Containers and methods for containing pressurized fluids using reinforced fibers and methods for making such containers

• US 7,147,124 B2
• Filed: 03/25/2003
• Issued: 12/12/2006
• Est. Priority Date: 03/27/2002
• Status: Expired due to Fees

• Current Assignee: Exxonmobil Upstream Research Company (Exxon Mobil Corporation)
• Original Assignee: Exxonmobil Upstream Research Company (Exxon Mobil Corporation)
• Inventors: Minta, Moses, Bowen, Ronald R.
• Primary Examiner(s): Elkins, Gary E.
• Application Number:
  US10/396,895
• Publication Number:
  US 20030183638A1
• Time in Patent Office: 1,358 Days
• Field of Search: 220586-590, 220/581, 220/560.04, 220/560.07, 220/560.08, 220/560.09, 62 451- 543, 114/74.A, 114/74.R
• US Class Current: 220/560.07
• CPC Class Codes: F17C 1/002 Storage in barges or on ships
• CPC Class Codes: F17C 2201/0109 with exteriorly curved end-piece
• CPC Class Codes: F17C 2201/0123 with variable thickness or diameter
• CPC Class Codes: F17C 2201/0128 spherical or elliptical
• CPC Class Codes: F17C 2201/035 with substantially horizontal main axis
• CPC Class Codes: F17C 2201/052 large (>1000 m3)
• CPC Class Codes: F17C 2201/054 medium (>1 m3)
• CPC Class Codes: F17C 2203/0604 Liners
• CPC Class Codes: F17C 2203/0607 Coatings
• CPC Class Codes: F17C 2203/0619 with two layers
• CPC Class Codes: F17C 2203/0621 with three layers
• CPC Class Codes: F17C 2203/0639 Steels
• CPC Class Codes: F17C 2203/0646 Aluminium
• CPC Class Codes: F17C 2203/0648 Alloys or compositions of metals
• CPC Class Codes: F17C 2203/0651 Invar
• CPC Class Codes: F17C 2203/066 Plastics
• CPC Class Codes: F17C 2203/0663 in form of fibers or filaments
• CPC Class Codes: F17C 2203/0673 Polymers
• CPC Class Codes: F17C 2205/018 Supporting feet
• CPC Class Codes: F17C 2205/0305 Bosses, e.g. boss collars
• CPC Class Codes: F17C 2209/221 : Welding
• CPC Class Codes: F17C 2209/232 : of walls
• CPC Class Codes: F17C 2221/033 : Methane, e.g. natural gas, CNG, LNG, GNL, GNC, PLNG
• CPC Class Codes: F17C 2223/0161 : cryogenic, e.g. LNG, GNL, PLNG
• CPC Class Codes: F17C 2223/033 : Small pressure, e.g. for liquefied gas
• CPC Class Codes: F17C 2223/035 : High pressure (>10 bar)
• CPC Class Codes: F17C 2260/012 : Reducing weight
• CPC Class Codes: F17C 2260/013 : Reducing manufacturing time or effort
• CPC Class Codes: F17C 2270/0105 : Ships
• CPC Class Codes: Y02E 60/32 : Hydrogen storage

Abstract

Containers suitable for storing pressurized fluids at cryogenic temperatures of −62° C. (−80° F.) and colder are provided and comprise a self-supporting liner and load-bearing composite overwrap, whereby means are provided for substantially preventing failure of the container during temperature changes.

Claims

1. A container suitable for storing a pressurized fluid at a pressure of about 1035 kPa (150 psia) to about 7590 kPa (1100 psia) and at a temperature of about −

123°

C. (−

190°

F.) to about −

62°

C. (−

80°

F.), said container comprising;

(a) a self-supporting liner, said self-supporting liner providing a substantially impermeable barrier to said pressurized fluid; and

(b) a load-bearing vessel in contact with said self-supporting liner, said load-bearing vessel having been made from composite materials and being suitable for withstanding pressures of about 1035 kPa (150 psia) to about 7590 kPa (1100 psia) and temperatures of about −

123°

C. (−

190°

F.) to about −

62°

C. (−

80°

F.), and said composite materials having a coefficient of thermal expansion (i) that is substantially the same as the coefficient of thermal expansion of said self-supporting liner at the interface with said self-supporting liner, and (ii) that gradually decreases through the thickness of said load-bearing vessel as the distance from said interface increases.

