System and method of producing Bisphenol-A (BPA) using direct crystallization of BPA in a single crystallization stage

• US 7,163,582 B2
• Filed: 09/12/2003
• Issued: 01/16/2007
• Est. Priority Date: 03/13/2002
• Status: Expired due to Fees

• Current Assignee: Mitsubishi Chemical Corporation (Mitsubishi Chemical Group Corp.)
• Original Assignee: Mitsubishi Chemical Corporation (Mitsubishi Chemical Group Corp.)
• Inventors: O'Young, Drow Lionel, Kelkar, Vaibhav, Hsieh, Shan Tao
• Primary Examiner(s): KUNEMUND, ROBERT M
• Application Number:
  US10/661,169
• Publication Number:
  US 20040204616A1
• Time in Patent Office: 1,222 Days
• Field of Search: 422/245.1, 422/250, 117/68, 117/69
• US Class Current: 117/68
• CPC Class Codes: C07C 37/20 using aldehydes or ketones
• CPC Class Codes: C07C 37/84 by crystallisation
• CPC Class Codes: C07C 39/16 Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes

Abstract

A system and method are provided for producing Bisphenol-A (BPA) using direct crystallization of BPA in a single crystallization stage. In one embodiment the method comprises reacting Phenol and Acetone in the presence of a catalyst to form a product solution including Bisphenol-A and Phenol; removing a part of the Phenol from the product solution if required, and providing a selective amount of solvent, so as to obtain a product solution with the desired phase equilibrium behavior; and feeding the product solution with a selective composition to a crystallization stage operated at a selected temperature, so as to recover substantially pure Bisphenol-A in crystal form.

Claims

1. A system for producing Bisphenol-A, comprising:

a reactor unit wherein a product stream is produced including at least Bisphenol-A and Phenol;

a mixer/separator unit, said mixer/separator unit being configured to selectively add solvent to the product stream wherein the composition of the product stream exhibits a phase equilibrium relationship such that Bisphenol-A crystals are formed during crystallization; and

a BPA crystallizer stage, the crystallizer stage receiving the product stream and wherein substantially pure Bisphenol-A crystals are produced directly upon crystallization in the BPA crystallizer stage, without prior adduct crystallization.

2. The system of claim 1 wherein the mixer/separator unit is located upstream of the BPA stage crystallizer.

3. The system of claim 1 further comprising:

a solvent recovery unit configured to recover solvent used in the system, the solvent recovery unit being coupled to at least any one, or more of, the reactor unit, mixer/separator or partial phenol removal unit to selectively adjust the composition of the product stream.

4. The system of claim 1 further comprising a partial phenol removal unit configured to adjust the composition of phenol in the product stream such that the product stream when fed to the BPA crystallizer stage does not contain more than 40 wt. % phenol.

5. The system of claim 1 where the BPA crystallizer stage is comprised of one or more crystallizer units.

6. A system for producing Bisphenol-A, comprising:

a reactor unit wherein a product stream is produced including at least Bisphenol-A and Phenol;

a partial phenol removal unit;

a mixer/separator unit, the mixer/separator unit receiving the product stream from the reactor unit or the partial phenol removal unit and being configured to selectively adjust the composition of the product stream by mixing with one or more recycle streams; and

a BPA crystallizer stage, the crystallizer stage receiving the product stream from the mixer/separator unit and whereupon crystallization substantially pure Bisphenol-A crystals are produced directly upon crystallization in the BPA crystallizer stage, without prior adduct crystallization.

7. The system of claim 6 further comprising a solvent recovery unit, wherein both of said partial phenol removal unit and said solvent recovery unit produce recycle streams, and where one or more of the recycle streams are conveyed to the mixer/separator.

8. The system of claim 6 further comprising one or more processing units downstream of the BPA crystallizer stage, and wherein the one or more processing units produce recycle streams, and where one or more of the recycle streams are conveyed to the mixer/separator.

9. The system of claim 6 further comprising a solvent recovery unit, the solvent recovery unit recovering solvent used in the system and being coupled to at least one, or more of, the partial phenol removal unit or the mixer/separator to selectively adjust the composition of the product stream.

10. The system of claim 6 wherein the partial phenol removal unit is configured to adjust the composition of phenol in the product stream such that the product stream when fed to the BPA crystallizer stage does not contain more than 40 wt. % phenol.

11. A system for producing Bisphenol-A, comprising:

a reactor unit wherein a product stream is produced including at least Bisphenol-A and Phenol;

a partial phenol removal unit;

a mixer/separator unit, the mixer/separator unit receiving the product stream from the reactor unit or the partial phenol removal unit and being configured to selectively adjust the composition of the product stream by mixing with one or more recycle streams;

a solvent recovery unit, the solvent recovery unit recovering solvent used in the system and being coupled to at least one, or more of, the partial phenol removal unit or the mixer/separator to selectively adjust the composition of the product stream; and

a BPA crystallizer stage, the crystallizer stage receiving the product stream and whereupon crystallization substantially pure Bisphenol-A crystals are produced directly upon crystallization in the BPA crystallizer stage, without prior adduct crystallization.