Nanoscale catalyst particles/aluminosilicate to reduce carbon monoxide in the mainstream smoke of a cigarette

• US 7,165,553 B2
• Filed: 06/13/2003
• Issued: 01/23/2007
• Est. Priority Date: 06/13/2003
• Status: Active Grant

• Current Assignee: Philip Morris USA Incorporated (Altria Group, Inc.)
• Original Assignee: Philip Morris USA Incorporated (Altria Group, Inc.)
• Inventors: Koller, Kent B., Deevi, Sarojini, Luan, Zhaohua, Gee, Diane L., Fournier, Jay A, Skinner, Ila
• Primary Examiner(s): MAYES, DIONNE WALLS
• Application Number:
  US10/460,632
• Publication Number:
  US 20040250828A1
• Time in Patent Office: 1,320 Days
• Field of Search: 131/364, 131/334, 131/360, 131/365, 162/139, 162/158, 162/164.2, 162/164.4
• US Class Current: 131/334
• CPC Class Codes: A24B 15/28 by chemical substances
• CPC Class Codes: A24B 15/282 by indirect addition of the chemical substances, e.g. in the wrapper, in the case
• CPC Class Codes: A24B 15/286 Nanoparticles
• CPC Class Codes: A24B 15/287 by inorganic substances only
• CPC Class Codes: A24D 3/16 of inorganic materials
• CPC Class Codes: A24D 3/166 Silicic acid or silicates

Abstract

A smoking article composition and a method of making a smoking article composition comprising tobacco cut filler, cigarette paper and/or cigarette filter material further comprising a catalyst capable of converting carbon monoxide to carbon dioxide, wherein the catalyst comprises nanoscale catalyst particles dispersed within a porous aluminosilicate matrix. The catalyst can be formed by combining nanoscale catalyst particles or a metal precursor solution thereof with an alumina-silica sol mixture to form a slurry, gelling the slurry to form the co-gel, heating the co-gel to form a catalyst comprising nanoscale catalyst particles dispersed within a porous aluminosilicate matrix. The catalyst can be incorporated in tobacco cut filler, cigarette paper and/or cigarette filter material by spraying, dusting and/or immersion.

Claims

1. A smoking article composition comprising tobacco cut filler, cigarette paper and/or cigarette filter material further comprising a catalyst capable of converting carbon monoxide to carbon dioxide, wherein the catalyst comprises nanoscale catalyst particles dispersed within a porous aluminosilicate matrix, and

wherein the nanoscale catalyst particles comprise iron oxide, and/or iron oxide hydroxide, and/or

wherein the matrix further comprises magnesia, titania, yttria, ceria or mixtures thereof.

2. The smoking article composition of claim 1, wherein the nanoscale catalyst particles are:

bound to the porous aluminosilicate matrix by forming the aluminosilicate matrix around the nanoscale catalyst particles, and/or

blended and uniformly cast into an aluminosilicate matrix.

3. The smoking article composition of claim 1, wherein the nanoscale catalyst particles comprise a Group IIIB element, a Group IVB element, a Group IVA element, a Group VA element, a Group VIA element, a Group VIIA element, a Group VIIIA element a Group IB element, magnesium, zinc, yttrium, a rare earth metal, and mixtures thereof.

4. The smoking article composition of claim 1, wherein the nanoscale catalyst particles comprise iron oxide.

5. The smoking article composition of claim 1, wherein the nanoscale catalyst particles comprise iron oxide hydroxide.

6. The smoking article composition of claim 1, wherein the nanoscale catalyst particles are carbon free.

7. The smoking article composition of claim 1, wherein the nanoscale catalyst particles have an average particle size less than about 50 nm.

8. The smoking article composition of claim 1, wherein the nanoscale catalyst particles have an average particle size less than about 10 nm.

9. The smoking article composition of claim 1, wherein the nanoscale catalyst particles have a crystalline structure.

10. The smoking article composition of claim 1, wherein the nanoscale catalyst particles have an amorphous structure.

11. The smoking article composition of claim 1, wherein the matrix further comprises magnesia, titania, yttria, ceria or mixtures thereof.

12. The smoking article composition of claim 1, wherein the matrix structure is crystalline.

13. The smoking article composition of claim 1, wherein the matrix has an amorphous structure.

14. The smoking article composition of claim 1, wherein the matrix has an average pore size of between about 1 nanometer and 100 nanometers.

15. The smoking article composition of claim 1, wherein the matrix has an average surface area of from about 20 to 2500 m²/g.

16. The smoking article composition of claim 1, wherein the catalyst comprises from about 1 to 50 wt. % iron oxide particles.

17. The smoking article composition of claim 1, wherein the catalyst is added in an amount effective to reduce the ratio of carbon monoxide to total particulate matter in mainstream smoke by at least 25%.

18. The smoking article composition of claim 1, wherein the catalyst is capable of acting as an oxidant for the conversion of carbon monoxide to carbon dioxide.

19. A cigarette comprising the smoking article composition of claim 1.

48. A method of smoking the cigarette of claim 19, comprising lighting the cigarette to form tobacco smoke and drawing the tobacco smoke through the cigarette, wherein during the smoking of the cigarette the catalyst reduces the amount of carbon monoxide in the tobacco smoke.