2. A container according to claim 1 wherein said load-bearing vessel has an outermost overwrap layer consisting essentially of carbon fibers or of a material that provides similar creep performance as carbon fibers would provide.

3. A container according to claim 1 wherein said composite materials comprise an intermediate material at the interface with said self-supporting liner, wherein said intermediate material has adequate shear strength or strain to substantially prevent failure of said container during changes in temperature between ambient and about −

123°

C. (−

190°

F.).

4. A container according to claim 1 wherein said self-supporting liner is made of a material consisting essentially of aluminum and said composite materials comprising fibers selected from the group consisting of (i) carbon, (ii) glass, (iii) aramid, and (iv) Ultra-High Molecular Weight Polyethylene.

5. A container according to claim 1 wherein said self-supporting liner is made of a material consisting essentially of a steel having a yield strength of at least about 690 MPa (100 ksi) and a ductile to brittle transition temperature lower than about −

62°

C. (−

80°

F.) in the base material and in its heat-affected-zone after welding and said composite materials comprising fibers selected from the group consisting of (i) carbon, (ii) glass, (iii) aramid, and (iv) Ultra-High Molecular Weight Polyethylene.

6. A container for storing a pressurized fluid comprising:

a self-supporting liner that provides a substantially impermeable barrier to a pressurized fluid; and

composite material disposed adjacent to the self-supporting liner and having a coefficient of thermal expansion that is about the same as the coefficient of thermal expansion of the self-supporting liner at the interface with the self-supporting liner, and wherein the coefficient of thermal expansion gradually decreases as the distance from the interface increases in the composite material.

7. The container of claim 6 comprising an overwrap layer, the overwrap layer having one of carbon fibers, a material that provides similar creep performance as carbon fibers, and any combination thereof.

8. The container of claim 6 wherein the composite material comprising an intermediate material at the interface with the self-supporting liner, wherein the intermediate material is configured to provide shear strength that prevents failure of the composite material in a temperature range from ambient to about −

123°

C. (−

190°

F.).

9. The container of claim 6 wherein the self-supporting liner comprises aluminum.

10. The container of claim 6 wherein the self-supporting liner comprises steel having a yield strength of at least about 690 MPa (100 ksi) and a ductile to brittle transition temperature lower than about −

62°

C. (−

80°

F.).

11. The container of claim 6 wherein the pressurized fluid comprises pressurized liquefied natural gas.

12. The container of claim 11 wherein the self-supporting liner and composite material are configured to handle pressures of about 1035 kPa (150 psia) to about 7590 kPa (1100 psia).

13. The container of claim 11 wherein the self-supporting liner and composite material are configured to handle temperatures of about −

123°

C. (−

190°

F.) to about −

62°

C. (−

80°

F.).

14. The container of claim 6 wherein the composite material comprises fibers from at least one of carbon, glass, aramid, Ultra-High Molecular Weight Polyethylene, and any combination thereof.

15. A system for storing a pressurized fluid comprising:

a transportation vessel;

at least one container associated with the transportation vessel, the at least one container comprising;

a self-supporting liner that provides a substantially impermeable barrier to a pressurized fluid; and

composite material disposed adjacent to the self-supporting liner and having a coefficient of thermal expansion that is about the same as the coefficient of thermal expansion of the self-supporting liner at the interface with the self-supporting liner, and wherein the coefficient of thermal expansion gradually decreases as the distance from the interface increases in the composite material.

16. The system of claim 15 wherein the at least one container is disposed within the transportation vessel by a two point support system.

17. The system of claim 15 wherein the at least one container comprises a nozzle to allow access to the container for storing pressurized liquefied natural gas.