Ultraviolet and visible-light-sensitive titania-based photocatalyst

• US 7,153,808 B2
• Filed: 03/24/2005
• Issued: 12/26/2006
• Est. Priority Date: 07/07/2004
• Status: Expired due to Fees

• Current Assignee: Kyoto University
• Original Assignee: Kyoto University
• Inventors: Inoue, Masashi, Ozaki, Hirotaka, Iwamoto, Shinji
• Primary Examiner(s): Lorengo, J. A.
• Assistant Examiner(s): Hailey, Patricia L.
• Application Number:
  US11/087,175
• Publication Number:
  US 20060009351A1
• Time in Patent Office: 642 Days
• Field of Search: 502/200, 502/242, 502/350
• US Class Current: 502/200
• CPC Class Codes: B01J 21/063 Titanium; Oxides or hydroxides thereof
• CPC Class Codes: B01J 27/24 Nitrogen compounds
• CPC Class Codes: B01J 35/39 Photocatalytic properties
• CPC Class Codes: B01J 35/613 10-100 m2/g
• CPC Class Codes: B01J 35/615 100-500 m2/g
• CPC Class Codes: B01J 37/033 Using Hydrolysis

Abstract

The present invention provides photocatalysts showing excellent sensitivity not only in ultraviolet light region but also in visible light region. The ultraviolet and visible light-sensitive titania-based photocatalysts according to the present invention are characterized by their composition as expressed by a general formula: TiSi_xN_yO_2+2x−y (where 0.01<x<1 and 0.003<y<0.3). The invented photocatalysts have optical properties that the relative absorbance at 450 nm to that of 300 nm is not lower than 0.1 and the relative absorbance at 600 nm to that of 300 nm is not higher than 0.1.

Claims

1. An ultraviolet and visible-light-sensitive titania-based photocatalyst, which is expressed by a general formula:

TiSi_xN_yO<sub>2+2x−

y</sub> (where 0.01<

x<

1 and 0.003<

y<

0.3), has a relative absorbance at 450 nm compared with that of 300 nm not lower than 0.1, and has a relative absorbance at 600 nm compared with that of 300 nm not higher than 0.1.

2. An ultraviolet and visible-light sensitive titania-based photocatalyst according to claim 1 which has a relative absorbance at 450 nm compared with that of 300 nm not lower than 0.2, and has a relative absorbance at 600 nm compared with that of 300 nm not higher than 0.05.

3. An ultraviolet and visible-light-sensitive titania-based photocatalyst according to claim 1 which has following composition as expressed in a general formula:

TiSi_xN_yO<sub>2+2x−

y</sub>, 0.03≦

x≦

0.3 and 0.005≦

y≦

0.03.

4. A preparation method of an ultraviolet and visible-light-sensitive titania-based photocatalyst, whose preparation method is characterized in that silica-modified titanias, in which Si atoms are incorporated in the crystal structure of titania, are heated in ammonia atmosphere preferably at a temperature ranging from 450 to 700°

C., and then heated in an oxidative atmosphere preferably at a temperature ranging from 300 to 600°

C.