20. A method of making a smoking article composition comprising tobacco cut filler, cigarette paper and/or cigarette filter material further comprising a catalyst, comprising the steps of:

combining nanoscale catalyst particles or a metal precursor solution thereof with an alumina-silica sol mixture to form a slurry,

gelling the slurry to form a co-gel,

heating the co-gel to form a catalyst comprising nanoscale catalyst particles dispersed within a porous aluminosilicate matrix; and

incorporating the catalyst in tobacco cut filler, cigarette paper and/or cigarette filter material.

21. The method of claim 20, wherein nanoscale catalyst particles comprising a metal and/or a metal oxide are combined with the alumina-silica sol mixture.

22. The method of claim 20, wherein nanoscale catalyst particles comprising a Group IIIB element, a Group IVB element, a Group IVA element, a Group VA element, a Group VIA element, a Group VIIA element, a Group VIIIA element, a Group IB element, magnesium, zinc, yttrium, a rare earth metal, and mixtures thereof are combined with the alumina-silica sol mixture.

23. The method of claim 20, wherein nanoscale catalyst particles comprising iron oxide are combined with the alumina-silica sol mixture.

24. The method of claim 20, wherein nanoscale catalyst particles comprising iron oxide hydroxide are combined with the alumina-silica sol mixture.

25. The method of claim 20, wherein nanoscale catalyst particles having an average particle size less than about 50 nm are combined with the alumina-silica sol mixture.

26. The method of claim 20, wherein nanoscale catalyst particles having an average particle size less than about 10 nm are combined with the alumina-silica sol mixture.

27. The method of claim 20, wherein nanoscale catalyst particles having a crystalline structure are combined with the alumina-silica sol mixture.

28. The method of claim 20, wherein nanoscale catalyst particles having an amorphous structure are combined with the alumina-silica sol mixture.

29. The method of claim 20, wherein a metal precursor solution comprising a metal precursor selected from the group consisting of β

-diketonates, dionates, oxalates and hydroxides is combined with the alumina-silica sol mixture.

30. The method of claim 20, wherein a metal precursor solution comprising a Group IIIB element, a Group IVB element, a Group IVA element, a Group VA element, a Group VIA element, a Group VIIA element, a Group VIIIA element, a Group IB element, magnesium, zinc, yttrium, a rare earth metal, and mixtures thereof is combined with the alumina-silica sol mixture.

31. The method of claim 20, wherein the nanoscale particles or the metal precursor solution are combined with an alumina-silica sol mixture further comprising magnesia, titania, yttria and/or ceria.

32. The method of claim 20, wherein the nanoscale particles or the metal precursor solution are combined with an alumina-silica sol mixture comprising an aluminum source selected from the group consisting of aluminum nitrate, aluminum chloride and aluminum sulfate and a silicon source selected from the group consisting of silica hydrogels, silica sols, colloidal silica, fumed silica, silicic acid and silanes.

33. The method of claim 20, wherein the step of forming the slurry and gelling the slurry are performed simultaneously.

34. The method of claim 20, wherein the step of gelling the slurry is conducted at a pH of at least about 7.

35. The method of claim 20, wherein the step of gelling the slurry is conducted by adding a ammonium hydroxide to the slurry to bring the pH in a range of from between about 8 to 11.

36. The method of claim 20, wherein the step of gelling the slurry is conducted at a temperature of less than about 100°

C.

37. The method of claim 20, wherein the step of heating is conducted at a temperature in a range of from about 200°

C. to 500°

C.

38. The method of claim 20, wherein the step of heating comprises heating the co-gel at a temperature sufficient to thermally decompose the metal precursor to form nanoscale catalyst particles.

39. The method of claim 20, further comprising the step of calcining the catalyst powder at a temperature in a range of from about 425 to 750°

C.

40. The method of claim 20, wherein the step of incorporating comprises spray coating, dusting and immersion.

41. The method of claim 20, wherein the co-gel is heated at a temperature sufficient to form nanoscale catalyst particles and/or an aluminosilicate matrix having a crystalline structure.

42. The method of claim 20, wherein the co-gel is heated at a temperature sufficient to form carbon-free nanoscale catalyst particles.

43. The method of claim 20, wherein the co-gel is heated at a temperature sufficient to form nanoscale catalyst particles and/or an aluminosilicate matrix having an amorphous structure.

44. The method of claim 20, wherein a slurry comprising from about 1 to 50 wt. % iron oxide nanoscale catalyst particles is gelled to form the co-gel.

45. The method of claim 20, wherein the catalyst is added to the smoking article composition in an amount effective to reduce the ratio of carbon monoxide to total particulate matter in mainstream smoke by at least 25%.

46. The method of claim 20, wherein the catalyst is added to the smoking article composition in an amount effective to catalyze and/or oxidize the conversion of carbon monoxide to carbon dioxide.

47. A method of making a cigarette comprising the steps of:

supplying tobacco cut filler to a cigarette making machine to form a tobacco column; and

placing cigarette paper around the tobacco column to form a tobacco rod of the cigarette, wherein at least one of the tobacco cut filler and cigarette paper wrapper are made according to the method of claim 20.