Energy efficient wastewater treatment for nitrogen and phosphorus removal

• US 7,172,699 B1
• Filed: 10/13/2004
• Issued: 02/06/2007
• Est. Priority Date: 10/13/2004
• Status: Active Grant

• Current Assignee: Ovivo Inc. (Susanne Klatten, MBA)
• Original Assignee: Eimco Water Technologies, LLC
• Inventors: Porteous, James, Trivedi, Hiren K.
• Primary Examiner(s): Prince; Fred G.
• Application Number:
  US10/909,104
• Time in Patent Office: 846 Days
• Field of Search: 210/605, 210/610, 210/620, 210/621, 210/623, 210/630, 210/903, 210/906, 210/252, 210/259
• US Class Current: 210/605
• CPC Class Codes: C02F 3/1268 Membrane bioreactor systems
• CPC Class Codes: C02F 3/302 Nitrification and denitrification treatment C02F3/308 takes precedence
• CPC Class Codes: C02F 3/308 Biological phosphorus removal
• CPC Class Codes: Y02W 10/10 Biological treatment of water, waste water, or sewage
• CPC Class Codes: Y10S 210/903 Nitrogenous
• CPC Class Codes: Y10S 210/906 Phosphorus containing

Abstract

In a wastewater treatment plant, the liquid side of the plant has preferably four stages for nitrification and/or denitrification, prior to further treatment such as a clarifier. Energy requirements are reduced by reducing aeration requirements. Four or more tanks/zones comprise serial anoxic and aerobic stages, but in the anoxic stages simultaneous nitrification/denitrification takes place in accordance with the known process of U.S. Pat. No. 5,906,746. By this arrangement the system can achieve a volume ratio of about 20% aerobic tankage to the total tankage volume, as compared to a much higher ratio in a typical prior art system of serial aerobic/anoxic stages, and greatly reducing aeration requirements.

Claims

1. In a liquid side of a sewage treatment system for treating wastewater, a biological nutrient removal (BNR) configuration of high efficiency with minimal aeration requirements, comprising:

at least four tanks or zones arranged for successive treatment of the wastewater, including simultaneous nitrification/denitrification, aerobic, anoxic and aerobic stages in sequence in the respective tanks or zones,

a first simultaneous nitrification/denitrification stage being maintained essentially at less than 1 ppm oxygen, and with the oxygen level adjusted to maintain simultaneous nitrification/denitrification, so that ammonia is broken down to produce nitrate, and nitrate is broken down to release nitrogen gas, within a single tank or zone and simultaneously,

a first aerobic stage being maintained essentially at greater than 1 ppm oxygen to promote nitrification,

an anoxic stage after the first aerobic stage, being maintained essentially at less than 1 ppm oxygen, and with the oxygen level adjusted to maintain an anoxic condition at least in part of the wastewater or part of the time, to break down nitrate to release nitrogen gas, and

a second aerobic stage being maintained essentially at greater than 1 ppm oxygen to promote nitrification.

2. The system of claim 1, the system being without recycle of sludge from any of the four stages back to any previous stage.

3. The system of claim 2, in combination with a clarifier stage downstream of the nitrification/denitrification stages, and including recycle of sludge from the clarifier stage back to the first simultaneous nitrification/denitrification stage.

4. The system of claim 2, wherein the anoxic stage includes simultaneous nitrification/denitrification, so that ammonia is broken down to produce nitrate, and nitrate is broken down to release nitrogen gas, within a single tank or zone and simultaneously.

5. The system of claim 2, wherein the four stages comprise portions of the total volume of the four stages as follows:

first stage, about 50% to 95%;

second stage, about 1% to 25%;

third stage, about 1% to 25%; and

fourth stage, about 1% to 25%.

6. The system of claim 1, wherein the four nitrification and/or denitrification stages are in four separate tanks, and wherein the ratio of total volume of the aerobic stage tanks to total volume of all stages is about 1:

5.

7. The system of claim 1, wherein the four stages are in four compartments or zones within a single tank, separated by either baffles or internal walls.

8. The system of claim 1, in combination with a membrane bioreactor positioned to remove clean water in lieu of a clarifier.

9. The system of claim 8, wherein the membrane bioreacter is incorporated in the second aerobic stage, and including recycle of sludge from the second aerobic stage back to the first simultaneous nitrification/denitrification stage.

10. The system of claim 1, wherein the simultaneous nitrification/denitrification stage includes means for releasing phosphorus in the wastewater by allowing an anaerobic condition to develop in the flocs to a pre-selected extent and thereby causing phosphorus to be released into the liquid, then adding dissolved oxygen to the aerobic/anoxic zone to effect recovery of at least some of the bacteria from the anaerobic condition and causing uptake of phosphorus, as well as effecting nitrification.

