Process for producing oxime

• US 7,161,036 B2
• Filed: 12/20/2004
• Issued: 01/09/2007
• Est. Priority Date: 12/22/2003
• Status: Expired due to Fees

• Current Assignee: Sumitomo Chemical Company Limited
• Original Assignee: Sumitomo Chemical Company Limited
• Inventors: Oikawa, Miyuki, Fukao, Masami
• Primary Examiner(s): Page; Thorman K.
• Assistant Examiner(s): Nwaonicha; Chukwuma
• Application Number:
  US11/014,812
• Publication Number:
  US 20050137423A1
• Time in Patent Office: 750 Days
• Field of Search: 564/267
• US Class Current: 564/253
• CPC Class Codes: C07C 249/04 of oximes
• CPC Class Codes: C07C 251/44 with the carbon atom of at least one of the oxyimino groups being part of a ring other than a six-membered aromatic ring

Abstract

A process for producing an oxime is provided, wherein the process comprises the step of reacting a ketone, hydrogen peroxide and ammonia in the presence of a crystalline titanosilicate having MWW structure under the condition that the ammonia concentration in the liquid portion of the reaction mixture is about 1% by weight or more. By the process, an ammoximation reaction of the ketone can be carried out with a high conversion of the ketone and a high selectivity to the oxime corresponding to the ketone, thereby producing the oxime with a high yield.

Claims

1. A process for producing an oxime, the process comprising the step of reacting a ketone, hydrogen peroxide and ammonia in the presence of a crystalline titanosilicate having a MWW structure, under the reaction condition that ammonia concentration in a liquid portion of the reaction mixture is about 1% by weight or more.

2. A process according to claim 1, wherein the reaction is carried out while supplying the ketone, hydrogen peroxide and ammonia to the reaction system while removing the liquid portion of the reaction mixture out of the reaction system.

3. A process according to claim 1 or 2, wherein the reaction is carried out using a solvent.

4. A process according to claim 3, wherein the solvent is a mixture of an alcohol and water.

5. A process according to claim 1 or 2, wherein the reaction is conducted under pressurized conditions by a pressure in the range of from 0.2 MPa to about 1 MPa in terms of an absolute pressure.

6. A process according to claim 1 or 2, wherein the ketone comprises a cycloalkanone.