
• Original Assignee: Acushnet Company (FILA Holdings Corp.)
• Inventors: Kuntimaddi, Manjari, Wu, Shenshen
• Primary Examiner(s): Buttner, David J.
• Application Number:
  US10/859,539
• Publication Number:
  US 20040220377A1
• Time in Patent Office: 902 Days
• Field of Search: None
• US Class Current: 528/61
• CPC Class Codes: A63B 37/0003 Golf balls
• CPC Class Codes: A63B 37/0024 Materials other than ionomers or polyurethane
• CPC Class Codes: A63B 37/0031 Hardness
• CPC Class Codes: A63B 37/0033 Thickness
• CPC Class Codes: A63B 37/0039 characterised by the material
• CPC Class Codes: A63B 37/0045 Thickness
• CPC Class Codes: A63B 37/0052 Liquid cores
• CPC Class Codes: A63B 37/0053 Thread wound
• CPC Class Codes: A63B 37/0056 Hollow; Gas-filled
• CPC Class Codes: A63B 37/12 Special coverings , i.e. outer layer material balls with finger holes A63B37/0001, golf ball covers A63B37/0023

Abstract

Golf balls comprising thermoplastic, thermoset, castable, or millable elastomer compositions are presently disclosed. These elastomer compositions comprise at least one amine-terminated polyamide and at least one isocyanate-containing prepolymer. These elastomer compositions can be used in any one or more portions of the golf balls, such as inner center, core, inner core layer, intermediate core layer, outer core layer, intermediate layer, cover, inner cover layer, intermediate cover layer, and/or outer cover layer.

Claims

1. A golf ball comprising at least one thermoplastic, thermoset, castable, or millable material formed from a composition comprising at least one amine-terminated polyamide and at least one isocyanate-containing prepolymer, wherein the amine-terminated polyamide is used to cure the prepolymer.

2. The golf ball of claim 1, wherein the amine-terminated polyamide has a general structure of:

3. The golf ball of claim 1, wherein the amine-terminated polyamide is a reaction product of at least one polyacid and at least one polyamine.

4. The golf ball of claim 3, wherein the polyacid is chosen from linear or branched aliphatic dicarboxylic acids having 2–

44 carbon atoms, alkane dicarboxylic acids having 6–

22 carbon atoms, cyclic or cycloaliphatic dicarboxylic acids having 6–

44 carbon atoms, aromatic dicarboxylic acids having about 8–

44 carbon atoms, triacids, tetracids, acid anhydrides, acid dianhydrides, acid chlorides, and acid esters.

5. The golf ball of claim 3, wherein the polyacid is chosen from maleic acid, fumaric acid, itaconic acid, citraconic acid, mesaconic acid, oxalic acid, malonic acid, glyceric acid, dimethyl malonic acid, succinic acid, methylsuccinic acid, diglycolic acid, glutaric acid, 3-methylglutaric acid, 2,2- and 3,3-dimethylglutaric acid, adipic acid, 2,2,4- and 2,4,4-trimethyladipic acid, pimelic acid, suberie acid, azelaic acid, sebacic acid, undecanedioic acid, dodecanedioic acid, brassylic acid, tetradecanedioic acid, pentadecanedioic acid, heptadecanedioic acid, heptadecanedioic acid, octadecanedioic acid, heptadecanedicarboxylic acid, octadecanedicarboxylic acid, 9(10)-carboxyoctadecanoic acid, nonadecanedicarboxylic acid, eicosanedicarboxylic acid, 1,1-cyclopropanedicarboxylic acid, 1,3-cyclopentanedicarboxylic acid, 1,2- and 1,4-cyclohexanedicarboxylic acid, 4,4′

-dicaboxydicyclohexylmethane, 3,3′

-dimethyl-4,4′

-dicarboxydicyclohexane, 4,4′

-dicarboxydicyclohexylpropane, 1,4-bis(carboxymethyl)cyclohexane, 2,3-, 2,5-, and 2,6-norbornanedicarboxylic acid, tetrahydrophthalic acid, hexahydrophthalic acid, hexahydroterephthalic acid, hexahydroisophthalic acid, hexahydronaphthalic acid, phthalic acid, isophthalic acid, tributylisophthalic acid, terephthalic acid, nitrophthalic acid, 5-methylisophtalic acid, 2-methylterephtalic acid, 2-chloroterephtalic acid, naphthalic acid, diphenic acid, 4,4′

-diphenyldicarboxylic acid, 4,4′

-oxydibenzoic acid, and 1,3-phenylenedioxy diacetic acid;

tricarboxylic acids, tetracarboxylic acids, mellitic acid, maleic anhydride, itaconic anhydride, citraconic anhydride, phthalic anhydride, pyromellitic dianhydride, naphthalene-1,4,5,8-tetracarboxylic dianhydride, and 3,3,4,4-biphenyltetracarboxylic dianhydride.