11. The system of claim 1, wherein the aerobic stages are maintained at greater than 2 ppm oxygen.

12. In a sewage treatment process, a method for high efficiency biological nutrient removal (BNR) for wastewater treatment, with minimal aeration requirements, comprising:

providing at least four tanks or zones arranged for successive treatment of the wastewater, including simultaneous nitrification/denitrification, aerobic, anoxic and aerobic stages in succession in the respective tanks or zones,

establishing a flow of wastewater through the stages in succession,

maintaining the first simultaneous nitrification/denitrification anoxic stage substantially at less than 1 ppm oxygen, and adjusting the oxygen level to maintain simultaneous nitrification/denitrification, so that ammonia is broken down to produce nitrate, and nitrate is broken down to release nitrogen gas, within a single tank or zone and simultaneously,

maintaining the first aerobic stage essentially at greater than 1 ppm oxygen to promote nitrification whereby ammonia is broken down to produce nitrate,

maintaining the anoxic stage substantially at less than 1 ppm oxygen, and adjusting the oxygen level to maintain an anoxic condition at least in part of the wastewater or part of the time, to break down nitrate to release nitrogen gas,

maintaining the second aerobic stage substantially at greater than 1 ppm oxygen to promote nitrification whereby ammonia is broken down to produce nitrate, and

performing the above steps without recycle of sludge from any of the stages back to any previous stage.

13. The method of claim 12, wherein the anoxic stage is maintained as a second simultaneous nitrification/denitrification stage, with the oxygen level being adjusted to maintain simultaneous nitrification/denitrification, so that ammonia is broken down to produce nitrate, and nitrate is broken down to release nitrogen gas, within a single tank or zone.

14. The method of claim 13, further including, in one of the simultaneous nitrification/denitrification stages, allowing an anaerobic condition to develop in flocs within the tank to a pre-selected extent and thereby causing phosphorus to be released into the wastewater, and then adding dissolved oxygen to the simultaneous nitrification/denitrification stage to effect recovery of at least some of the bacteria from the anaerobic condition and causing uptake of phosphorus, as well as effecting nitrification, whereby in an aerobic stage downstream of said one simultaneous nitrification/denitrification stage, biological phosphorus uptake is enhanced, and whereby denitrification as well as phosphorus removal are effected in the at least four tanks or zones.

15. The method of claim 12, further including, in the first simultaneous nitrification/denitrification stage, allowing an anaerobic condition to develop in flocs within the tank to a pre-selected extent and thereby causing phosphorus to be released into the wastewater, and then adding dissolved oxygen to the simultaneous nitrification/denitrification stage to effect recovery of at least some of the bacteria from the anaerobic condition and causing uptake of phosphorus, as well as effecting nitrification, whereby in an aerobic stage downstream of the simultaneous nitrification/denitrification stage, biological phosphorus uptake is enhanced, and whereby denitrification as well as phosphorus removal are effected in the at least four tanks or zones.

16. The method of claim 12, wherein the aerobic stages are maintained at greater than 2 ppm oxygen.

17. The method of claim 12, wherein the four tanks or zones for the four stages comprise portions of the total volume of the four stages as follows:

first stage, about 50% to 95%;

second stage, about 1% to 25%;

third stage, about 1% to 25%; and

fourth stage, about 1% to 25%.

18. The method of claim 12, further including removing liquid in a clarifier downstream of the second aerobic stage, and including recycle of sludge from the clarifier back to the first simultaneous nitrification/denitrification stage.

19. In a sewage treatment process, a method for high efficiency biological nutrient removal (BNR) for wastewater treatment, with minimal aeration requirements, comprising:

providing at least four tanks or zones arranged for successive treatment of the wastewater, including simultaneous nitrification/denitrification, aerobic, anoxic and aerobic stages in succession in the respective tanks or zones, establishing a flow of wastewater through the stages in succession,

maintaining the first simultaneous nitrification/denitrification anoxic stage substantially at less than 1 ppm oxygen, and adjusting the oxygen level to maintain simultaneous nitrification/denitrification, so that ammonia is broken down to produce nitrate, and nitrate is broken down to release nitrogen gas, within a single tank or zone and simultaneously,

maintaining the first aerobic stage essentially at greater than 1 ppm oxygen to promote nitrification whereby ammonia is broken down to produce nitrate,

maintaining the anoxic stage substantially at less than 1 ppm oxygen, and adjusting the oxygen level to maintain an anoxic condition at least in part of the wastewater or part of the time, to break down nitrate to release nitrogen gas,

maintaining the second aerobic stage substantially at greater than 1 ppm oxygen to promote nitrification whereby ammonia is broken down to produce nitrate, and removing clean water with a membrane bioreacter positioned at the end of the stages.

20. The method of claim 19, wherein the membrane bioreacter is incorporated in the second aerobic stage, and including recycling sludge from the second aerobic stage back to the first simultaneous nitrification/denitrification stage.