Golf balls containing interpenetrating polymer networks

• US 7,175,545 B2
• Filed: 12/18/2003
• Issued: 02/13/2007
• Est. Priority Date: 04/13/2001
• Status: Expired due to Term

• Current Assignee: Acushnet Company (FILA Holdings Corp.)
• Original Assignee: Acushnet Company (FILA Holdings Corp.)
• Inventors: Bulpett, David A., Kuntimaddi, Manjari
• Primary Examiner(s): Kim; Eugene
• Assistant Examiner(s): Hunter, Jr.; Alvin A.
• Application Number:
  US10/738,091
• Publication Number:
  US 20040132546A1
• Time in Patent Office: 1,153 Days
• Field of Search: 473351-378
• US Class Current: 473/378
• CPC Class Codes: A63B 37/0003 Golf balls
• CPC Class Codes: A63B 37/00221 characterised by the material
• CPC Class Codes: A63B 37/0024 Materials other than ionomers or polyurethane
• CPC Class Codes: A63B 37/003 Coefficient of restitution
• CPC Class Codes: A63B 37/0031 Hardness
• CPC Class Codes: A63B 37/0034 Deflection or compression
• CPC Class Codes: A63B 37/0037 Flexural modulus; Bending stiffness
• CPC Class Codes: A63B 37/0051 Materials other than polybutadienes; Constructional details
• CPC Class Codes: A63B 37/0074 Two piece balls, i.e. cover and core
• CPC Class Codes: A63B 37/0075 Three piece balls, i.e. cover, intermediate layer and core
• CPC Class Codes: A63B 37/0076 Multi-piece balls, i.e. having two or more intermediate layers
• CPC Class Codes: A63B 37/06 Elastic cores
• CPC Class Codes: C08G 18/10 Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
• CPC Class Codes: C08G 18/3206 aliphatic
• CPC Class Codes: C08G 2270/00 Compositions for creating interpenetrating networks
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/06 Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof
• CPC Class Codes: C08L 2666/22 Macromolecular compounds not provided for in C08L2666/16 - C08L2666/20
• CPC Class Codes: C08L 75/04 Polyurethanes

Abstract

The present invention is directed to a method of forming a golf ball that contains an interpenetrating polymer network, or IPN, which includes at least two polymeric components, in one or more of the layers. In one preferred embodiment, the present invention is directed to a method of forming an intermediate or cover layer that contains an IPN.

Claims

1. A method of forming a portion of a golf ball comprising the steps of:

providing at least a first polymeric component and a second polymeric component, each polymeric component comprising at least one monomer, oligomer, prepolymer, or a combination thereof;

sufficiently polymerizing each polymeric component sequentially or simultaneously to form a polymer or polymer network;

crosslinking each polymer or polymer network to the other polymer or polymer network to form an interpenetrating polymer network (“

IPN”

); and

forming the IPN into the portion of the golf ball,

wherein each polymeric component of the mixture is polymerized by exposing the mixture to at least one energy source, at least one initiator present in an amount from about 0.1 to about 10 parts per hundred of total polymer component, or a combination thereof for a time sufficient to polymerize the polymeric component.

2. The method of claim 1, wherein the at least one energy source is selected from the group consisting of microwave radiation, infrared radiation, visible radiation, ultraviolet radiation, x-ray radiation, gamma radiation, electron beam radiation and a combination thereof.

3. The method of claim 1, wherein the at least one initiator is selected from the group consisting of a thermal free radical initiator, a photoinitiator, a cationic initiator, and a mixture thereof.

4. The method of claim 3, wherein the thermal free radical initiator is selected from the group consisting of an azo compound, a peroxide, a persulfate, a redox initiator, and mixtures thereof.

5. The method of claim 3, wherein the photoinitiator is selected from the group consisting of a peroxide, an azo compound, quinine, benzophenone, nitroso compound, acyl halide, hydrazone, a mercapto compound, a pyrylium compound, a triacylimidazole, an organophosphorus compounds, a bisimidazole, a chioroalkyltriazine, a benzoate, a benzoyl compound, a benzoin ether, a benzil ketal, a thioxanthone, an acetophenone derivative, a ketone, a metallocene, a hexafluorophosphate salt, a sulfonium salt, a diacrylate, a polyoi, a pyrollidone, and mixtures thereof.