6. The golf ball of claim 3, wherein the polyamine is chosen from aromatic polyamines, araliphatic polyamines, aliphatic polyamines, alicyclic polyamines, heterocyclic polyamines, saturated polyamines, triamines, tetramines, and higher polyamines.

7. The golf ball of claim 3, wherein the polyacid comprises at least two carboxylic acid groups separated by a C₆ or longer chain, and the polyamine comprises at least two amine groups separated by a C₆ or longer chain.

8. The golf ball of claim 7, wherein at least one of the chains comprise at least one pendant linear or branched alkyl moieties.

9. The golf ball of claim 7, wherein the polyamine is chosen from hexamethylene diamine, 2,2,4- and 2,4,4-trimethyl-1,6-hexane diamine, N,N-bis(aminopropyl)hexylamine, N,N-bis(aminopropyl)octylamine, and fatty polyamines.

10. The golf ball of claim 1, wherein the amine-terminated polyamide has a general structure of:

11. The golf ball of claim 10, wherein the amine-terminated polyamide is a reaction product of at least one polyamine or polyol and at least one cyclic amide or amino acid.

12. The golf ball of claim 11, wherein the polyamine or polyol is chosen from aromatic polyamines, araliphatic polyamines, aliphatic polyamines, alicyclic polyamines, heterocyclic polyamines, saturated polyamines, diamines, triamines, tetramines, higher polyamines, aromatic polyols, araliphatic polyols, aliphatic polyols, alicyclic polyols, saturated polyols, diols, triols, tetraols, and higher polyols.

13. The golf ball of claim 11, wherein the cyclic amide or amino acid is chosen from propiolactam, N-methyl-β

-propiolactam, N-phenyl-β

-propiolactam, butyrolactam, N-methyl-2-pyrrolidone, N-vinyl-2-pyrrolidone, N-phenyl-2-pyrrolidone, N-t-butyl-2-pyrrolidone, N-methyl-5-methyl-2-pyrrolidone, valerolactam, N-methyl-2-piperidone, N-carbethoxy-2-piperidone, 4-chloro-N-methyl-2-piperidine, 4-hydroxy-N-methyl-2-piperidine, N-vinyl-2-piperidone, N-phenyl-2-piperidone, N-acetyl-2-piperidone, N-t-butyl-2-piperidone, dimethyl-2-piperidone, caprolactam, N-methyl-ε

-caprolactam, N-phenyl-ε

-caprolactam, enantholactam, caprylolactam, undecanolactam, laurolactam, N-methyl-ω

-laurolactam, N-vinyl-ω

-laurolactam, halogenated derivatives thereof, and mixtures thereof.

14. The golf ball of claim 1, wherein the amine-terminated polyamide is polyamine polycaprolactam having a generic structure of:

15. The golf ball of claim 1, wherein the amine-terminated polyamide has a weight average molecular weight of 200–

5,000.

16. The golf ball of claim 1, wherein the material at least in part forms at least one portion of the golf ball chosen from inner center, core, inner core layer, intermediate core layer, outer core layer, intermediate layer, cover, inner cover layer, intermediate cover layer, outer cover layer, discontinuous layer, wound layer, foamed layer lattice network layer, web or net, adhesion or coupling layer, barrier layer, layer of uniformed or non-uniformed thickness, layer having a plurality of discrete elements, and layer filled with liquid, gel, powder, and/or gas.

17. A golf ball comprising a cure and a cover, wherein the cover is formed from a composition comprising an isocyanate-containing prepolymer and an amine-terminated polyamide curative.

18. The golf ball of claim 17, wherein the cover has a thickness of 0.125 inches or less and a Shore D hardness of from 20 to 80.