Doping of organic opto-electronic devices to extend reliability

• US 7,179,543 B2
• Filed: 10/06/2003
• Issued: 02/20/2007
• Est. Priority Date: 10/06/2003
• Status: Active Grant

• Current Assignee: The Trustees of Princeton University (Princeton University), Universal Display Corporation
• Original Assignee: The Trustees of Princeton University (Princeton University), Universal Display Corporation
• Inventors: Forrest, Stephen R., D'Andrade, Brian Wendell, Chwang, Anna
• Primary Examiner(s): GARRETT, DAWN L
• Application Number:
  US10/680,065
• Publication Number:
  US 20050074629A1
• Time in Patent Office: 1,233 Days
• Field of Search: 428/690, 428/917, 313/504, 313/506
• US Class Current: 428/690
• CPC Class Codes: H10K 2101/10 Triplet emission
• CPC Class Codes: H10K 2102/103 comprising indium oxides, e.g. ITO
• CPC Class Codes: H10K 30/00 Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation integrated devices or assemblies of multiple devices H10K39/00, H10K65/00; electrolytic light-sensitive devices H01G9/20
• CPC Class Codes: H10K 50/11 characterised by the electroluminescent [EL] layers
• CPC Class Codes: H10K 50/14 Carrier transporting layers
• CPC Class Codes: H10K 50/155 comprising dopants
• CPC Class Codes: H10K 50/165 comprising dopants
• CPC Class Codes: H10K 50/18 Carrier blocking layers
• CPC Class Codes: H10K 71/30 Doping active layers, e.g. electron transporting layers
• CPC Class Codes: H10K 85/111 comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
• CPC Class Codes: H10K 85/324 comprising aluminium, e.g. Alq3
• CPC Class Codes: H10K 85/342 comprising iridium
• CPC Class Codes: H10K 85/611 Charge transfer complexes
• CPC Class Codes: Y02E 10/549 Organic PV cells
• CPC Class Codes: Y10S 428/917 Electroluminescent

Abstract

The present invention is directed to multi-layer organic devices having improved stability, wherein at least one layer of the device comprises a host material that is morphologically unstable and a dopant material that provides improved morphological properties to the layer. The layer may be incorporated into, for example, OLEDs, organic phototransistors, organic photovoltaic cells, and organic photodetectors.

Claims

1. An organic layer in an opto-electronic device comprising:

a host material that is morphologically unstable, the host material comprising a hole blocking material or an exciton blocking material; and

a dopant material that enhances the morphological stability of the host material,

wherein the dopant material is present in the host material at a concentration of 50% by weight or less, and wherein the organic layer does not have an emissive function in the device.

2. The organic layer of claim 1, wherein the host material is a hole blocking material.

3. The organic layer of claim 1 that is incorporated into an organic light emitting device.

4. The organic layer of claim 1, wherein the dopant material is present in the host material at a concentration of about 1% to about 45%.

5. The organic layer of claim 1, wherein the dopant material is present in the host material at a concentration of about 5% to about 40%.

6. The organic layer of claim 1, wherein the host material has a glass transition temperature less than about 70°

C.

7. The organic layer of claim 6, wherein the dopant material has a glass transition temperature above 90°

C.

8. The organic layer of claim 7, wherein the organic layer has a glass transition temperature above 80°

C.

9. The organic layer of claim 1 wherein the host material comprises a small molecule material.

10. The organic layer of claim 1 wherein the host material comprises a polymeric material.

11. The organic layer of claim 1, wherein the host blocking material is an exciton blocking material.

12. An organic light emitting device comprising

an anode;

a cathode;

a first organic layer disposed between and in electrical connection with the anode and the cathode, wherein the first organic layer is an emissive layer; and

a second organic layer disposed between the first organic layer and the cathode or between the first organic layer and the anode, wherein the second organic layer is a blocking layer,

wherein the second organic layer comprises;

a host material that is morphologically unstable; and

a dopant material that enhances the morphological stability of the host material,

wherein the dopant material is present in the host material at a concentration of 50% by weight or less, and

wherein the device has a lifetime that is at least about 25% longer than an analogous device having a second organic layer that does not contain the dopant material.

13. The organic light emitting device of claim 12, wherein the second organic layer is a hole blocking layer.

14. The organic light emitting device of claim 12, wherein the host material is Bphen and the dopant material is BAlq.

15. The organic light emitting device of claim 12, wherein the dopant material is present in the host material at a concentration of about 1% to about 45%.

16. The organic light emitting device of claim 15, wherein the dopant material is present in the host material at a concentration of about 5% to about 40%.

17. The organic light emitting device of claim 12, wherein the host material has a glass transition temperature of that is below 70°

C.

18. The organic layer of claim 17, wherein the dopant material has a glass transition temperature above 90°

C.

19. The organic light emitting device of claim 18, wherein the second organic layer has a glass transition temperature above 80°

C.

20. The organic light emitting device of claim 12, wherein the second organic layer is an exciton blocking layer.

21. The organic light emitting device of claim 12, wherein the second organic layer is disposed between the first organic layer and the anode, and wherein the second organic layer is an electron blocking layer.

22. An organic light emitting device comprising:

an anode;

a cathode;

a first organic layer disposed between and in electrical connection with the anode and the cathode, wherein the first organic layer is an emissive layer; and

a second organic layer disposed between the first organic layer and the cathode or between the first organic layer and the anode,

wherein the second organic layer comprises;

a mixture of a host material that is morphologically unstable, and a dopant material that enhances the morphological stability of the host material,

wherein the dopant material is present in the host material at a concentration of 50% by weight or less,

the host material is a hole blocking material or an exciton blocking material that becomes at least 20% crystalline after 100 hours at 35°

C. when deposited as a initially amorphous this film, and

the mixture of the host material and the dopant material does not become more than 10% crystalline after 100 hours at 35°

C. when deposited as a initially amorphous this film.

23. An organic light emitting device comprising:

an anode;

a cathode;

a first organic layer disposed between and in electrical contact with the anode and the cathode, wherein the first organic layer is an emissive layer;

a second organic layer disposed between the first organic layer and the cathode or between the first organic layer and the anode, wherein the second organic layer is a hole blocking layer or an exciton blocking layer disposed adjacent to the first organic layer, the second organic layer comprising;

a mixture of a host material that is morphologically unstable, and a dopant material that enhances the morphological stability of the host material,

wherein the dopant material is present in the host material at a concentration of 50% by weight or less.

24. The organic light emitting device of claim 23, wherein the second organic layer is a hole blocking layer.

25. The organic light emitting device of claim 23, wherein the second organic layer is an exciton blocking layer.

26. An organic layer in an opto-electronic device comprising:

a host material that is morphologically unstable, the host material comprising a polymeric material; and

a dopant material that enhances the morphological stability of the host material,

wherein the dopant material is present in the host material at a concentration of 50% by weight or less, and wherein the organic layer does not have an emissive function in the device.