6. The method of claim 3, wherein the cationic initiator is selected from the group consisting of a Group IA organo compound, Group IIA organo compound, aryl sulfonium salt, hexafluorometallic salt, Bronsted acid, Lewis acid, and mixtures thereof.

7. The method of claim 1, wherein the initiator is present in an amount from about 0.01 to about 15 parts per hundred of total polymer component.

8. The method of claim 1, wherein the initiator is present in an amount from about 0.1 to about 10 parts per hundred of total polymer component.

9. The method of claim 1, wherein the polymerization of each polymeric component is subsequent or simultaneous with the crosslinking of each polymer or polymer network to the other polymer or polymer network.

10. The method of claim 1, wherein the first polymeric component is polymerized in the presence or absence of a second polymeric component to form a first polymer or first polymer network.

11. The method of claim 10, wherein the at least a second polymeric component is polymerized in the presence of the first polymeric component or the first polymer or first polymer network to form a second polymer or second polymer network.

12. The method of claim 11, wherein crosslinking of the first polymer or first polymer network to the second polymer or second polymer network occurs subsequently or simultaneously with the polymerization of the second polymeric component to form the second polymer or second polymer network.

13. The method of claim 1, wherein the polymerization of each polymeric component and the crosslinking of-each polymer or polymer network to the other polymer or polymer network occurs simultaneously to form an IPN.

14. The method of claim 1, wherein the first polymeric component and the second polymeric component comprise monomeric, oligomeric or prepolymeric precursors of vinyl resins;

polyolefins;

polyurethanes;

polyureas;

polyamides;

polyamide/polyurethane copolymers, polyamide/polyurea copolymers, epoxy-end-capped polyurethanes, epoxy-end-capped polyureas, polyamide/polyurethane ionomers, polyamide/polyurea ionomers, acrylic resins;

olefinic rubbers;

polyphenylene oxide resins;

polyesters;

blends of vulcanized, unvulcanized or non-vulcanizable rubbers with polyethylene, polypropylene, polyacetal, nylon, polyesters, or cellulose esters;

or polymers or copolymers possessing epoxy-containing, or post-polymerization epoxy-functionalized repeat units.

15. The method of claim 1, wherein the portion of the golf ball formed from the IPN is a core, intermediate layer or cover layer.

16. The method of claim 1, wherein the portion of the golf ball comprises a cover layer.

17. A method of forming a golf ball having a center, a cover, and an intermediate layer disposed between the center and the cover comprising the steps of:

providing at least a first polymeric component and a second polymeric component, each polymeric component comprising at least one monomer, oligomer, prepolymer, or a combination thereof;

sufficiently polymerizing each polymeric component sequentially or simultaneously to form a polymer or polymer network;

crosslinking each polymer or polymer network to the other polymer or polymer network to form an interpenetrating polymer network (“

IPN”

); and

forming an intermediate layer from the IPN,

wherein each polymeric component of the mixture is polymerized by exposing the mixture to at least one energy source, at least one initiator, or a combination thereof for a time sufficient to polymerize the polymeric component.

18. The method of claim 17, wherein the initiator is present in an amount from about 0.01 to about 15 parts per hundred of total polymer component.

19. The method of claim 17, wherein the initiator is present in an amount from about 0.1 to about 10 parts per hundred of total polymer component.

20. A method of forming a portion of a golf ball comprising the steps of:

providing at least a first polymeric component and a second polymeric component, each polymeric component comprising at least one monomer, oligomer, prepolymer, or a combination thereof;

sufficiently polymerizing each polymeric component sequentially or simultaneously to form a polymer or polymer network;

crosslinking each polymer or polymer network to the other polymer or polymer network to form an interpenetrating polymer network (“

IPN”

); and

forming the IPN into the portion of the golf ball,

wherein each polymeric component of the mixture is polymerized by exposing the mixture to at least one energy source, at least one thermal free radical initiator selected from the group consisting of an azo compound, a peroxide, a persulfate, a redox initiator, and mixtures thereof, or a combination thereof for a time sufficient to polymerize the polymeric component.